Blends containing polystyrene-polyisoprene-polystyrene block copolymers and articles thereof

• US 5,358,783 A
• Filed: 12/17/1993
• Issued: 10/25/1994
• Est. Priority Date: 08/11/1989
• Status: Expired due to Term

• Current Assignee: TSRC (USA) Investment Corp.
• Original Assignee: The Dow Chemical Company (Dow, Inc.), Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: Diehl, Charles F., Tancrede, Jean M.
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): Clark, W. Robinson H.
• Application Number:
  US08/169,165
• Time in Patent Office: 312 Days
• Field of Search: 525/89, 525/95, 525/98, 428/500, 428/507, 428/511, 428/515, 428/344, 428/355
• US Class Current: 428/344
• CPC Class Codes: A61L 15/58 Adhesives
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: C08F 297/046 polymerising vinyl aromatic monomers and isoprene, optionally with other conjugated dienes
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C09J 153/02 Vinyl aromatic monomers and conjugated dienes
• CPC Class Codes: Y10T 428/2804 Next to metal
• CPC Class Codes: Y10T 428/2852 Adhesive compositions
• CPC Class Codes: Y10T 428/31895 Paper or wood
• CPC Class Codes: Y10T 428/31909 Next to second addition polymer from unsaturated monomers

Abstract

Blends of low styrene content polystyrene-polyisoprene-polystyrene block copolymer and high styrene content polystyrene-polyisoprene-polystyrene block copolymer can be used with tackifier resins, plasticizer oil and antioxidants to formulate pressure sensitive adhesives of improved cohesive strength vis-a-vis adhesives formed from the low styrene content polystyrene-polyisoprene-polystyrene block copolymer while maintaining good balance between tack, bonding characteristics and heat resistance.

Claims

1. A composition of matter which comprises a blend of A-B-A block copolymers, where the A component of each block copolymer of the blend is polystyrene and the B component is polyisoprene, said blend including:

A) a first A-B-A block copolymer having an overall number average molecular weight ranging from about 90,000 to about 250,000, wherein the polyisoprene has a number average molecular weight ranging from about 80,000 to about 225,000, the polystyrene block has a number average molecular weight ranging from about 8,000 to about 17,000 and the overall styrene content of the block copolymer ranges from about 10 percent to about 24 percent; and

B) a second A-B-A block copolymer having an overall number average molecular weight ranging from about 60,000 to about 110,000, wherein the polyisoprene has a number average molecular weight ranging from about 30,000 to about 70,000, the polystyrene block as a number average molecular weight ranging from about 12,000 to about 20,000, and the overall styrene content of the block copolymer ranges from about 25 percent to about 50 percent.

2. The composition of claim 1 wherein said first A-B-A block copolymer is of the formula:

(a) B-(AB)_n wherein n is greater than or equal to 2;

(b) A-(BA)_n wherein n is greater than or equal to 1;

or

(c) (AB)_n wherein n is greater than or equal to 2.

3. The composition of claim 1 wherein the overall styrene content of said first A-B-A block copolymer ranges from about 13 percent to about 19 percent.

4. The composition of claim 1 wherein the overall styrene content of said second A-B-A block copolymer ranges from about 28 to about 45 percent.

5. The composition of claim 3 wherein the overall styrene content of said second A-B-A block copolymer ranges from about 28 to about 45 percent.

6. The composition of claim 1 wherein the first A-B-A block copolymer has an overall number average molecular weight ranging from about 110,000 to about 170,000, the polyisoprene block of said first A-B-A block copolymer has a number average molecular weight ranging from about 90,000 to about 140,000, the polystyrene block has a number average molecular weight ranging from about 10,000 to about 14,000, and the overall styrene content of said first A-B-A block copolymer ranges from about 13 percent to about 19 percent.

7. The composition of claim 1 wherein the second A-B-A block copolymer has an overall number average molecular weight ranging from about 70,000 to about 100,000, the polyisoprene block of said second A-B-A block copolymer has a number average molecular weight ranging from about 40,000 to about 70,000, the polystyrene block has a number average molecular weight ranging from about 13,000 to about 19,000, and the overall styrene content of said second A-B-A block copolymer ranges from about 28 percent to about 45 percent.

8. The composition of claim 1 wherein the first A-B-A block copolymer has an overall number average molecular weight ranging from about 110,000 to about 170,000, the polyisoprene block of said first A-B-A block copolymer has a number average molecular weight ranging from about 90,000 to about 140,000, the polystyrene block has a number average molecular weight ranging from about 10,000 to about 14,000, and the overall styrene content of said first A-B-A block copolymer ranges from about 13 percent to about 19 percent;

and wherein the second A-B-A block copolymer has an overall number average molecular weight ranging from about 70,000 to about 100,000, the polyisoprene block of said second A-B-A block copolymer has a number average molecular weight ranging from about 40,000 to about 70,000, the polystyrene block has a number average molecular weight ranging from about 13,000 to about 19,000, and the overall styrene content of said second A-B-A block copolymer ranges from about 28 percent to about 45 percent.

9. The composition of claim 1 wherein the blend contains from about 40 parts to about 95 parts of the first A-B-A block copolymer, and from about 5 parts to about 60 parts of the second A-B-A block copolymer.

10. The composition of claim 9 wherein the blend contains from about 60 parts to about 80 parts of the first A-B-A block copolymer and from about 20 parts to about 40 parts of the second A-B-A block copolymer.

11. An article comprising a backing substrate having on at least one major surface thereof a layer of an adhesive composition which comprises a tackifying resin and the blend of A-B-A block copolymers of claim 1.

12. The article of claim 11 wherein the adhesive composition is mixed and coated upon the substrate as a hot melt mass.

13. The article of claim 11 wherein the adhesive composition is dissolved in a hydrocarbon solvent and applied to the substrate.

14. The article of claim 11 wherein the backing substrate is paper, cloth, film, metal foil or tape.

15. The article of claim 11 wherein the backing substrate is paper, plastic film or foam.

16. The article of claim 15 wherein the substrate is either a film selected from polyester, polypropylene and polyethylene or a foam selected from polyurethane and polystyrene.

17. The article of claim 13 wherein the backing substrate is paper, cloth, film, metal foil or tape.

18. The article of claim 16 wherein the substrate is paper, plastic film or foam.

19. The article of claim 11 wherein the backing substrate is tape.

20. An article comprising a backing substrate having on both sides of the substrate an adhesive composition which comprises a tackifying resin and the blend of A-B-A block copolymer of claim 1.