Groundwater treatment process

• US 5,352,335 A
• Filed: 11/09/1992
• Issued: 10/04/1994
• Est. Priority Date: 11/09/1992
• Status: Expired due to Fees

• Current Assignee: Albemarle Corporation
• Original Assignee: Albemarle Corporation
• Inventors: Beaver, Phillip R.
• Primary Examiner(s): Manoharan, Virginia
• Application Number:
  US07/973,972
• Time in Patent Office: 694 Days
• Field of Search: 203/11, 203/10, 203/49, 203/92, 203/14, 203/96, 203/42, 202/202, 202/182, 202/183, 202/205, 570/262, 261/136, 261/147, 210/664, 210/737
• US Class Current: 203/11
• CPC Class Codes: B01D 3/34 with one or more auxiliary substances
• CPC Class Codes: C07C 17/38 Separation; Purification; Stabilisation; Use of additives
• CPC Class Codes: Y10S 210/908 Organic

Abstract

A continuous process for the extraction of halogenated hydrocarbons from a dilute, halogenated hydrocarbon-containing aqueous fluid, in high efficiency, while dramatically reducing the stripping medium requirement for the extraction and without substantially increasing the amount of halogenated hydrocarbons discharged to the atmosphere.

Claims

1. A carbon adsorption-free process for extracting halogenated hydrocarbons from a dilute, halogenated hydrocaron-containing aqueous fluid, said process comprising:

(a) introducing dilute, halogenated hydrocarbon-containing aqueous fluid into an upper portion of an upright enclosed chamber;

(b) introducing a stripping medium into a lower portion of the chamber whereby the stripping medium intimately contacts the dilute, halogenated hydrocarbon-containing aqueous fluid in a countercurrent manner;

(c) removing halogenated hydrocarbon-depleted aqueous fluid from the lower portion of the chamber;

(d) removing a halogenated hydrocarbon rich vapor stream from the upper portion of the chamber;

(e) condensing at least a portion of the halogenated hydrocarbon-rich vapor stream thereby forming a halogenated hydrocarbon-rich liquid portion and a halogenated hydrocarbon-containing non-condensed portion;

(f) contacting at least a portion of the non-condensed portion with an aqueous absorbing fluid whereby the amount of halogenated hydrocarbons in the contacted non-condensed portion is reduced by at least about 85 wt. % based on the initial weight of halogenated hydrocarbons in the non-condensed portion; and

(g) collecting contacted absorbing fluid from step (f) and introducing collected fluid into the upright enclosed chamber.

2. The process of claim 1 wherein said stripping medium is steam.

3. The process of claim 2 wherein said halogenated hydrocarbon is a chlorinated or brominated hydrocarbon.

4. The process of claim 3 wherein said halogenated hydrocarbon is predominantly 1,2-dichloroethane.

5. The process of claim 3 wherein said halogenated hydrocarbon is predominantly ethylene dibromide.

6. The process of claim 1 wherein the stripping medium is steam and wherein the dilute, halogenated hydrocarbon-containing aqueous fluid and steam are contacted under subatmospheric pressure.

7. The process of claim 6 wherein said dilute, halogenated hydrocarbon-containing aqueous fluid is introduced into said chamber at a temperature in the range of from about 0°

to about 40°

C.

8. The process of claim 7 wherein the subatmospheric pressure within the chamber is in the range of from about 20 to about 200 mm Hg.

9. The process of claim 6 wherein the subatmospheric pressure within the chamber is in the range of from about 1 to about 600 mm Hg.

10. The process of claim 1 wherein said dilute, halogenated hydrocarbon-containing aqueous fluid is introduced into said enclosed chamber at a temperature in the range of from about 0°

to about 40°

C.

11. The process of claim 10 wherein the subatmospheric pressure within the chamber is in the range of from about 60 to about 120 mm Hg.

12. A carbon adsorption-free continuous process for extracting halogenated hydrocarbons from a dilute, halogenated hydrocarbon-containing aqueous fluid, said process comprising:

(a) continuously introducing dilute, halogenated hydrocarbon-containing aqueous fluid into an upper portion of an upright, elongated, enclosed chamber containing contact packing material;

(b) continously introducing steam into a lower portion of the enclosed chamber below the contact packing whereby the steam contacts the dilute, halogenated hydrocarbon-containing aqueous fluid in a countercurrent manner within the enclosed chamber;

(c) continously removing a halogenated hydrocarbon-depleted aqueous fluid from the lower portion of the enclosed chamber;

(d) continously removing a vapor stream containing halogenated hydrocarbon and steam from the upper portion of the enclosed chamber;

(e) continuously condensing at least a portion of the halogenated hydrocarbon and steam in the vapor steam from the upper portion of the enclosed chamber thereby forming a halogenated hydrocarbon rich liquid portion and a non-condensed portion;

(f) continously contacting at least a portion of the non-condensed portion with an aqueous absorbing fluid whereby the amount of halogenated hydrocarbon is contacted non-condensed portion is reduced by at least about 85wt. % based on the initial weight of halogenated hydrocarbons in the non-condensed portion; and

(g) collecting contacted absorbing fluid from step (f) and introducing collected fluid into the upright enclosed chamber.

13. The process of claim 12 wherein said halogenated hydrocarbon is a brominated or chlorinated hydrocarbon.

14. The process of claim 13 wherein said chlorinated hydrocarbon is predominantly 1,2-dichloroethane.

15. The process of claim 13 wherein said brominated hydrocarbon is predominantly ethylene dibromide.

16. The process of claim 12 wherein dilute, halogenated hydrocarbon-containing aqueous fluid and steam are contacted under subatmospheric pressure.

17. The process of claim 16 wherein said dilute, halogenated hydrocarbon-containing aqueous fluid is introduced into said enclosed chamber at a temperature in the range of from about 0°

to about 40°

C.

18. The process of claim 17 wherein the subatmospheric pressure within the enclosed chamber is in the range of from about 40 to about 120 mm Hg.

19. The process of claim 17 wherein said dilute, halogenated hydrocarbon-containing aqueous fluid is introduced into said enclosed chamber at a temperature in the range of from about 0°

to about 40°

C.