Visible-spectrum anti-reflection coating including electrically-conductive metal oxide layers

• US 5,362,552 A
• Filed: 09/23/1993
• Issued: 11/08/1994
• Est. Priority Date: 09/23/1993
• Status: Expired due to Fees

• Current Assignee: Photran Corporation
• Original Assignee: Photran Corporation
• Inventors: Austin, R. Russel
• Primary Examiner(s): Robinson, Ellis P.
• Assistant Examiner(s): Speer, Timothy M.
• Application Number:
  US08/126,128
• Time in Patent Office: 411 Days
• Field of Search: 428/216, 428/432, 428/698, 428/701, 428/913, 428/, 428/336, 428/426, 428/702, 359/359, 359/360, 359/588, 359/586, 359/580, 359/589
• US Class Current: 428/216
• CPC Class Codes: B32B 17/06 comprising glass as the main or only constituent of a layer, next to another layer of a specific material
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: G02B 1/116 including electrically conducting layers
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

A six-layer anti-reflection coating (20 and 20A) includes three layers (24, 28, and 34) which may be formed from an electrically-conductive metal oxide having a refractive index between about 1.9 and 2.1 at a wavelength of 520 nanometers. Up to a total optical thickness of about one-wavelength of visible light of the electrically-conductive metal oxide may be included in the coating, while still providing less than 0.25 percent photopic reflection.

Claims

1. An antireflection coating for a substrate, comprising:

six-layers designated the first through the sixth in consecutive numerical order beginning with the layer furthest from the substrate, each of said layers having a physical thickness of at least about 9.0 nanometers, each of said layers having an extinction coefficient less than 0.1 for visible light and wherein one or more of said layers is formed of an electrically-conductive metal oxide which is transparent to visible light;

said first layer having a refractive index between about 1.46 and 1.52 at a wavelength of about 520 nm and having an optical thickness of about one-quarter wavelength of visible light;

said sixth layer having a refractive index greater than the refractive index of the substrate;

said fifth layer having a refractive index less than the refractive index of said sixth layer;

said fifth and sixth layers having a combined optical thickness between about one-tenth and one-quarter wavelength of visible light;

said third layer having a refractive index greater than about 2.15 at a wavelength of about 520 nanometers;

said second layer having a refractive index less than the refractive index of said third layer and greater than the refractive index of said first layer;

said fourth layer having a refractive index less than the refractive index of said third layer and greater than the refractive index of said fifth layer; and

said second, third, and fourth layers having a combined optical thickness between about one-half wavelength and one wavelength of visible light.

2. The coating of claim 1, wherein at least one of said second and fourth layers is formed from a transparent electrically-conductive metal oxide selected from the group consisting of aluminum-doped zinc oxide, tin oxide, indium oxide, indium tin oxide, cadmium tin oxide, antimony- doped tin oxide, and fluorine-doped tin oxide.

3. The coating of claim 2, wherein the second and fourth layers are formed from indium tin oxide.

4. The coating of claim 3, wherein the combined optical thickness of said second, third, and fourth layers is about one half-wavelength and said fourth layer is thicker than said second layer.

5. The coating of claim 4, wherein said third layer has an optical thickness less than one-quarter wavelength.

6. The coating of claim 4, wherein said first and fifth layers are formed from silicon dioxide.

7. The coating of claim 6, wherein said third layer has a refractive index of about 2.35 at a wavelength of about 520 nanometers.

8. The coating of claim 6, wherein said third layer has a refractive index between about 2.15 and 2.25 at a wavelength of about 520 nanometers.

9. The coating of claim 3, wherein said sixth layer is formed from indium tin oxide.

10. The coating of claim 2, wherein the combined optical thickness of said second third and fourth layers is about one-wavelength of visible light and said second layer is thicker than said fourth layer.

11. The coating of claim 1, wherein said second fourth and sixth layers each has a refractive index between about 1.9 and 2.1 at a wavelength of about 520 nanometers.

12. An antireflection coating for a substrate, comprising:

six-layers designated the first through the sixth in consecutive numerical order beginning with the layer furthest from the substrate, each of said layers having a physical thickness of at least about 9.0 nanometers, each of said layers having an extinction coefficient less than 0.1 for visible light and wherein one or more of said layers is formed of an electrically-conductive metal oxide which is transparent to visible light;

;

said first layer formed from silicon dioxide and having an optical thickness of about one-quarter wavelength of visible light;

said sixth layer having a refractive index greater than the refractive index of the substrate;

said fifth layer having a refractive index less than the refractive index of said fourth and sixth layers;

said fifth and sixth layers having a combined optical thickness between about one-tenth and one-quarter wavelength of visible light;

said third layer having a refractive index greater than about 2.1 at a wavelength of about 520 nanometers;

said second and fourth layers having a refractive index between about 1.9 and 2.1 at a wavelength of about 520 nanometers; and

said second, third and fourth layers having a combined optical thickness between about one-half wavelength and one wavelength of visible light.

13. The coating of claim 12, wherein at least one of said second, fourth, and sixth layers is formed from an electrically-conductive metal oxide selected from the group consisting of aluminum-doped zinc oxide, tin oxide, indium oxide, indium tin oxide, cadmium tin oxide, antimony-doped tin oxide, and fluorine-doped tin oxide.

14. The coating of claim 13, wherein each of said second, fourth, and sixth layers is formed from electrically-conductive indium tin oxide.

15. The coating of claim 14, wherein said fifth layer is formed from silicon dioxide.