Purge effluent repressurized adsorption process

• US 5,354,346 A
• Filed: 10/01/1992
• Issued: 10/11/1994
• Est. Priority Date: 10/01/1992
• Status: Expired due to Fees

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Kumar, Ravi
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US07/955,630
• Time in Patent Office: 740 Days
• Field of Search: 55/25, 55/26, 55/58, 55/62, 55/68, 55/74, 55/75
• US Class Current: 95/101
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2253/104 Alumina
• CPC Class Codes: B01D 2253/106 Silica or silicates
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2259/40001 Methods relating to additional, e.g. intermediate, treatment of process gas
• CPC Class Codes: B01D 2259/40066 Six
• CPC Class Codes: B01D 2259/40069 Eight
• CPC Class Codes: B01D 2259/4061 using five beds
• CPC Class Codes: B01D 53/047 Pressure swing adsorption

Abstract

A pressure swing adsorption process is set forth for the recovery of two gas products at high recovery and high purity using the steps of adsorption, depressurization, low pressure purge, evacuation and repressurization. The purge effluent and a portion of the depressurization effluent are used to partially accomplish the repressurization step.

Claims

1. In a pressure swing adsorption process for the recovery of two gas products at high recovery and high purity from a feed gas stream containing said products wherein a first gas product is one or more, less strongly adsorbed components and a second gas product is one or more, more strongly adsorbed components, and wherein said process comprises the steps of:

(a) introducing a feed gas stream at elevated pressure containing said one or more, less strongly adsorbed components and said one or more, more strongly adsorbed components into one of a plurality of parallel adsorptive beds filled with one or more adsorbents selective for said one or more, more strongly adsorbed components, so as to retain said one or more, more strongly adsorbed components on said one or more adsorbents and allow said one or more, less strongly adsorbed components to pass through said bed for recovery as said first gas product at high recovery and high purity;

(b) terminating the introduction of said feed gas stream into said bed before said one or more, more strongly adsorbed components break through the downstream end of said bed and depressurizing said bed to approximately ambient pressure to remove said one or more, less strongly adsorbed components from said bed and recycling at least a portion of the resulting depressurization effluent to said feed gas stream;

(c) passing a low pressure purge gas stream of one or more, more strongly adsorbed components through said bed to remove any residual one or more, less strongly adsorbed components from said bed;

(d) evacuating said bed to a subambient pressure to recover said one or more, more strongly adsorbed components as said second gas product at high recovery and high purity; and

(e) repressurizing said bed with one or more, less strongly adsorbed components to approximately the pressure of the feed gas stream, wherein the steps (a) through (e) are performed on said plurality of beds to result in a continuous process;

the improvement to increase the energy efficiency of the process comprising a purge effluent repressurization step wherein said bed is partially repressurized after step (d) and prior to step (e) with the effluent from one of said parallel beds presently undergoing step (c).

2. The process of claim 1 wherein the improvement further comprises a depressurization effluent repressurization step wherein said bed is partially repressurized after step (d) and prior to the purge effluent repressurization step with a last portion of the effluent from one of said parallel beds presently undergoing step (b).

3. The process of claim 1 wherein the elevated pressure of said feed gas stream is in the range of approximately 30 to 500 psia.

4. The process of claim 1 wherein the depressurization is conducted down to a pressure of approximately 15 psia.

5. The process of claim 1 wherein the evacuation is conducted down to a pressure in the range of approximately 40 to 200 torr.

6. The process of claim 1 wherein said less strongly adsorbed components and said more strongly adsorbed components are selected from the group consisting of hydrogen, oxygen, carbon dioxide, nitrogen, carbon monoxide, methane, and other hydrocarbons.

7. The process of claim 1 wherein the adsorbent is selected from the group consisting of zeolites, carbons, aluminas and silica gels.

8. The process of claim 1 wherein the feed gas temperature is in the range of approximately 0°

to 300°

F.