Process for converting polymers by contacting same with particulate material suspended in a toroidal shape

• US 5,354,930 A
• Filed: 06/11/1993
• Issued: 10/11/1994
• Est. Priority Date: 06/29/1992
• Status: Expired due to Fees

• Current Assignee: Torftech Limited (Mortimer Technology Holdings Ltd.)
• Original Assignee: BP Chemicals Ltd. (BP PLC)
• Inventors: Kidd, David A., Atkins, Martin P.
• Primary Examiner(s): PAL, ASOKKUMAR
• Application Number:
  US08/076,233
• Time in Patent Office: 487 Days
• Field of Search: 585/240, 585/241
• US Class Current: 585/241
• CPC Class Codes: C10G 1/10 from rubber or rubber waste

Abstract

This invention relates to a method of cracking polymers, especially waste hydrocarbon polymers to produce products of lower molecular weight. The process comprises feeding the polymer into a processing chamber or circular-cross section which chamber also has a bed of particulate material maintained in suspension and in toroidal shape by a hot gas introduced into said chamber so that the polymer intermingles with the particulate materials of the bed and is cracked into products of lower molecular weight. The invention is useful for converting polymeric wastes into products of commercial value such as e.g. waxes, lubricants and monomeric olefins at the same time reducing environmental pollution.

Claims

1. A process for the conversion of a polymer, especially hydrocarbon polymers, into products of lower molecular weight than the starting polymer, said process comprising:

a. generating in a processing chamber of circular cross-section in its vertical orientation a stream of hot gas which flows in an angular and upward direction causing

(i) a bed or particulate material to be entrained in the flow of the gas and held in suspension in a toroidal shape and

(ii) the polymer introduced into said chamber in turn to intermingle with the particulate material and assume said toroidal shape thereby cracking said polymer at a temperature in the range from 300-600°

C. into products of lower molecular weight and

(iii) recovering said products of lower molecular weight from said chamber.

2. A process according to claim 1 wherein the polymer is introduced into the reactor as strips, pellets, extrudates or as a melt.

3. A process according to claim 1 wherein the polymer is selected from polyethylene, polypropylene, polystyrene, PVC or polyethylene terephthalate.

4. A process according to claim 1 wherein the polymer is a waste polymer.

5. A process according to claim 1 wherein the bed of particulate material comprises catalytic materials, non-catalytic materials or mixtures thereof.

6. A process according to claim 1 wherein the bed of particulate material comprises one or more of a zeolite, clay or amorphous silica-alumina, silica, quartz, alumina, zirconia, incineration pellets and calcium oxide.

7. A process according to claim 1 wherein the hot gas is selected from hydrogen, nitrogen, steam, carbon dioxide, carbon monoxide, flue gases and mixtures thereof which are substantially free of oxygen.

8. A process according to claim 1 wherein the polymer is cracked at a temperature in the range from 300-600°

C.

9. A process according to claim 1 wherein the residence time of the polymer in the processing chamber is less than 10 seconds.

10. A process according to claim 1, wherein the polymer is cracked and uses a momentum of exchange between the gas and the polymer.

11. A process according to claim 10 wherein the flow of the gas is inverted and channelled through a series of baffles or blades converting the pressure head in the gas stream into a velocity head and lifting and transporting the bed or particulate material.