Process for producing carbon dioxide clathrate

• US 5,362,467 A
• Filed: 11/24/1992
• Issued: 11/08/1994
• Est. Priority Date: 12/02/1991
• Status: Expired due to Fees

• Current Assignee: Chubu Electric Power Company Incorporated, Mitsubishi Jukogyo Kabushiki Kaisha (Mitsubishi Heavy Industries, Ltd.)
• Original Assignee: Chubu Electric Power Company Incorporated, Mitsubishi Jukogyo Kabushiki Kaisha (Mitsubishi Heavy Industries, Ltd.)
• Inventors: Ishibashi, Masaru, Saji, Akira, Kitamura, Hikaru, Sakai, Matsushige, Kamata, Toshihiro, Murakami, Takefumi, Hondoh, Takeo, Noda, Hidetomo, Kawata, Yutaka, Negoro, Masaaki, Tanii, Tadaaki
• Primary Examiner(s): Straub, Gary P.
• Assistant Examiner(s): Vanoy, Timothy C.
• Application Number:
  US07/981,328
• Time in Patent Office: 714 Days
• Field of Search: 23/295 R, 423/220, 423/415 R, 423/437 R, 423/415.2, 423/415.1, 55/82, 62/71, 62/73, 62/352, 62/532, 588/261, 95/290, 422/245
• US Class Current: 423/437.1
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01J 3/04 Pressure vessels, e.g. autoclaves
• CPC Class Codes: C01B 32/50 Carbon dioxide
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02P 20/151 Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

A carbon dioxide clathrate having a lump diameter enough to precipitate on a desired abyssal position of the sea without being drifted by a seawater flow of the abyss can be produced by bringing an aqueous solution into contact with carbon dioxide with the interposition of an interface in a reactor and retaining this contact; adjusting the pressure in the reactor to 13 atm or more, the temperature of the aqueous solution to a level of more than 5° C. to 10° C., the temperature of the interface to a level of more than 10° C. to 15° C. and the temperature of a lug inserted into the aqueous solution to a level of more than 0° C. to 5° C.; producing/growing the carbon dioxide clathrate on the lug; and then heating the lug to a temperature of more than 10° C. to 30° C. to separate/drop the carbon dioxide clathrate therefrom.

Claims

1. A process for producing a carbon dioxide clathrate which comprises:

the step of disposing a water portion comprising an aqueous solution of water or seawater and a carbon dioxide portion comprising carbon dioxide in a reactor so that these portions may come in contact with each other with the interposition of an interface, and positioning, in the water portion, a lug of which the temperature is controllable;

the step of adjusting the pressure in the reactor to 13 atm or more and the temperature of the aqueous solution in the water portion to a level of more than 5°

C. and not greater than 10°

C., and adjusting an interface temperature between the water portion and the carbon dioxide portion to a level of more than 10°

C. and not greater than 15°

C.;

the step of maintaining the temperature of the lug at a level of more than 0°

C. and not greater than 5°

C. to form, away from said interface, crystallized carbon dioxide clathrate on the lug; and

the step of heating the lug to a temperature of more than 10°

C. and not greater than 30°

C. to separate and drop the crystallized carbon dioxide clathrate from the lug.

2. The process according to claim 1 wherein the step of forming the crystallized carbon dioxide clathrate on the lug and the step of separating and dropping the crystallized carbon dioxide clathrate from the lug are alternately repeated plural times.

3. A process of producing a carbon dioxide clathrate which comprises:

the step of disposing a water portion comprising an aqueous solution of water or seawater and a carbon dioxide portion comprising carbon dioxide in a reactor so that these portions may come in contact with each other with the interposition of an interface;

the step of adjusting the pressure in the reactor to 13 atm or more and the temperature of the aqueous solution in the water portion to a level of more than 5°

C. and not greater than 10°

C., and adjusting an interface temperature between the water portion and the carbon dioxide portion to a level of more than 10°

C. and not greater than 15°

C.;

the step of positioning, in the water portion, a lug of which the temperature is controllable;

the step of maintaining the temperature of the lug at a level of more than 0°

C. and not greater than 5°

C. to form, away from said interface, crystallized carbon dioxide clathrate on the lug; and

the step of heating the lug to a temperature of more than 10°

C. and not greater than 30°

C. to separate and drop the crystallized carbon dioxide clathrate from the lug.

4. The process according to claim 3 wherein the step of forming the crystallized carbon dioxide clathrate on the lug and the step of separating and dropping the crystallized carbon dioxide clathrate from the lug are alternately repeated plural times.

5. An apparatus for producing a carbon dioxide clathrate, said apparatus comprising:

a reactor means, including a water portion comprising an aqueous solution of water or seawater and a carbon dioxide portion comprising carbon dioxide, for contacting said portions at an interface,

a temperature controlled lug disposed in said water portion of said reactor means away from said interface;

means for adjusting the pressure in the reactor means to 13 atm or more and the temperature of the aqueous solution in the water portion to a level of more than 5°

C. and not greater than 10°

C., and for adjusting an interface temperature between the water portion and the carbon dioxide portion to a level of more than 10°

C. and not greater than 15°

C.; and

means for maintaining the temperature of the lug at a level of more than 0°

C. and not greater than 5°

C. for a period of time to form thereby forming crystallized carbon dioxide clathrate on the lug and for heating the lug to a temperature of more than 10°

C. and not greater than 30°

C. to separate and drop the crystallized carbon dioxide clathrate from the lug.

6. The apparatus according to claim 5 wherein means for maintaining the temperature of said lug thereby forming the crystallized carbon dioxide clathrate on the lug and heating the lug thereby dropping the crystallized carbon dioxide clathrate from the lug, comprises a means for alternately heating and cooling said lug a repeated plurality of times.