Laser imageable photomask constructions

• US 5,354,633 A
• Filed: 09/22/1993
• Issued: 10/11/1994
• Est. Priority Date: 09/22/1993
• Status: Expired due to Term

• Current Assignee: Presstek Incorporated (MAI Holdings, Inc.)
• Original Assignee: Presstek Incorporated (MAI Holdings, Inc.)
• Inventors: Lewis, Thomas E., Nowak, Michael T.
• Primary Examiner(s): ROSASCO, STEPHEN D
• Application Number:
  US08/125,321
• Time in Patent Office: 384 Days
• Field of Search: 430/5, 430/20, 430/273, 430/323, 430/271, 428/408
• US Class Current: 430/5
• CPC Class Codes: B41M 5/24 Ablative recording, e.g. by burning marks; Spark recording marking by high energetic means, e.g. by laser otherwise than burning or ablative removal B41M5/26; materials or methods for recording or reproduction by optical means G11B7/00
• CPC Class Codes: G03F 1/50 Mask blanks not covered by G03F1/20 - G03F1/34; Preparation thereof
• CPC Class Codes: G03F 1/68 Preparation processes not covered by groups G03F1/20 - G03F1/50

Abstract

Novel photomask blanks and methods for producing photomasks using laser-imaging apparatus. The photomask blanks include at least one layer that absorbs laser energy and ablates in response thereto, and, where unremoved as a result of the imaging process, perform the masking function by blocking the passage of actinic radiation; and a a mechanically strong, durable and flexible substrate that is substantially transparent to actinic radiation.

Claims

1. A photomask construction for use in conjunction with a source of actinic radiation, the construction comprising:

a. an ignition layer at least partially opaque to actinic radiation and ignitable by exposure to laser radiation;

b. an ignitable metal layer at least partially opaque to actinic radiation and which combines with the first layer to block at least 99% of incident actinic radiation, the metal layer ablating in response to combustion of the ignition layer;

c. a mechanically strong, durable and flexible third layer that is substantially transparent to actinic radiation.

2. The construction of claim 1 further comprising a protective, overlying polymeric surface layer.

3. The construction of claim 1 further comprising a protective, overlying, abrasion-resistant inorganic surface layer.

4. The construction of claim 3 wherein at least one of the ignition layer and the inorganic surface layer is fabricated from at least one material selected from the group consisting of compounds of the formula TiO_x, where 0.8<

×

<

2;

TiN;

TiC;

WC;

compounds of the formula VO_x, where 0.8<

×

<

2.5;

compounds of the formula WO_x, where 2<

×

<

3; and

Co₃ O₄.

5. The construction of claim 1 wherein the metal layer is a metal selected from the group consisting of aluminum, chromium, nickel, zinc, copper, and titanium.

6. The construction of claim 1 wherein the ignition layer preferentially absorbs IR radiation.

7. The construction of claim 1 wherein the ignition layer preferentially absorbs ultraviolet radiation.

8. The construction of claim 1 wherein:

a. The ignition layer is TiO; and

b. The metal layer is aluminum.

9. The construction of claim 8 wherein the TiO layer is no thicker than 100 Å

and the metal layer is at least 200 Å

thick.

10. The construction of claim 1 wherein the third layer is at least 0.001 inch thick and no greater than 0.01 inch thick.

11. A photomask construction for use in conjunction with a source of actinic radiation, the construction comprising:

a. a first layer at least partially opaque to actinic

b. a metal layer at least partially opaque to actinic radiation and which combines with the first layer to block at least 99% of incident actinic radiation;

c. a mechanically strong, durable and flexible third layer that is substantially transparent to actinic radiation; and

d. a fourth layer located between the metal and third layers, the fourth layer;

i. exhibiting limited thermal stability; and

ii. having sufficient thickness to ablate only partially in response to ablation of the metal layer.

12. The construction of claim 11 wherein the fourth layer is selected from the group consisting of polymethylmethacrylate, polycarbonates, polyesters, polyurethanes, polystyrenes, styrene/acrylonitrile polymer, cellulosic ethers and esters, polyacetals, and combinations thereof.