Waste treatment process for removal of contaminants from aqueous, mixed-waste solutions using sequential chemical treatment and crossflow microfiltration, followed by dewatering

• US 5,366,634 A
• Filed: 08/26/1992
• Issued: 11/22/1994
• Est. Priority Date: 08/26/1992
• Status: Expired due to Fees

• Current Assignee: United States Department of Energy
• Original Assignee: United States Department of Energy
• Inventors: Buckley, Leo P., Wong, Chi F., Vijayan, Sivaraman
• Primary Examiner(s): CINTINS, IVARS C
• Application Number:
  US07/935,328
• Time in Patent Office: 818 Days
• Field of Search: 210/638, 210/639, 210/665, 210/667, 210/669, 210/682, 210/687, 210/688, 210/694, 210/651
• US Class Current: 210/638
• CPC Class Codes: B01D 2311/04 Specific process operations in the feed stream; Feed pretreatment
• CPC Class Codes: B01D 61/147 Microfiltration
• CPC Class Codes: B01D 61/16 Feed pretreatment
• CPC Class Codes: C02F 1/283 using coal, charred products, or inorganic mixtures containing them
• CPC Class Codes: C02F 1/444 by ultrafiltration or microfiltration
• CPC Class Codes: C02F 1/5245 using basic salts, e.g. of aluminium and iron
• CPC Class Codes: C02F 2101/006 Radioactive compounds
• CPC Class Codes: C02F 2103/06 Contaminated groundwater or leachate
• CPC Class Codes: G21F 9/10 by flocculation

Abstract

In processes of this invention aqueous waste solutions containing a variety of mixed waste contaminants are treated to remove the contaminants by a sequential addition of chemicals and adsorption/ion exchange powdered materials to remove the contaminants including lead, cadmium, uranium, cesium-137, strontium-85/90, trichloroethylene and benzene, and impurities including iron and calcium. Staged conditioning of the waste solution produces a polydisperse system of size enlarged complexes of the contaminants in three distinct configurations: water-soluble metal complexes, insoluble metal precipitation complexes, and contaminant-bearing particles of ion exchange and adsorbent materials. The volume of the waste is reduced by separation of the polydisperse system by cross-flow microfiltration, followed by low-temperature evaporation and/or filter pressing. The water produced as filtrate is discharged if it meets a specified target water quality, or else the filtrate is recycled until the target is achieved.

Claims

1. A waste treatment process for removal of contaminants including metals, radionuclides and organic matter from a feed of water containing contaminants including metals, radionuclides and organic matter, comprising the following steps:

treating said feed of water with a base, a powdered ion-exchange material, sodium carbonate, and a powdered adsorbent to remove contaminants; and

separating suspended solids, produced from the treatment, from said feed by passing said feed through a crossflow microfiltration means.

2. A waste treatment process of claim 1 wherein said base is lime, said powdered ion-exchange material is zeolite, and said powdered adsorbent is activated carbon.

3. A waste treatment process for removal of contaminants including metals, radionuclides and organic matter from a feed of water containing coarse particles, calcium and contaminants, said contaminants including metals including heavy metals, radionuclides and organic matter, comprising the following steps:

removing coarse particles suspended in said feed of water by passing said feed through a filter;

precipitating metals including heavy metals from said feed of water by the addition of a base;

sorbing residual dissolved heavy metals and a portion of any dissolved radionuclides from said feed by adding an ion-exchange material;

separating metal precipitates and ion-exchange particles from said feed by a first stage crossflow microfiltration;

precipitating calcium and a portion of radioactive strontium from said feed by adding soda;

sorbing a portion of radionuclides from said feed by adding an ion-exchange material;

separating calcium and strontium precipitates, radionuclides and ion-exchange particles from said feed by a second stage crossflow microfiltration;

removing residual radionuclides and organic contaminants from said feed by adding activated carbon and ion-exchange material;

separating said organic contaminants from said feed by a third stage crossflow microfiltration.

4. A process of claim 3 further comprising the step of neutralizing the pH level of said feed to a value suitable for waste water discharge.

5. The process of claim 3 further comprising the step of dewatering a concentrate stream from each of the crossflow microfiltration means.

6. A waste treatment process for removal of contaminants including metals, radionuclides and organic matter from a feed of water containing coarse particles, calcium and contaminants, said contaminants including metals, radionuclides and organic matter, comprising the following steps:

precipitating contaminants from said feed of water by adding a base to said feed of contaminated water;

sorbing contaminants from said feed of water by adding an ion-exchange material;

precipitating calcium and contaminants from said feed by adding soda;

adsorbing contaminants from said feed of water by adding a powdered adsorbent; and

separating suspended particles, produced by the addition of said base, ion-exchange material, soda, and adsorbent, from said feed of water by passing said feed through a crossflow microfiltration means.

7. A process of claim 6 further comprising the step of neutralizing the pH level of said feed to a value suitable for waste water discharge.

8. A process of claim 6 wherein said contaminants precipitated, sorbed by ion-exchange and adsorbed from said feed are removed by passing said feed through a crossflow microfiltration means prior to additional precipitation, sorbing by ion-exchange and adsorption of any remaining contaminants.

9. A process of claim 6 further comprising the step of dewatering a concentrate stream from the crossflow microfiltration means.

10. The process of claim 6 wherein said ion-exchange material includes zeolite.

11. The process of claim 6 wherein said powdered adsorbent includes activated carbon.

12. The process of claim 6 wherein said suspended particles include heavy metals, metals, radionuclides, organic matter, calcium, soda, ion-exchange material, and activated carbon.

13. The process of claim 6 further comprising the steps of filtering coarse suspended particles in said feed of contaminated water and sampling said feed for analysis of the contaminants prior to the removal of said contaminants.