Gas generator ignited by lamina or film

• US 5,351,619 A
• Filed: 02/18/1992
• Issued: 10/04/1994
• Est. Priority Date: 02/18/1991
• Status: Expired due to Fees

• Current Assignee: ICI Canada, Inc. (Ici Paints), Imperial Chemical Industries PLC (Nouryon BV)
• Original Assignee: ICI Canada, Inc. (Ici Paints), Imperial Chemical Industries PLC (Nouryon BV)
• Inventors: Chan, Sek K., Graham, Steven J., Leiper, Graeme A.
• Primary Examiner(s): Nelson, Peter A.
• Application Number:
  US07/843,942
• Time in Patent Office: 959 Days
• Field of Search: 102/289, 102/290
• US Class Current: 102/289
• CPC Class Codes: B60R 2021/26047 of film shape
• CPC Class Codes: B60R 21/2644 using only solid reacting substances, e.g. pellets, powder
• CPC Class Codes: C06B 45/14 a layer or zone containing an inorganic explosive or an inorganic explosive or an inorganic thermic component
• CPC Class Codes: C06C 9/00 Chemical contact igniters; Chemical lighters
• CPC Class Codes: F42B 3/04 for producing gas under pressure generators of inflation fluid especially adapted for vehicle air bags B60R21/26
• CPC Class Codes: F42B 5/16 characterised by composition or physical dimensions or form of propellant charge, with or without projectile, or powder chemical composition C06B; F42B5/24 takes precedence
• CPC Class Codes: F42C 19/0803 characterised by the combination of per se known chemical composition in the priming substance

Abstract

A vehicle occupant safety restraint gas generator is provided in which the ignition system for the propellant comprises a pyrotechnic layer (22), e.g. a reactive film, preferably comprising a substrate of oxidizing polymeric film such as polytetrafluoro-ethylene (PTFE) having at least a portion of its surface covered with a layer of oxidizable material, for example magnesium, which may be vapour-deposited on the surface. The propellant is preferably a propellant train (12, 14, 16, 18) which comprises a plurality of adjacent propellant grains such as toroidal discs which surround the pyrotechnic layer or are completeley encased thereby. The gas generator is simpler and more economical to manufacture, and has improved safety during use.

Claims

1. A gas generating device comprising:

a compacted particulate gas-generating propellant charge; and

a pyrotechnic igniter for said propellant charge, said pyrotechnic igniter comprising a lamina or film comprising a pyrotechnic layer, and said pyrotechnic layer being in ignition transmission relationship with said propellant charge.

2. A device as claimed in claim 1 wherein said lamina or film encloses or is enclosed by the propellant charge.

3. A device as claimed in claim 1 wherein said lamina or film comprises a substrate of an oxidizing polymeric film having a layer of an oxidizable material on at least a portion of at least one surface of said substrate, and said polymeric film and said oxidizable material are conjointly capable of reacting together exothermically on ignition.

4. A device as claimed in claim 3 wherein the oxidizing polymeric film contains atoms chemically bound therein and selected from the group consisting of halogens, oxygen, sulphur, nitrogen and phosphorous.

5. A device as claimed in claim 4 wherein the oxidizing polymeric film is made from a polymer selected from the group consisting of polytetrafluoro-ethylene (PTFE), polyhexafluoropropylene copolymers of vinylidene fluoride and hexafluoropropylene, copolymers of tetrafluoroethylene and perfluoropropylene, copolymers of chlorotrifluoroethylene and vinylidene fluoride, homopolymers of perfluoropropylene, copolymers of perfluoropropylene and vinylidene fluoride, trichloroethylene homopolymer, copolymers of trichloroethylene and vinylidene fluoride and mixtures of two or more of such polymers.

6. A device as claimed in claim 3 wherein the oxidizable material is vapour-deposited on the film.

7. A device as claimed in claim 3 wherein the oxidizable material comprises a metal selected from the group consisting of lithium, sodium, magnesium, beryllium, calcium, strontium, barium, aluminum, titanium, zirconium and alloys of such metals.

8. A device as claimed in claim 7 wherein the ratio of metal to the oxidizing polymeric film is substantially stoichiometric at the location of the film underlying the metal.

9. A device as claimed in claim 1 wherein the propellant charge is encased in an envelope or pouch of the lamina or film comprising the pyrotechnic layer.

10. A device as claimed in claim 9 wherein the lamina or film comprises a polymeric film which is impervious to air or moisture and the propellant charge is sealed within the lamina or film.

11. A device as claimed in claim 1 wherein the propellant charge comprises a sodium azide based composition.

12. A device as claimed in claim 1 wherein the propellant charge comprises compacted pellets or discs stacked adjacently end-to-end to form a propellant train.

13. A device as claimed in claim 12 wherein the propellant charge comprises compacted propellant discs having projecting portions or castellations formed on at least one of the cylindrical end surfaces of the disc.

14. A device as claimed in claim 13 wherein the projecting portions are shaped so that when the discs are stacked a series of radially offset channels is provided to facilitate the flow of gas from the center to the outside of the stack.

15. A device as claimed in claim 13 wherein the area of the projecting portions is greater than the area therebetween.

16. A device as claimed in claim 12 wherein the compacted propellant discs are toroidal discs.

17. A device as claimed in claim 16 wherein the lamina or film comprising the pyrotechnic layer confronts the inner toroid surfaces as a tubular insert optionally containing further propellant material.

18. A method of igniting a compacted particulate gas-generating propellant charge wherein a performed lamina or film comprising a pyrotechnic layer is placed in ignition transmission relationship with the propellant charge and the said lamina or film is ignited.

19. A gas generating device comprising:

a compacted particulate gas-generating propellant charge comprising compacted pellets or discs stacked adjacently end-to-end to form a propellant train; and

a pyrotechnic igniter in ignition transmission relationship with said propellant charge, said pyrotechnic igniter comprising a lamina or film comprising a substrate of an oxidizing polymeric film having a layer of an oxidizable material on at least a portion of at least one surface of said substrate, said polymeric film and said oxidizable material being conjointly capable of reacting together exothermically on ignition, said oxidizing polymeric film containing atoms chemically bound therein and selected from the group consisting of halogens, oxygen, sulphur, nitrogen and phosphorous, and said oxidizing polymeric film being made from a polymer selected from the group consisting of polytetrafluoro-ethylene (PTFE), polyhexafluoropropylene copolymers of vinylidene fluoride and hexafluoropropylene, copolymers of tetrafluoroethylene and perfluoropropylene, copolymers of chlorotrifluoroethylene and vinylidene fluoride, homopolymers of perfluoropropylene, copolymers of perfluoropropylene and vinylidene fluoride, trichloroethylene homopolymer, copolymers of trichloroethylene and vinylidene fluoride and mixtures of two or more of such polymers.

20. A gas generating device comprising:

a compacted particulate gas-generating propellant charge comprising compacted pellets or discs stacked adjacently end-to-end to form a propellant train; and

a pyrotechnic igniter in ignition transmission relationship with said propellant charge, said pyrotechnic igniter comprising a lamina or film comprising a substrate of an oxidizing polymeric film having a layer of an oxidizable material on at least a portion of at least one surface of said substrate, said polymeric film and said oxidizable material being conjointly capable of reacting together exothermically on ignition, said oxidizing polymeric film containing atoms chemically bound therein and selected from the group consisting of halogens, oxygen, sulphur, nitrogen and phosphorous, and said oxidizable material comprises a metal selected from the group consisting of lithium, sodium, magnesium, beryllium, calcium, strontium, barium, aluminum, titanium, zirconium and alloys of such metals.

21. A method of generating gas comprising the steps of:

igniting a pyrotechnic igniter comprising a lamina or film comprising a substrate of an oxidizing polymeric film having a layer of an oxidizable material on at least a portion of at least one surface of said substrate, said polymeric film and said oxidizable material being conjointly capable of reacting together exothermically on ignition, wherein said ignited pyrotechnic igniter ignites a compacted particulate gas-generating propellant charge to thereby generate said gas.