Stabilized built aqueous liquid softergent compositions

• US 5,364,553 A
• Filed: 08/16/1993
• Issued: 11/15/1994
• Est. Priority Date: 04/13/1990
• Status: Expired due to Fees

• Current Assignee: Colgate-Palmolive Company
• Original Assignee: Colgate-Palmolive Company
• Inventors: Cao, Hoai C.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): HERTZOG, ARDITH E
• Application Number:
  US08/106,972
• Time in Patent Office: 456 Days
• Field of Search: 252/174.12, 252/DIG. 12, 252/174.19, 252/135, 252/DIG. 14
• US Class Current: 510/321
• CPC Class Codes: C11D 1/29 Sulfates of polyoxyalkylene ethers
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/722 Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups C11D1/721 takes precedence
• CPC Class Codes: C11D 1/83 Mixtures of non-ionic with anionic compounds
• CPC Class Codes: C11D 3/1266 in liquid compositions
• CPC Class Codes: C11D 3/128 Aluminium silicates, e.g. zeolites C11D3/1253 takes precedence
• CPC Class Codes: C11D 3/3765 in liquid compositions
• CPC Class Codes: C11D 3/38663 Stabilised liquid enzyme compositions

Abstract

The preferred "softergent" compositions include a clay softener, a mixture of anionic and nonionic surfactants, and detergent builder(s). The detergent builder is preferably a crystalline aluminosilicate zeolite. Stabilization is achieved using an antiflocculating structurant polymer, such as low molecular weight polyacrylic acid. The anionic surfactant is preferably an ethoxylated alkyl sulfate. Enzymes and enzyme stabilizers are also included in preferred compositions.

Claims

1. An enzyme-containing liquid detergent composition comprising:

A) from about 5 to about 75% by weight, of one or more surface active detergent compounds;

B) from about 5 to about 30%, by weight, of one or more detergency builders comprising a zeolite;

C) from about 0.01 to about 5%, by weight, of protease enzymes;

D) an enzyme stabilization system comprising;

(i) from about 0.25 to about 10%, by weight, of a boron compound selected from the group consisting of boric acid, boric oxide, and alkali metal borates;

(ii) from about 1 to about 3%, by weight, of an hydroxypolycarboxylic acid selected from the group consisting of alphatic di- and tri-carboxylic acids with from 1 to 4 hydroxyl groups and with from 4 to 8 carbon atoms; and

(iii) a water soluble calcium salt in an amount sufficient to provide from about 18 to 50 millimoles of calcium ion per liter of the composition; and

E) water.

2. The liquid detergent composition of claim 1 wherein the enzyme stabilization system comprises (i) borax, (ii) citric acid, and (iii) calcium chloride.

3. The liquid detergent composition of claim 2 wherein the enzyme stabilization system comprises from about 0.5 to about 8% by weight borax, from about 1.5 to about 2.5% by weight citric acid and calcium chloride in an amount sufficient to provide from about 22 to about 36 millimoles of calcium ion per liter of the composition.

4. The liquid detergent composition of claim 1 wherein the enzyme stabilization system comprises from about 0.5 to about 8% by weight borax, from about 1.5 to about 2.5% by weight citric acid and calcium chloride in an amount sufficient to provide from about 22 to about 36 millimoles of calcium ion per liter of the composition.

5. The liquid detergent composition of claim 1 which further comprises a softening effective amount of a clay softening agent.

6. The liquid detergent composition of claim 1 which comprises (A) from about 5 to about 30%, by weight, of a mixture of (a) non-soap anionic surface active compound and (b) nonionic surface active detergent compound at an (a):

(b) ratio, by weight, of from about 1;

4 to about 10;

1.

7. The liquid detergent composition of claim 6 wherein the anionic (a) is an alkyl polyethoxy sulfate wherein the alkyl is from 10 to 18 carbon atoms and which includes from 3 to 11 ethoxy groups, and wherein the nonionic (b) is a mixed ethylene oxide-propylene oxide fatty alcohol condensation product of the formula

9. A method of laundering stained or soiled fabrics comprising contacting the fabrics with the stabilized enzyme containing liquid detergent composition of claim 1.

8. A built aqueous liquid enzyme containing cleaning composition comprising:

(A) from about 5 to about 30%, by weight, of at least one surface active detergent compound selected from the group consisting of anionic, nonionic and ampholytic detergent compounds;

(B) from about 5 to about 25%, by weight, of a detergency builder comprising a zeolite;

(C) from about 0.1 to about 3%, by weight, protease enzyme;

(D) an enzyme stabilization system containing;

(i) from about 0.5 to about 8%, by weight, of boric acid, boric oxide or alkali metal borate;

(ii) from about 1.5 to about 2.5%, by weight, of citric acid; and

(iii) a water-soluble calcium salt in an amount sufficient to provide from about 22 to about 36 millimoles of calcium ion per liter of the composition;

(E) from about 5 to about 20% by weight of a clay softening agent; and

(F) water, and optionally perfume and other adjuvants.