Oil-spill marking method and composition

• US 5,356,465 A
• Filed: 07/23/1993
• Issued: 10/18/1994
• Est. Priority Date: 07/23/1993
• Status: Expired due to Fees

• Current Assignee: The Midsungroup Incorporated
• Original Assignee: Midsun Group, Inc.
• Inventors: Eldridge, Kevin T.
• Primary Examiner(s): GREEN, ANTHONY J
• Application Number:
  US08/095,855
• Time in Patent Office: 452 Days
• Field of Search: 106/21 R, 106/21 A, 106/20 B, 503/214, 503/215, 436/56, 252/965
• US Class Current: 106/31.32
• CPC Class Codes: C09D 11/00 Inks
• CPC Class Codes: Y10S 252/965 Retrospective product identification, e.g. tags and tracers
• CPC Class Codes: Y10T 436/13 Tracers or tags

Abstract

A method for visibly marking an area contaminated with transformer oil or other organic liquid uses a marking composition that consists of a colorant held within a solid carrier material, the colorant being such as to effect a visibly perceptible change upon contact with the organic liquid. The carrier material may be an absorbent that permits delivery of the colorant through capillary action, or the colorant may be encapsulated by a cell-forming matrix material that interacts with the contaminating liquid to effect release.

Claims

1. A method for visibly marking an area contaminated with an organic liquid, comprising:

providing a marking composition comprised of a colorant held within a solid carrier material, said carrier material being interactive with an organic liquid for effecting direct contact between said organic liquid and said colorant; and

distributing said marking composition over an area suspected of contamination by said organic liquid, said colorant effecting a visibly perceptible change upon contact with said organic liquid.

2. The method of claim 1 wherein said colorant is oilsoluble, and is soluble in said organic liquid.

3. The method of claim 2 wherein said organic liquid is a dielectric mineral oil.

4. The method of claim 2 wherein said marking composition further comprises an oil vehicle, said colorant being dissolved in said oil vehicle to provide a colorant composition.

5. The method of claim 4 wherein said colorant composition contains about 5 to 25 percent of said colorant, based upon the weight of said colorant composition.

6. The method of claim 4 wherein said oil vehicle has a surface energy in the range 40 to 60 dynes/cm³.

7. The method of claim 4 wherein said colorant composition is held within said carrier material by means selected from the group consisting of absorption and encapsulation.

8. The method of claim 7 wherein said oil vehicle is of such composition that no more than 10 percent by weight of water is soluble therein.

9. The method of claim 7 wherein there is at least a 20 percent difference between the Pantone color value of said marking composition before and after contact occurs between said marking composition and said organic liquid.

10. The method of claim 9 wherein said Pantone color value of said marking composition is no more than about 10 percent of the Pantone color value of said colorant composition.

11. The method of claim 7 wherein said means by which said colorant composition is held constitutes absorption, and wherein the weight ratio of said carrier to said colorant composition in the range 25 to 60:

1.0.

12. The method of claim 7 wherein said colorant composition further includes a quantity of surfactant for promoting the affinity of said colorant for said organic liquid.

13. The method of claim 1 wherein said marking composition is in a finely divided dry form, and wherein said step of distributing is effected by means selected from the class consisting of mechanical, pneumatic and manual means.

14. The method of claim 1 wherein said marking composition is admixed with water in a weight ratio of water to marking composition in the range 1.0 to 3.0:

1.0, and wherein said step of distributing is effected by spraying the resultant admixture upon said area.

15. The method of claim 7 wherein said means by which said colorant composition is held constitutes microencapsulation, wherein said carrier is in the form of a matrix of cells having a diameter of at least about 60 microns, and wherein said oil vehicle is of such composition that no more than 2 percent by weight of water is soluble therein, said colorant composition being contained in said cells and the material of which said matrix is formed being hydrophobic and waterinsoluble.

16. The method of claim 7 wherein said means by which said colorant composition is held constitutes macroencapsulation, and wherein said carrier is in the form of a matrix of cells in which said colorant composition is contained, the material of which said matrix is formed being fusible at temperatures above ambient.

17. The method of claim 1 wherein said colorant is of such character that the perceptibility of said perceptible change is enhanced in response to radiation outside of the visible range, and wherein said method further comprises the step of exposing said area to radiation, outside of the visible range, to which said colorant is responsive.

18. The method of claim 17 wherein said radiation is in the ultraviolet spectral region.