Microfiber fillers for orthopedic casting tapes

• US 5,354,259 A
• Filed: 01/25/1993
• Issued: 10/11/1994
• Est. Priority Date: 01/25/1993
• Status: Expired due to Term

• Current Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Original Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Inventors: Scholz, Matthew T., Mindaye, Worku A.
• Primary Examiner(s): CANNON, JAMES
• Application Number:
  US08/008,755
• Time in Patent Office: 624 Days
• Field of Search: 602/8, 428/241, 428/242, 428/244, 428/240, 427/180, 427/203, 427/341
• US Class Current: 602/8
• CPC Class Codes: A61L 15/12 containing macromolecular materials
• CPC Class Codes: A61L 15/14 Use of materials characterised by their function or physical properties
• CPC Class Codes: C08K 2201/016 Additives defined by their aspect ratio
• CPC Class Codes: C08K 7/02 Fibres or whiskers
• CPC Class Codes: Y10T 442/20 Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
• CPC Class Codes: Y10T 442/2861 Coated or impregnated synthetic organic fiber fabric
• CPC Class Codes: Y10T 442/2992 Coated or impregnated glass fiber fabric

Abstract

The present invention provides an article, comprising: a fabric sheet; a curable resin coated onto the fabric sheet; and a plurality of microfiber fillers dispersed into the resin. The incorporation of microfiber fillers into the casting materials of the present invention adds substantially to the strength of the cured casting material, particularly when the fabric used therein is a non-fiberglass fabric, while not detracting from the handling properties of the uncured casting tape or bandage.

The microfiber fillers useful in this invention are generally characterized as being short fibers having an aspect ratio greater than five to one. Blends of microfibers having different aspect ratios may be utilized in the casting tapes of the present invention. Preferred microfiber fillers or blends have an aspect ratio between 5:1 and 200:1, more preferably, the aspect ratio of the microfiber is between 5:1 and 50: 1, and most preferably, the aspect ratio of the microfiber is between 10:1 and 30:1.

Claims

1. An article, comprising:

a fabric sheet;

a curable liquid resin coated onto said fabric sheet; and

a microfiber filler, having an aspect ratio at least 5;

1, associated with said resin.

2. An article, as defined in claim 1, wherein said fabric sheet comprises fiberglass fibers.

3. An article, as defined in claim 1, wherein said fabric sheet comprises organic fibers.

4. An article, as defined in claim 1, wherein said curable resin is a water-curable resin comprising isocyanate-functional prepolymers.

5. An article, as defined in claim 1, wherein said curable resin is a water-curable resin comprising a water-reactive liquid organometallic compound and an organic polymer.

6. An article, as defined in claim 1, wherein said microfiber is characterized as having an aspect ratio between 5:

1 and 200;

1.

7. An article, as defined in claim 4, wherein said microfiber is characterized as having an aspect ratio between 5:

1 and 50;

1.

8. An article, as defined in claim 3, wherein said microfiber is characterized as having an aspect ratio between 10:

1 and 30;

1.

9. An article, as defined in claim 6, wherein said microfiber is characterized as having a mean diameter between approximately 1 and 60 microns and a mean length between approximately 25 and 1000 microns.

10. An article, as defined in claim 7, wherein said microfiber is characterized as having a mean diameter between approximately 1 and 40 microns and a mean length between approximately 30 and 1,000 microns.

11. An article, as defined in claim 7, wherein said microfiber is characterized as having a mean diameter between approximately 1 and 30 microns and a mean length between approximately 30 and 500 microns.

12. An article, as defined in claim 1, wherein said microfiber is selected from the group consisting of carbon/graphite fibers, aramid fibers, boron fibers, potassium titanate fibers, calcium sulfate fibers, asbestos, and calcium metasilicate.

13. An article, as defined in claim 6, wherein said microfiber comprises calcium sulfate fibers.

14. An article, as defined in claim 6, wherein said microfiber comprises calcium metasilicate.

15. An article, as defined in claim 1, wherein said microfiber is present in an amount in said resin between about 3 and about 25 percent microfiber based on the weight of resin and microfiber filler and exclusive of the weight of the fabric.

16. An article, as defined in claim 1, wherein said microfiber is present in an amount in said resin between about 7 and about 25 percent microfiber based on the weight of resin and microfiber filler and exclusive of the weight of the fabric.

17. An article, as defined in claim 1, wherein said microfiber and said resin are in the form of a suspension prior to application to said fabric, and wherein said suspension has a viscosity between about 5 and 100 Pa s.

18. An article, as defined in claim 1, wherein said microfiber and said resin are in the form of a suspension prior to application to said fabric, and wherein said suspension has a viscosity between about 10 and 70 Pa s.

19. An article, as defined in claim 1, wherein said fabric sheet comprises organic fibers, wherein said microfiber filler is selected from the group consisting of calcium sulfate fibers and calcium metasilicate fibers, wherein said microfiber is characterized as having an aspect ratio between 5:

1 and 50;

1 and is present in an amount in said resin between about 7 and about 25 percent microfiber based on the weight of resin and microfiber and exclusive of the weight of the fabric.

20. A method of making an orthopedic casting bandage, comprising the step of:

coating a fabric with a curable liquid resin and a microfiber filler.

21. A method according to claim 20, wherein said resin and microfiber filler are concurrently coated onto said fabric.

22. A method according to claim 20, wherein said fabric comprises fiberglass fibers.

23. A method according to claim 20, wherein said fabric comprises organic fibers.

24. A method according to claim 20, wherein said curable resin is a water-curable resin comprising isocyanate-functional prepolymers.

25. A method according to claim 20, wherein said curable resin is a water-curable resin comprising a water-reactive liquid organometallic compound and an organic polymer.

26. A method according to claim 20, wherein said microfiber is characterized as having an aspect ratio between 5:

1 and 50;

1.

27. A method according to claim 23, wherein said micro fiber is characterized as having an aspect ratio between 10:

1 and 30;

1.

28. A method according to claim 26, wherein said microfiber is characterized as having a mean diameter between approximately 1 and 60 microns and a mean length between approximately 25 and 1000 microns.

29. A method according to claim 27, wherein said microfiber is characterized as having a mean diameter between approximately 1 and 40 microns and a mean length between approximately 30 and 1,000 microns.

30. A method according to claim 20, wherein said microfiber is selected from the group consisting of carbon/graphite fibers, aramid fibers, boron fibers, potassium titanate fibers, calcium sulfate fibers, asbestos, and calcium metasilicate.

31. A method according to claim 20, wherein said microfiber is present in an amount in said resin between about 7 and about 25 percent microfiber based on the weight of resin and microfiber filler and exclusive of the weight of the fabric.

32. A method according to claim 20, wherein said microfiber and said resin are in the form of a suspension prior to application to said fabric, and wherein said suspension has a viscosity between about 5 and 100 Pa s.

33. A method according to claim 20, wherein said microfiber and said resin are in the form of a suspension prior to application to said fabric, and wherein said suspension has a viscosity between about 10 and 70 Pa s.

34. A method of applying an orthopedic casting material comprising the steps of:

contacting a casting material comprising a fabric sheet, a water-curable liquid resin, and microfiber fillers with water to initiate curing of said resin, and

applying said casting material to a patient.

35. A method according to claim 34, wherein said microfiber fillers are selected from the group consisting of calcium sulfate fibers, and calcium metasilicate;

said microfiber and said resin being in the form of a suspension prior to application to said fabric, and wherein said suspension has a viscosity between about 5 and 100 Pa s; and

said microfiber fillers are characterized as having an aspect ratio between 5;

1 and 50;

1.