Method of producing consistent high quality coke

• US 5,350,503 A
• Filed: 07/29/1992
• Issued: 09/27/1994
• Est. Priority Date: 07/29/1992
• Status: Expired due to Term

• Current Assignee: Atlantic Richfield Company Incorporated (BP PLC)
• Original Assignee: Atlantic Richfield Company Incorporated (BP PLC)
• Inventors: Holloway, Richard L., Kiracofe, Ronald J., Freymeyer, Douglas A., Sampath, Vijay R.
• Primary Examiner(s): MYERS, HELANE ELEANORA
• Application Number:
  US07/919,397
• Time in Patent Office: 790 Days
• Field of Search: 208/131, 208/50
• US Class Current: 208/131
• CPC Class Codes: C10B 55/00 Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material cracking oils C10G
• CPC Class Codes: C10B 57/045 containing mineral oils, bitumen, tar or the like or mixtures thereof

Abstract

A consistent high quality coke is produced by feeding a balancing stream comprising hydrocarbons to a delayed coking drum in addition to the heavy hydrocarbonaceous coker feedstock. The process of this invention reduces the contaminant content of coke by coking contaminant-containing residua and a reduced contaminant hydrocarbon balancing stream. Preferably, the balancing stream is a contaminant diluent, such as unreduced crude. The balancing stream may be a crude which is different from the base crude processed in the refinery crude tower and is preferably selected as a sulfur and/or metals diluent having a lower concentration of sulfur-containing or metal-containing compounds than the heavy coker feedstock.

Claims

1. In a delayed coking process wherein a heavy hydrocarbonaceous feedstock comprising contaminant-containing compounds, wherein said contaminant is a compound comprising sulfur, is fed to a delayed coking drum and is subjected to delayed coking conditions to form petroleum coke, the improvement comprising:

determining contaminant content of said heavy hydrocarbonaceous feedstock, determining contaminant content of a hydrocarbon balancing stream and feeding to said delayed coking drum a feed of said hydrocarbon balancing stream having a different contaminant content than said heavy hydrocarbonaceous feedstock, wherein said balancing stream is a contaminant diluent selected from the group consisting of virgin unreduced crude oil, desalted unreduced crude oil, reduced crude oil which has a lower API gravity and higher contaminant content than unreduced crude and which has a higher API gravity and lower contaminant content than atmospheric tower bottoms or vacuum tower bottoms, and mixtures thereof, wherein said hydrocarbon balancing stream is fed to said delayed coking drum at a rate which is adjusted in response to changes in concentration of contaminant-containing compounds of said heavy hydrocarbonaceous feedstock to maintain a consistent concentration of contaminants in said petroleum coke so formed.

2. A process in accordance with claim 1 wherein said delayed coking process is a component process of a refinery comprising a crude tower which processes a base crude and said balancing stream is an unreduced crude oil having a different concentration of contaminant than said base crude.

3. A delayed coking process comprising:

a. determining contaminant content of a heavy hydrocarbonaceous feedstock and determining contaminant content of a hydrocarbon balancing stream;

b. feeding to a first fractionator said heavy hydrocarbonaceous feedstock, said hydrocarbon balancing stream having a different concentration of a compound comprising sulfur than said heavy hydrocarbonaceous feedstock, wherein said balancing stream is a contaminant diluent selected from the group consisting of virgin unreduced crude oil, desalted unreduced crude oil, reduced crude oil which has a lower API gravity and higher contaminant content than unreduced crude and which has a higher API gravity and lower contaminant content than atmospheric tower bottoms or vacuum tower bottoms, and mixtures thereof, and a coker overhead product stream, as a first fractionator feed;

c. separating said first fractionator feed in said first fractionator into an overhead fraction, a bottoms fraction, and side fraction;

d. feeding to a delayed coking drum at least a portion of said bottoms fraction; and

e. operating said delayed coking drum under delayed coking conditions to form petroleum coke and a coker overhead product stream; and

f. adjusting rate of feed of said hydrocarbon balancing stream to said first fractionator in response to change in concentration of compound comprising sulfur of said heavy hydrocarbonaceous feedstock to maintain a consistent concentration of compound comprising sulfur in said petroleum coke so formed.

4. A process in accordance with claim 3 wherein said delayed coking process is a component process of a refinery comprising a crude tower which processes a base crude and said balancing stream is an unreduced crude oil having a different concentration of a compound comprising a sulfur component than said base crude.

5. A process in accordance with claim 3 wherein at least a portion of said side fraction is recovered as product.

6. A process in accordance with claim 3 wherein at least a portion of said overhead fraction is fed to a second fractionator.

7. A process in accordance with claim 6 wherein said overhead fraction is fed to a second fractionator and is separated in said second fractionator into a first, lighter fraction and a second, heavier fraction.

8. A process in accordance with claim 7 wherein at least a portion of said second, heavier fraction is fed to said first fractionator.

9. A process in accordance with claim 7 wherein at least a portion of said first, lighter fraction is withdrawn as product.

10. A process in accordance with claim 3 wherein at least a portion of said second, heavier fraction and said hydrocarbon balancing stream are passed through a heat exchange means wherein heat is transferred from said second, heavier fraction to said hydrocarbon balancing stream.

11. A process in accordance with claim 3 wherein said first, lighter fraction is separated into a third fraction, a fourth fraction and a fifth fraction, wherein said fifth fraction has a boiling point intermediate between said third fraction and said fourth fraction, and said fifth fraction is withdrawn as product.

12. In a delayed coking process wherein a heavy hydrocarbonaceous feedstock comprising contaminant-containing compounds, wherein said contaminant is a compound comprising a metal component, is fed to a delayed coking drum and is subjected to delayed coking conditions to form petroleum coke, the improvement comprising determining contaminant content of said heavy hydrocarbonaceous feedstock, determining contaminant content of a hydrocarbon balancing stream and feeding to said delayed coking drum a feed of said hydrocarbon balancing stream having a different contaminant content than said heavy hydrocarbonaceous feedstock, wherein said balancing stream is a contaminant diluent selected from the group consisting of virgin unreduced crude oil, desalted unreduced crude oil, reduced crude oil which has a lower API gravity and higher contaminant content than unreduced crude and which has a higher API gravity and lower contaminant content than atmospheric tower bottoms or vacuum tower bottoms, and mixtures thereof wherein said hydrocarbon balancing stream is fed to said delayed coking drum at a rate which is adjusted in response to changes in concentration of contaminant-containing compounds of said heavy hydrocarbonaceous feedstock to maintain a consistent concentration of contaminants in said petroleum coke so formed.

13. A process in accordance with claim 12 wherein said delayed coking process is a component process of a refinery comprising a crude tower which processes a base crude and said balancing stream is an unreduced crude oil having a different concentration of contaminant than said base crude.

14. A process in accordance with claim 12 wherein said hydrocarbon balancing stream is fed to said delayed coking drum at a rate which is adjusted in response to changes in the concentration of a compound comprising a metal component in said heavy hydrocarbonaceous feedstock to maintain a consistent concentration of a compound comprising a metal component in said petroleum coke so formed.

15. A delayed coking process comprising:

a. determining contaminant content of a heavy hydrocarbonaceous feedstock and determining contaminant content of a hydrocarbon balancing stream;

b. feeding to a first fractionator said heavy hydrocarbonaceous feedstock, said hydrocarbon balancing stream having a different concentration of a compound comprising a metal component than said heavy hydrocarbonaceous feedstock, wherein said balancing stream is a contaminant diluent selected from the group consisting of virgin unreduced crude oil, desalted unreduced crude oil, reduced crude oil which has a lower API gravity and higher contaminant content than unreduced crude and which has a higher API gravity and lower contaminant content than atmospheric tower bottoms or vacuum tower bottoms, and mixtures thereof, and a coker overhead product stream, as a first fractionator feed;

c. separating said first fractionator feed in said first fractionator into an overhead fraction, a bottoms fraction, and side fraction;

d. feeding to a delayed coking drum at least a portion of said bottoms fraction;

e. operating said delayed coking drum under delayed coking conditions to form petroleum coke and a coker overhead product stream; and

f. adjusting rate of feed of said hydrocarbon balancing stream to said first fractionator in response to change in concentration of compound comprising a metal component of said heavy hydrocarbonaceous feedstock to maintain a consistent concentration of compound comprising a metal component in said petroleum coke so formed.

16. A process in accordance with claim 15 wherein said delayed coking process is a component process of a refinery comprising a crude tower which processes a base crude and said balancing stream is an unreduced crude oil having a different concentration of a compound comprising a metal component than said base crude.

17. A process in accordance with claim 15 wherein at least a portion of said side fraction is recovered as product.

18. A process in accordance with claim 15 wherein at least a portion of said overhead fraction is fed to a second fractionator.

19. A process in accordance with claim 18 wherein said overhead fraction is fed to a second fractionator and is separated in said second fractionator into a first, lighter fraction and a second, heavier fraction.

20. A process in accordance with claim 19 wherein at least a portion of said second, heavier fraction is fed to said first fractionator.

21. A process in accordance with claim 19 wherein at least a portion of said first, lighter fraction is withdrawn as product.

22. A process in accordance with claim 15 wherein at least a portion of said second, heavier fraction and said hydrocarbon balancing stream are passed through a heat exchange means wherein heat is transferred from said second, heavier fraction to said hydrocarbon balancing stream.

23. A process in accordance with claim 15 wherein said first, lighter fraction is separated into a third fraction, a fourth fraction and a fifth fraction, wherein said fifth fraction has a boiling point intermediate between said third fraction and said fourth fraction, and said fifth fraction is withdrawn as product.