Limited coalescence process

• US 5,354,799 A
• Filed: 11/16/1992
• Issued: 10/11/1994
• Est. Priority Date: 11/16/1992
• Status: Expired due to Term

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Bennett, James R., Smith, Dennis E.
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Ashton, Rosemary
• Application Number:
  US07/977,224
• Time in Patent Office: 694 Days
• Field of Search: 430/137, 523/333, 523/339, 524/457, 524/458, 528/934, 526/203
• US Class Current: 524/458
• CPC Class Codes: C08J 2325/06 Polystyrene
• CPC Class Codes: C08J 3/12 Powdering or granulating
• CPC Class Codes: Y10S 528/934 Latex

Abstract

A limited coalescence method of making polymer particles having an average particle size of 3 μm or less comprising dispersing the polymer particles in an organic liquid diluent after they are separated from the aqueous suspension medium in which they are prepared, to thereby eliminate or substantially avoid agglomeration between the polymer particles upon drying.

Claims

1. In a limited coalescence method of making polymer particles of controlled size, which method comprises forming an aqueous suspension of polymer droplets, such droplets being immiscible with the aqueous suspension medium and having a layer of particulate suspension stabilizer on their surfaces which limits coalescence between droplets, forming solid particles from the droplets and separating the polymer particles having a layer of particulate suspension stabilizer on their surfaces from the aqueous suspension medium, the improvement comprising (a) controlling the coalescence between the droplets to provide polymer particles having an average particle size of not more than 3 μ

m, (b) reslurry washing the separated polymer particles by dispersing them in an organic liquid diluent that is miscible with the aqueous suspension medium and is a nonsolvent for the polymer particles, and (c) separating the polymer particles from the diluent to thereby substantially avoid agglomeration between the polymer particles upon drying.

2. The method of claim 1, wherein the average particle size of the polymer particles is in the range of about 1 to 3 μ

m.

3. The method of claim 1, wherein the average particle size of the polymer particles is in the range of about 1 to 2 μ

m .

4. The method of claim 1, wherein the diluent has a molecular weight up to about 100.

5. The method of claim 1, wherein the diluent has a molecular weight less than 50.

6. The method of claim 4, wherein the diluent is an alkanol containing up to 4 carbon atoms.

7. The method of claim 6, wherein the alkanol is methanol.

8. The method of claim 1, wherein the particulate suspension stabilizer is an inorganic particulate stabilizer and the aqueous suspension medium comprises a promotor.

9. The method of claim 8, wherein the stabilizer is silica.

10. The method of claim 1, wherein the droplets are formed by polymerization of monomers within the droplets.

11. The method of claim 10, wherein the polymer formed within the droplets is a crosslinked polymer.

12. The method of claim 11, wherein the crosslinked polymer is a styrene polymer.

13. The method of claim 12, wherein the styrene polymer is crosslinked with divinylbenzene.

14. The method of claim 10, wherein potassium dichromate is present in the aqueous suspension as a polymerization inhibitor.

15. The method of claim 1, wherein the polymer droplets comprise polycondensation polymer.

16. The method of claim 15, wherein the polycondensation polymer is a polyester.