Biofoam II

• US 5,360,828 A
• Filed: 03/21/1994
• Issued: 11/01/1994
• Est. Priority Date: 04/06/1993
• Status: Expired due to Fees

• Current Assignee: Regents of the University of California (University of California)
• Original Assignee: Regents of the University of California (University of California)
• Inventors: Morrison, Robert L.
• Primary Examiner(s): Foelak, Morton
• Application Number:
  US08/215,159
• Time in Patent Office: 225 Days
• Field of Search: 521/64, 521/61, 106/122, 106/124, 106/125, 106/126, 106/129, 106/133, 106/205, 106/207, 106/218
• US Class Current: 521/64
• CPC Class Codes: C08J 2201/048 Elimination of a frozen liquid phase
• CPC Class Codes: C08J 2201/054 Precipitating the polymer by adding a non-solvent or a different solvent
• CPC Class Codes: C08J 2305/00 Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2301/00 or C08J2303/00
• CPC Class Codes: C08J 2389/00 Characterised by the use of proteins; Derivatives thereof
• CPC Class Codes: C08J 9/0085 Use of fibrous compounding ingredients C08J9/0076 takes precedence
• CPC Class Codes: C08J 9/28 by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum

Abstract

Biofoam is a rigid, microcellular organic foam made from organic materials derived from natural products and biological organisms. Starting materials include agar, agarose, gelatin, algin, alginates, gellan gum, and microcrystalline cellulose. The organic material is dissolved in a polar solvent, typically water, and the mixture is gelled. The water in the gel pores is replaced at least once with another solvent to reduce the pore size of the final biofoam. The solvent in the gel pores may be replaced several times. After the final replacement of solvent, the gel is frozen and freeze-dried to form a biofoam. Translucent biofoams are formed by selecting a final solvent that forms very small crystals. A variety of crystalline, fibrous, amorphous, or metallic additives may be incorporated into the foam structure to produce lightweight composite materials with enhanced strength and insulating properties.

Claims

1. A method for forming a rigid, microcellular biofoam, comprising:

(a) dissolving a naturally occurring organic material in a primary solvent to form a mixture;

(b) forming a gel from the mixture, where the pores in the gel are occupied by the primary solvent;

(c) replacing the primary solvent with a second solvent;

(d) freezing the gel; and

(e) drying the gel to form an organic biofoam.

2. A method for forming a biofoam as recited in claim 1, wherein the naturally occurring organic material comprises at least one of agars, agarose, algins, alginates, gums, resins, gum resins, and gelatins.

3. A method for forming a biofoam as recited in claim 1, wherein the primary solvent comprises a polar solvent.

4. A method for forming a biofoam as recited in claim 1, wherein the primary solvent is selected from the group consisting of ketones, ethers, alcohols, aldehydes, amines, water, and mixtures thereof.

5. A method for forming a biofoam as recited in claim 1, wherein the primary solvent comprises water and the second solvent is selected from the group consisting of ketones, ethers, alcohols, aldehydes, amines, and mixtures thereof.

6. A method for forming a biofoam as recited in claim 1, further comprising the step of replacing the second solvent with a third solvent before freezing the gel.

7. A method for forming a biofoam as recited in claim 6, wherein the second solvent is soluble in the first and third solvents.

8. A method for forming a biofoam as recited in claim 6, wherein the third solvent comprises a nonpolar solvent.

9. A method for forming a biofoam as recited in claim 6, wherein the third solvent is selected from the group consisting of nonpolar hydrocarbons and nonpolar aromatics.

10. A method for forming a biofoam as recited in claim 9, wherein the third solvent is selected from the group consisting of 1,4-dimethylbenzene, cyclohexane, hexadecane, naphthalene, freons, and mixtures thereof.

11. A method for forming a biofoam as recited in claim 10, wherein the primary solvent comprises water, the second solvent comprises an alcohol, and the third solvent comprises 1,4-dimethylbenzene and cyclohexane.

12. A method for forming a biofoam as recited in claim 1, wherein the drying step is carried out by freeze-drying.

13. A method for forming a biofoam as recited in claim 1, wherein the drying step is carried out by evaporation.

14. A method for forming a biofoam as recited in claim 1, further comprising the step of adding an additive to the mixture before forming the gel to produce a composite biofoam material.

15. A method for forming a biofoam as recited in claim 14, wherein the additive is selected from the group consisting of fibers, carbon powder, and metal powders.

16. A method for forming a biofoam as recited in claim 14, wherein the additive is selected from the group consisting of graphite fibers, microcrystalline cellulose, sawdust, amadine fibers, cotton fibers, polyester fibers, fiberglass, alkali tetratitanate, metal powders, and carbon powder.