Method for fabricating fiber-reinforced slag gypsum cement-based, lightweight set articles

• US 5,366,549 A
• Filed: 03/24/1994
• Issued: 11/22/1994
• Est. Priority Date: 11/28/1990
• Status: Expired due to Fees

• Current Assignee: Mitsui Takeda Chemicals Inc (Mitsui Chemicals)
• Original Assignee: Kyowa Giken Company Limited, Naigai Technos Corporation (Obayashi Corporation), Obayashi Corporation, Daiichi Cement Co. Ltd. (Taiheiyo Cement Corporation), Takeda Chemical Industries, Ltd. (Takeda Pharmaceutical Company Limited)
• Inventors: Koibuchi, Kiyoshi, Nasu, Koji, Takenami, Katsumi, Ishikawa, Youich, Imaizumi, Shokichi, Kazama, Seiji, Hori, Nagao, Aoyama, Tsuyoshi
• Primary Examiner(s): Group, Karl
• Assistant Examiner(s): MARCANTONI, PAUL D
• Application Number:
  US08/217,025
• Time in Patent Office: 243 Days
• Field of Search: 106/682, 106/711, 106/715, 106/723, 106/679, 106/680, 106/695, 106/696, 106/782, 106/772, 106/776, 106/789, 106/790, 264/333, 264/DIG. 43
• US Class Current: 106/715
• CPC Class Codes: C04B 28/065 Calcium aluminosulfate cements, e.g. cements hydrating into ettringite

Abstract

A method is provided for making a fiber-reinforced slag gypsum cement lightweight hardened product. The method consists essentially of mixing (1) from 5 to 140 parts by weight of aggregates having a maximum size of not larger than 2000 μm to (2) 100 parts by weight of a mixture which comprises 100 parts by weight of Portland cement, (3) from 20 to 350 parts by weight of slag fine powder which has a fineness ranging from 6,000 to 12,000 cm² /g as Blaine'"'"'s specific surface area, (4) from 0 to 20 parts by weight of lime, (5) from 20 to 100 parts by weight of calcium aluminate and gypsum fine powder, (6) 0.01 to 1.5 parts of a setting retardant; mixing water, prefoamed foams and reinforcing fibers with the mixture to obtain a slurry; subjecting the slurry to molding to obtain a molded product; removing the molded product to obtain a hardened product; and curing the hardened product with steam. In the method of the invention, the slurry sets and hardens within a short time, permitting the hardened product to be immediately removed from a mold.

Claims

1. A method for making a fiber-reinforced slag gypsum cement lightweight hardened product which consists essentially of the steps of:

adding from 5 to 140 parts by weight of aggregates having a maximum size of not larger than 2000 μ

m to 100 parts by weight of a mixture which comprises 100 parts by weight of Portland cement, from 20 to 350 parts by weight of slag fine powder which has a fineness ranging from 6,000 to 12,000 cm² /g as Blaine'"'"'s specific surface area, from 0 to 20 parts by weight of lime, and from 20 to 100 parts by weight of calcium aluminate and gypsum fine powder in total, provided that a ratio by weight of the gypsum fine powder and the calcium aluminate is in the range of 0.5 to 2.0;

1;

adding from 0.01 to 1.5 parts by weight of a setting retardant to the mixture;

mixing water, prefoamed foams and reinforcing fibers with the mixture to obtain a slurry;

subjecting the slurry to molding to obtain a molded product;

removing the molded product to obtain a hardened product; and

curing the hardened product with steam;

wherein the amount of the prefoamed foams to be added to the slurry is the amount necessary to obtain a hardened product having an air-dried specific gravity of from 0.4 to 1.5.

2. The method according to claim 1, wherein said slag fine powder is a slag fine powder which is obtained by classification after milling of a blast furnace granulated slag.

3. The method according to claim 1, wherein said calcium aluminate is CA, CA₂, C₃ A, C₁₂ A₇, C₁₁ A₇ . CaF₂ or mixtures thereof.

4. The method according to claim 1, wherein said gypsum fine powder has a fineness of not smaller than 2,500 cm² /g in terms of Blaine'"'"'s specific area.

5. The method according to claim 1, wherein when molded, said slurry is applied with vibrations at a frequency of 100 to 10,000 V.P.M.

6. The method according to claim 1, wherein when molded, compressed air is blown against the slurry.

7. The method according to claim 1, wherein said slurry sets and hardens within 3 to 60 minutes after the molding and can be immediately removed from a mold and worked.

8. The method according to claim 1, wherein the steam curing temperature is not higher than 90°

C. and the curing is effected at not less than 150°

C. . hour.

9. A method of making a fiber-reinforced slag gypsum cement lightweight hardened product which consist essentially of the steps of:

adding from 5 to 140 parts by weight of aggregates having a maximum size of not larger than 2000 μ

m to 100 parts by weight of a mixture which comprises 100 parts by weight of Portland cement, from 20 to 350 parts by weight of slag fine powder, from 0 to 20 parts by weight of lime, and from 20 to 100 parts by weight of calcium aluminate and gypsum fine powder in total_L provided that a ratio by weight of the gypsum fine powder and the calcium aluminate is in the range of 0.5 to 2.0;

1;

adding from 0.01 to 1.5 parts by weight of a setting retardant to the mixture;

mixing water, foaming agent and reinforcing fibers with the mixture to obtain a slurry;

subjecting the slurry to molding to obtain a molded product;

removing the molded product to obtain a hardened product; and

curing the hardened product with steam;

wherein the amount of the foaming agent to be added to the slurry is the amount necessary to obtain a hardened product having an air-dried specific gravity of from 0.4 to 1.5.

10. The method according to claim 9, wherein said slag fine powder is a slag fine powder which is obtained by classification after milling of a blast furnace granulated slag and which has a fineness ranging from 6,000 to 12,000 cm² /g as Blaine'"'"'s specific surface area.

11. The method according to claim 9, wherein said calcium aluminate is CA, CA₂, C₃ A, C₁₂ A₇, C₁₁ A₇.CaF₂ or mixtures thereof.

12. The method according to claim 9, wherein said gypsum fine powder has a fineness of not small than 2,500 cm² /g in terms of Blaine'"'"'s specific surface area.

13. The method according to claim 9, wherein during molding said slurry is subjected to vibrations at a frequency of 100 to 10,000 V.P.M.

14. The method according to claim 9, wherein during molding compressed air is blown against the slurry.

15. The method according to claim 9, wherein said slurry sets and hardens within 3 to 60 minutes after said molding step and is immediately removed from the mold and worked.

16. The method according to claim 9, wherein the steam curing temperature is not higher than 90°

C. and the curing is effected at not less than 150°

C. . hour.