Hair color rinse composition containing haloginated fluorescein dyes

• US 5,356,438 A
• Filed: 01/07/1993
• Issued: 10/18/1994
• Est. Priority Date: 10/16/1992
• Status: Expired due to Fees

• Current Assignee: AmorePacific Group, Inc.
• Original Assignee: AmorePacific Group, Inc.
• Inventors: Cha, Jin K., Kang, Eung S., Kim, Chang K.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): LIOTT, CAROLINE L
• Application Number:
  US08/001,645
• Time in Patent Office: 649 Days
• Field of Search: 8/405, 8/429, 8/435, 8/581, 8/648, 424/70, 252/DIG. 13
• US Class Current: 8/405
• CPC Class Codes: A61K 8/498 having 6-membered rings or their condensed derivatives, e.g. coumarin
• CPC Class Codes: A61K 8/899 containing sulfur, e.g. sodium PG-propyldimethicone thiosulfate copolyol
• CPC Class Codes: A61Q 5/065 Preparations for temporary colouring the hair, e.g. direct dyes
• CPC Class Codes: A61Q 5/12 Preparations containing hair conditioners

Abstract

A hair color rinse composition that simultaneously dyes and conditions hair which comprises a tinctorial amount of one or more acidic dyes, from about 0.01 to 0.5 parts by weight based on the total weight of the composition of one or more halogenated fluorescein dyes and from about 1.0 to 20.0 parts by weight based on the total weight of the composition of a disodium dimethicone copolyol sulfosuccinate is disclosed.

Claims

1. A hair color rinse composition consisting essentially of:

(a) from about 0.01 to 2.0 parts by weight, based on the total weight of the composition, of at least one acid dye selected from the group consisting of FD&

C Red 2, FD&

C Red 3, C.I. 16255 Acid Red 18, C.I. 45100 Acid Red 52, FD&

C Yellow 5, FD&

C Yellow 6, FD&

C Green 3, FD&

C Blue 1, FD&

C Blue 2, D&

C Red 33, D&

C Green 5, D&

C Green 4, D&

C Blue 4, D&

C Orange 4, FD&

C Red 4, Ext. D&

C Violet 2 and D&

C Black 1;

(b) from about 0.01 to 0.5 parts by weight, based on the total weight of the composition, of at least one halogenated fluorescein dye of the formula;

##STR2## wherein, X, which may be the same or different, is a hydrogen atom or a halogen atom selected from the group consisting of chlorine, bromine and iodine, provided that at least two of the 4 X'"'"'s are halogen atoms,

Y, all of which are the same, is a hydrogen atom or a halogen atom selected from the group consisting of chlorine and bromine,

M is a hydrogen atom or a metal selected from the group consisting of Na and K; and

(c) from about 1.0 to 20.0 parts by weight, based on the total weight of the composition, of disodium dimethicone copolyol sulfosucinate having molecular weight of from 10,000 to 30,000.

2. The composition according to claim 1 in which the halogenated fluorescein dyes are selected from the group consisting of D&

C Red No. 28 of the chemical name Phloxine B, Disodium salt of 2,4,5,7-tetrabromo-9-(3,4,5,6-tetrachloro-o-carboxyphenyl)-6-hydroxy-3-isoxanthone], CI No. 45440 of the chemical name Rose bengal, Disodium salt of 9-(3,4,5,6-tetrachloro-o-carboxyphenyl-6-hydroxy-2,4,5,7-tetraiodo-3-isoxantlone], D&

C Red No. 19 of the chemical name Rhodamine, 3-Ethochloride of 9-o-carboxyphenyl-6-diethylamino-3-ethylamino-3-isoxanthene], D&

C Red No. 27 of the chemical name Tetrachlorotetrabromofluorescein, 2,4,5,7-Tetrabromo-12,13,14,15-tetrachloro-3,6-fluorandiol], D&

C Red No. 21 of the chemical name Tetrabromofluorescein, 2,4,5,7-Tetrabromo-3,6fluorandiol. D&

C Red No. 22 of the chemical name Eosine YS, Disodium salt of 2,4,5,7-Tetrabromo-9-o-carboxyphenyl-6-hydroxy-3-isoxanthone], D&

C Red No. 23 of the chemical name Eosine YSK, Dipotassium salt of 2,4,5,7-tetrabromo-9-o-carboxyphenyl-6-hydroxy-3-isoxanthone], C.I. 45410 Acid Red 92 of the chemical name Phloxine BK, Dipotassium salt of 2,4,5,7-tetrabromo-9-(3,4,5,6-tetrachloro-o-carboxyphenyl)-6-hydroxy-2,4,5,7-tetrachloro-3-isoxanthone], D&

C Orange No. 5 of the chemical name Dibromofluorescein, 4,5-Dibromo-3,6-fluorandiol. D&

C Orange No. 10 of the chemical name Diiodofluoresceine, 4,5-Diiodo-3,6-Fluorandiol, and D&

C Orange No. 11 of the chemical name Erythrosine Yellow NA, Disodium salt of 9-o-carboxyphenyl-6-hydroxy-4,5-diiodo-3-isoxanthone.

3. The composition according to claim 1 in which the pH of the composition is adjusted to 3.0 to 5.0.

4. A process for simultaneously dyeing and conditioning hair which comprises applying a hair color rinse to hair and allowing said composition to remain in contact with the hair for a time sufficient to impart color to the hair whereby the hair becomes more manageable and has a natural, even color, wherein said hair color rinse composition consists essentially of

(a) from about 0.01 to 2.0 parts by weight, based on the total weight of the composition, of at least one acid dye selected from the group consisting of FD&

C Red 2, FD&

C Red 3, C.I. 16255 Acid Red 18, C.I 45100 Acid Red 52, FD&

C Yellow 5, FD&

C Yellow 6, FD&

C Green 3, FD&

C Blue 1, FD&

C Blue 2, D&

C Red 33, D&

C Green 5, D&

C Green 4, D&

C Blue 4, D&

C Orange 4, FD&

C Red 4, Ext. D&

C Biolet 2 and D&

C Black 1;

(b) from about 0.01 to 0.5 parts by weight, based on the total weight of the composition, of at least one halogenated fluorescein dye of the formula;

##STR3## wherein, X, which may be the same or different, is a hydrogen atom or a halogen atom selected from the group consisting of chlorine, bromine and iodine, provided that at least two of the 4 X'"'"'s are halogen atoms,

Y, all of which are the same, is a hydrogen atom or a halogen atom selected from the group consisting of chlorine and bromine,

M is a hydrogen atom or a metal selected from the group consisting of Na and K; and

(c) from about 1.0 to 20.0 parts by weight, based on the total weight of the composition, of disodium dimethicone copolyol sulfosuccinate having molecular weight of from 10,000 to 30,000.