Carbonic acid gas sensor

• US 5,352,352 A
• Filed: 09/23/1992
• Issued: 10/04/1994
• Est. Priority Date: 09/24/1991
• Status: Expired due to Term

• Current Assignee: Hitachi, Ltd.
• Original Assignee: Hitachi, Ltd.
• Inventors: Tsukada, Keiji, Shibata, Yasuhisa, Watanabe, Yoshio, Miyahara, Yuji
• Primary Examiner(s): TUNG, TA HSUNG
• Application Number:
  US07/948,646
• Time in Patent Office: 741 Days
• Field of Search: 204/415-420, 204/153.17, 204/153.22, 204/433
• US Class Current: 204/415
• CPC Class Codes: A61B 5/14539 for measuring pH
• CPC Class Codes: A61B 5/14542 for measuring blood gases A61B5/14551 takes precedence
• CPC Class Codes: A61B 5/1468 using chemical or electrochemical methods, e.g. by polarographic means A61B5/1486 takes precedence
• CPC Class Codes: G01N 27/4045 for gases other than oxygen
• CPC Class Codes: G01N 33/4925 measuring blood gas content, e.g. O2, CO2 , HCO3

Abstract

A sensor for detecting a carbonic acid gas dissolved in body fluids has a laminated structure including an outer plate having a carbonic acid gas permeable window, a plate for a pH-electrode having a pH sensitive membrane, an intermediate plate having a cavity for accommodating an electrolyte, and a plate for a reference electrode. The plate for the pH-electrode is constituted in a manner that a pH sensitive membrane constituted by a membrane of an oxide of a platinum group metal is formed on an insulating substrate and the electrolyte contacts with the pH sensitive membrane in a groove. The pH sensitive membrane is disposed so as to oppose to the carbonic acid gas permeable window.

Claims

1. A carbonic acid gas sensor capable of detecting carbonic acid gas dissolved in fluid, comprising:

an outer plate including first and second glass substrates each having a window formed therein and fixedly sandwiching a gas permeable membrane to form a carbonic acid gas permeable window;

a first supporting plate supporting a pH-electrode, for detecting a pH of an electrolyte, including an insulating substrate, a pH sensitive membrane formed on said substrate so as to oppose said carbonic acid gas permeable window, and a compartment for accommodating the electrolyte, said compartment extending through the thickness of said first supporting plate; and

a second supporting plate supporting a reference electrode, wherein said outer plate, said first supporting plate and said second supporting plate are laminated.

2. A carbonic acid gas sensor according to claim 1, wherein said pH sensitive membrane is formed by an oxide of a platinum group metal.

3. A carbonic acid gas sensor according to claim 2, wherein said oxide is a palladium oxide.

4. A carbonic acid gas sensor according to claim 2, wherein said oxide is an iridium oxide.

5. A carbonic acid gas sensor according to claim 2, wherein said oxide is a platinum oxide.

6. A carbonic acid gas sensor according to claim 1, wherein said pH sensitive membrane is an indium oxide membrane.

7. A carbonic acid gas sensor according to claim 1, wherein said first supporting plate further includes a conductive layer formed on said insulating substrate and to be connected to an external lead wire, and said pH sensitive membrane is disposed on said conductive layer so as to cover a part thereof.

8. A carbonic acid gas sensor according to claim 7, wherein each of said first supporting plate and said second supporting plate has a through hole for wiring, and the lead wire connected to said conductive layer is extracted out of said second supporting plate through said through holes.

9. A carbonic acid gas sensor according to claim 1, wherein said pH sensitive membrane contacts with the electrolyte in said compartment.

10. A carbonic acid gas sensor according to claim 1, wherein said compartment of said first supporting plate includes a hole formed in said insulating substrate and a groove formed at a part of a composite resin layer covering the surface of said insulating substrate, and said groove communicates with said hole.

11. A carbonic acid gas sensor according to claim 1, further comprising an intermediate plate having a cavity for accommodating the electrolyte and disposed between said first supporting plate and said second supporting plate.

12. A carbonic acid gas sensor according to claim 1, wherein an exposed area of said pH sensitive membrane is smaller than an area of said carbonic acid gas permeable window.