Crimped acrylic fibers having improved thixotropic performance

• US 5,362,562 A
• Filed: 03/12/1993
• Issued: 11/08/1994
• Est. Priority Date: 03/12/1993
• Status: Expired due to Fees

• Current Assignee: Sterling Chemicals Incorporated (Eastman Chemical Company)
• Original Assignee: Cytec Technology Corp.
• Inventors: Evans, Robert E., Kaminski, Stanley S., Maranci, Arutun
• Primary Examiner(s): Zitomer, Fred
• Application Number:
  US08/030,953
• Time in Patent Office: 606 Days
• Field of Search: 428/369, 428/401
• US Class Current: 428/369
• CPC Class Codes: C08J 5/04 Reinforcing macromolecular compounds with loose or coherent fibrous material
• CPC Class Codes: C09K 2200/0239 Oxides, hydroxides, carbonates
• CPC Class Codes: C09K 2200/0447 Fats, fatty oils, higher fatty acids or derivatives thereof
• CPC Class Codes: C09K 2200/0682 Containing sulfur
• CPC Class Codes: C09K 3/1028 Fibres
• CPC Class Codes: D01F 6/18 from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
• CPC Class Codes: Y10T 428/2904 Staple length fiber
• CPC Class Codes: Y10T 428/2922 Nonlinear [e.g., crimped, coiled, etc.]
• CPC Class Codes: Y10T 428/2967 Synthetic resin or polymer
• CPC Class Codes: Y10T 428/2973 Particular cross section
• CPC Class Codes: Y10T 428/298 Physical dimension

Abstract

Crimped acrylic fibers with a small diameter, a minimum aspect ratio in the 20-50 range, and having a crimp of greater than about 10% so as to enhance the viscosity of polymers, resistance to gravity-induced slumping when applied to vertical surfaces, and mix stability, as well as provide matrix reinforcement and toughness, are adapted to act as improved physical thixotropes in adhesives, sealants, coatings, paints, grouts, building materials and the like.

Claims

1. A physical thixotrope comprising crimped acrylic fibers having a maximum diameter of less than 100 micrometers, a minimum length in the range of 0.5-3 mm, a minimum aspect ratio (L/D) in the 20-50 range and a crimp of greater than 3%.

2. Crimped acrylic fibers as defined in claim 1 which are non-fibrillated.

3. Crimped acrylic fibers as defined in claim 1 which are fibrillated.

4. Crimped acrylic fibers as defined in claim 1 comprised of a polymer containing acrylonitrile in a quantity more than 35 wt%.

5. Crimped acrylic fibers as defined in claim 1 comprised of a polymer containing acrylonitrile in a quantity more than 85 wt %.

6. Crimped acrylic fibers as defined in claim 1 which have a uniform length.

7. Crimped acrylic fibers as defined in claim 1 which comprise a mixture of lengths.

8. Crimped acrylic fibers as defined in claim 1 having an average diameter in the range of about 2-15 micrometers, and having a crimp of greater than 5%.

9. Crimped acrylic fibers as defined in claim 8 having an average diameter in the range of up to about 8 micrometers, and having a crimp of greater than 10%.

10. Crimped acrylic fibers as defined in claim 1 having an aspect ratio (L/D) of greater than about 100.

11. Crimped acrylic fibers as defined in claim 1 having a modulus of greater than about 0.8 msi.

12. Crimped acrylic fibers as defined in claim 1 having a molecular weight of greater than about 100,000 (M_K).

13. Crimped acrylic fibers as defined in claim 1 having a finished surface.

14. Crimped acrylic fibers as defined in claim 1 having a cross-section which is non-round.

15. Crimped acrylic fibers as defined in claim 1 which are pre-oxidized and thermally-stable.

16. A thixotropic agent produced from crimped monocomponent or bicomponent fibers of a polymer containing acrylonitrile in a quantity more than 35 wt %, said fibers having a fiber diameter less than 100 micrometers, a fiber length greater than 0.5 mm, a minimum aspect ratio in the range of 20-50, and being crimped to greater than about 5% so as

(i) to provide improved viscosity to a matrix polymer,

(ii) to provide a composite of a polymer and said thixotropic agent having greater resistance to slumping than the resistance to slumping of a composite comprising said polymer and a thixotropic agent comprising the corresponding uncrimped, non-texturized fibers, and

(iii) to provide a composite having a greater resistance to fiber-matrix separation or dewetting.

17. A thixotropic agent as defined in claim 16, wherein said crimped acrylic fibers are comprised of a polymer containing acrylonitrile in a quantity of more than 85 wt %.

18. A thixotropic agent as defined in claim 16, wherein said crimped acrylic fibers have a uniform length.

19. A thixotropic agent as defined in claim 16, wherein said crimped acrylic fibers comprise a mixture of lengths.

20. A thixotropic agent as defined in claim 16, wherein said crimped acrylic fibers have an average diameter in the range of about 2-15 micrometers, and have a crimp of greater than 10%.

21. A thixotropic agent as defined in claim 20, wherein said crimped acrylic fibers have an average diameter in the range of up to about 8 micrometers, and have a crimp of greater than 20%.

22. A thixotropic agent as defined in claim 16, wherein said crimped acrylic fibers have an aspect ratio (L/D) of greater than about 100.

23. A thixotropic agent as defined in claim 16, wherein said crimped acrylic fibers have an average diameter in the range of about 5-15 micrometers, and have a crimp of greater than 10%.