Method for liquefying natural gas

• US 5,363,655 A
• Filed: 03/08/1993
• Issued: 11/15/1994
• Est. Priority Date: 11/20/1992
• Status: Expired due to Fees

• Current Assignee: Chiyoda Corporation (Mitsubishi Corporation)
• Original Assignee: Chiyoda Corporation (Mitsubishi Corporation)
• Inventors: Nakamura, Moritaka, Sakaguchi, Junichi, Yamamoto, Osamu, Kikkawa, Yoshitsugi
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US08/028,025
• Time in Patent Office: 617 Days
• Field of Search: 62/9, 62/23, 62/39
• US Class Current: 62/613
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/0035 by gas expansion with extraction of work
• CPC Class Codes: F25J 1/0037 of a return stream
• CPC Class Codes: F25J 1/004 by flash gas recovery F25J1/0267 takes precedence
• CPC Class Codes: F25J 1/0055 originating from an incorporated cascade
• CPC Class Codes: F25J 1/0219 in combination with an internal quasi-closed refrigeration loop, e.g. using a deep flash recycle loop
• CPC Class Codes: F25J 1/0231 for the working-up of the hydrocarbon feed, e.g. reinjection of heavier hydrocarbons into the liquefied gas
• CPC Class Codes: F25J 1/0278 Unit being stationary, e.g. on floating barge or fixed platform
• CPC Class Codes: F25J 1/0285 Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings
• CPC Class Codes: F25J 1/0288 using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
• CPC Class Codes: F25J 1/0291 Refrigerant compression by combined gas compression and liquid pumping
• CPC Class Codes: F25J 1/0294 Multiple compressor casings/strings in parallel, e.g. split arrangement
• CPC Class Codes: F25J 2205/02 using simple phase separation in a vessel or drum
• CPC Class Codes: F25J 2210/06 Splitting of the feed stream, e.g. for treating or cooling in different ways
• CPC Class Codes: F25J 2220/62 Separating low boiling components, e.g. He, H2, N2, Air
• CPC Class Codes: F25J 2220/64 Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general
• CPC Class Codes: F25J 2230/60 the fluid being hydrocarbons or a mixture of hydrocarbons
• CPC Class Codes: F25J 2235/60 the fluid being (a mixture of) hydrocarbons
• CPC Class Codes: F25J 2240/40 Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval

Abstract

Provided is a method for liquefying natural gas which can be readily adapted to LNG plants of all sizes without requiring expensive and special heat exchangers. The liquefaction of feed gas of natural gas and recycle natural gas is carried out with a single-component refrigerant or a mixed refrigerant in a high temperature stage, and with a substantially isentropic expansion in a low temperature stage, and a non-liquefied part of the recycle gas after the expansion step is pressurized with a compressor and recycled along with a recycle stream of non-liquefied par of the feed natural gas, the liquefied part by the refrigerant exchanging heat with the non-liquefied part stream produced from the substantially isentropic expansion, in a plate-fin heat exchanger or the like. The compressor is driven by the power obtained by the substantially isentropic expansion.

Claims

1. A method for liquefying natural gas, comprising the steps of:

cooling feed natural gas with a refrigerant in a first feed gas stage to produce liquefied and non-liquefied parts of said feed natural gas;

cooling the non-liquefied part of said feed natural gas with a substantially isentropic expansion in a second feed gas stage to produce liquefied and non-liquefied parts of said feed natural gas;

pressurizing and recycling the non-liquefied part of said feed natural gas from said second feed gas stage by using a first compressor to produce a recycle natural gas;

cooling the recycle natural gas with a refrigerant in a first recycle gas stage to produce liquefied and non-liquefied parts of said recycle natural gas;

cooling the non-liquefied part of said recycle natural gas from said first recycle gas stage with a substantially isentropic expansion in a second recycle gas stage to produce liquefied and non-liquefied parts of said recycle natural gas; and

recovering the liquefied parts of said feed natural gas and said recycle natural gas;

said first compressor being driven at least partly by power obtained by at least one of said substantially isentropic expansion steps.

2. A method according to claim 1, wherein said cooling steps using a refrigerant comprise the use of a common plate-fin heat exchanger.

3. A method according to claim 1 further comprising the step of exchanging heat between the liquefied part of said feed natural gas from said first feed gas stage and the non-liquefied part of said feed natural gas from said second feed gas stage.

4. A method according to claim 1 further comprising the step of exchanging heat between the liquefied part of said recycle natural gas from said first recycle gas stage and the non-liquefied part of said recycle natural gas from said second recycle gas stage.

5. A method according to claim 1, wherein said first feed gas stage and said first recycle gas stage each comprise a stage for cooling the natural gas from a start temperature to an intermediate temperature lower than said start temperature;

and

said second feed gas stage and said second recycle gas stage each comprise a stage for cooling the natural gas from said intermediate temperature to a final temperature at which the natural gas is liquefied.

6. A method according to claim 1, further comprising the steps of pressurizing and recycling the non-liquefied part of said recycle natural gas from said second recycle gas stage by using a second compressor.

7. A method according to claim 6, wherein said second compressor is driven at least partly by power obtained by at least one of said substantially isentropic expansion steps.

8. A method according to claim 6, wherein said first and second compressors comprise a common compressor.

9. A method according to claim 8, wherein said substantial isentropic expansion for said feed natural gas and said recycle natural gas is carried out in a common turbo expander.

10. A method according to claim 8, wherein said substantial isentropic expansion for said feed natural gas and said recycle natural gas is carried out in two separate turbo expanders.

11. A method according to claim 1, wherein the refrigerant is a mixed refrigerant having the composition (mol %):

space="preserve" listing-type="tabular">______________________________________ N.sub.2 0-10 C.sub.1 7-60 C.sub.2 25-80 C.sub.3 3-20 C.sub.4 7-30 C.sub.5 7-30 ______________________________________

said method further comprising the steps of;

circulating said mixed refrigerant in a closed loop with a compressor to produce a pressurized refrigerant;

partly liquefying said pressurized refrigerant with an after-cooler;

separating the partly liquefied refrigerant with a separation drum to produce a gas refrigerant fraction and a first liquid refrigerant fraction;

passing said gas and said first liquid refrigerant fractions in separate paths of a heat exchanger cooled by a low-temperature, low-pressure mixed refrigerant, and thereby liquefying said gas refrigerant fraction to produce a second liquid refrigerant fraction;

passing said second liquid refrigerant fraction through an expansion valve or an expansion drum so as to convert said second liquid refrigerant fraction into a low-temperature, low-pressure mixed refrigerant;

passing said low-temperature, low-pressure mixed refrigerant through said heat exchanger in a direction opposite to that of said gas refrigerant fraction;

mixing said low-temperature, low-pressure mixed refrigerant with said first liquid refrigerant fraction and flowing the combined mixed refrigerant in a direction opposite to that of said gas refrigerant fraction; and

recycling said combined mixed refrigerant to the compressor.

12. A method according to claim 11, wherein said heat exchanger comprises a plate-fin heat exchanger.