Fiber marker including an erasable ink

• US 5,362,167 A
• Filed: 01/29/1993
• Issued: 11/08/1994
• Est. Priority Date: 12/18/1991
• Status: Expired due to Term

• Current Assignee: Berol Corp (Newell Brands Inc.)
• Original Assignee: Gillette Company (The Procter & Gamble Company)
• Inventors: Loftin, Rachel M.
• Primary Examiner(s): DeMille, Danton D.
• Application Number:
  US08/012,967
• Time in Patent Office: 648 Days
• Field of Search: 523/161, 524/836, 524/88, 401/199, 401/198, 401/196
• US Class Current: 401/198
• CPC Class Codes: C09D 109/08 Latex
• CPC Class Codes: C09D 11/16 Writing inks
• CPC Class Codes: Y10T 428/249995 Constituent is in liquid form
• CPC Class Codes: Y10T 428/249996 Ink in pores

Abstract

An aqueous-based erasable ink composition suitable for use in highlighters and other writing instruments includes a styrene-butadiene copolymer and a water-insoluble pigment. It preferably also includes a release agent and an anti-oxidant, and has a viscosity of between 10cps and 30cps.

Claims

1. A method of providing an erasable marking on paper comprising

providing a marker comprising an outer body;

a porous writing tip at one end of said body;

a fiber reservoir included within said body and connected to said porous writing tip; and

within said porous writing tip and said fiber reservoir an aqueous-based, non-shear thinning erasable ink having a viscosity of between 10cps and 30cps and comprising water, a water-insoluble colorant, and a latex, said latex having a viscosity of less than about 50cps and including a styrene/butadiene copolymer having a styrene content of less than 35%; and

contacting said porous writing tip with a paper substrate to transfer said ink from said porous writing tip to said paper substrate to provide an erasable marking, wherein during said contacting said ink is delivered from said fiber reservoir to said porous writing tip via capillary action.

2. The method of claim 1, further comprising the step of erasing said erasable marking from said paper substrate.

3. The method of claim 1, wherein said ink has a viscosity of between 10cps and 20cps.

4. The marker of claim 1, wherein said latex comprises a styrene-butadiene copolymer.

5. The marker of claim 1, wherein said ink further comprises an antioxidant.

6. The marker of claim 1, wherein said ink further comprises a release agent.

7. The marker of claim 1, wherein said ink further comprises a fluorescent pigment.

8. A marker comprising an outer body;

a porous writing tip at one end of said body;

a fiber reservoir included within said body and connected to said writing tip; and

within said reservoir an aqueous-based, non-shear thinning ink that is erasable from 60 lb. offset printing paper, said ink having a viscosity of between 10cps and 30cps and comprising a water-insoluble colorant and a latex, said latex having a viscosity of less than about 50cps and including a styrene/butadiene copolymer having a styrene content of less than 35%;

wherein when said writing tip is contacted with 60 lb. offset printing paper to mark said paper said ink is delivered from said reservoir to said tip by capillary action.

9. The marker of claim 8, wherein said ink has a viscosity of between 10cps and 20cps.

10. The marker of claim 8, wherein said latex comprises a styrene-butadiene copolymer.

11. The marker of claim 8, wherein said ink further comprises an antioxidant.

12. The marker of claim 8, wherein said ink further comprises a release agent.

13. The marker of claim 8, wherein said ink further comprises a fluorescent pigment.

14. A method of providing an erasable marking on a paper substrate comprising

providing a marker comprising an outer body;

a porous writing tip at one end of said body;

a fiber reservoir included within said body and connected to said porous writing tip; and

within said porous writing tip and said fiber reservoir an aqueous-based, non-shear thinning erasable ink having a viscosity of between 10cps and 30cps and comprising water, a water-insoluble colorant, and a latex emulsion, said latex emulsion having a viscosity of less than about 50cps and including a styrene/butadiene copolymer having a styrene content of less than 35%; and

contacting said porous writing tip with a paper substrate to transfer said ink from said porous writing tip to said paper substrate to provide an erasable marking, wherein during said ink is delivered from said fiber reservoir to said porous writing tip via capillary action when said porous writing tip contacts said paper substrate.

15. The method of claim 14, further comprising the step of erasing said erasable marking from said paper substrate.

16. The method of claim 14 wherein said ink has a solids content of less than 50%.

17. The method of claim 14 wherein said latex has a viscosity of less than 50cps.

18. The method of claim 17 wherein said latex has a solids content of less than 50%.

19. The method of claim 16 wherein said latex has a viscosity of less than 50cps and comprises a styrene-butadiene copolymer having a styrene:

butadiene ratio of between 10;

90 and 35;

65.

20. The method of claim 18 wherein said copolymer has a Mooney value of at least 90.

21. The method of claim 14 wherein said ink further comprises a silicone release agent.

22. The method of claim 14 wherein said ink further comprises an anti-oxidant.

23. The method of claim 22 wherein said anti-oxidant is a cresol.

24. The method of claim 14 wherein said colorant is a fluorescent pigment.

25. A marker comprising an outer body;

a writing tip at one end of said body;

a fiber reservoir included within said body and connected to said writing tip; and

within said reservoir an aqueous-based non-shear thinning ink that is erasable from 60 lb. offset printing paper, said ink having a viscosity of between 10cps and 30cps and comprising water, a water-insoluble colorant, and a latex emulsion, said latex emulsion having a viscosity of less than about 50cps and including a styrene/butadiene copolymer having a styrene content of less than 35%;

wherein said tip is porous and said ink is delivered from said fiber reservoir to said tip by capillary action.

26. The marker of claim 25 wherein the viscosity of said ink composition is between 10cps and 20cps.

27. The marker of claim 25 wherein said latex has a rubber solid content of between 20% and 40%.

28. The marker of claim 25 wherein said ink includes between 60% and 90% of said latex by weight.

29. The marker of claim 25 wherein the viscosity of said latex emulsion is less than 50cps.

30. The marker of claim 25 wherein said latex comprises a styrene-butadiene copolymer.

31. The marker of claim 30 wherein said styrene-butadiene copolymer has a Mooney value of at least 90.

32. The marker of claim 30 wherein said copolymer has a styrene:

butadiene ratio of between 10;

90 and 35;

65.

33. The marker of claim 25 wherein said ink includes a release agent.

34. The marker of claim 33 wherein said release agent is a silicone.

35. The marker of claim 25 wherein said ink includes an anti-oxidant.

36. The marker of claim 35 wherein said anti-oxidant is a cresol.

37. The marker of claim 35 wherein said colorant is a fluorescent pigment.

38. The marker of claim 29 wherein said latex has a solids content of less than 50%.

39. The marker of claim 38 wherein said latex comprises styrene-butadiene copolymer having a styrene:

butadiene ratio of between 10;

90 and 35;

65.

40. The marker of claim 39 wherein said marking composition further comprises a fluorescent pigment.

41. The marker of claim 25 wherein said latex has a solids content of less than 50%.

42. The marker of claim 38 wherein said marking composition further comprises a silicone release agent.