Constant voltage fuel cell with improved reactant supply and control system

• US 5,366,821 A
• Filed: 03/13/1992
• Issued: 11/22/1994
• Est. Priority Date: 03/13/1992
• Status: Expired due to Term

• Current Assignee: BDF IP Holdings Ltd. (Superior Plus Corporation)
• Original Assignee: Ballard Power Systems Corporation (Superior Plus Corporation)
• Inventors: Blair, James D., Merritt, Robert D.
• Primary Examiner(s): Chaudhuri, Olik
• Assistant Examiner(s): EVERHART, CARIDAD
• Application Number:
  US07/850,570
• Time in Patent Office: 984 Days
• Field of Search: 429/21, 429/22, 429/23, 429/24, 429/25
• US Class Current: 429/422
• CPC Class Codes: H01M 8/04 Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
• CPC Class Codes: H01M 8/04089 of gaseous reactants
• CPC Class Codes: H01M 8/04097 with recycling of the reactants H01M8/04119, H01M8/04104 take precedence
• CPC Class Codes: H01M 8/04156 with product water removal
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A method and apparatus for providing a substantially constant output voltage from a fuel cell, notwithstanding output current variations, is disclosed. The voltage and secondarily the current of the cell is determined at least periodically. The pressure of the reactant gas in the fuel cell is then regulated so substantially the nominal voltage is maintained. The temperature in the fuel cell may also be regulated to maintain the nominal output voltage. Also, a method and apparatus for minimizing the parasitic power drain in a electric power generation system is disclosed. The fuel cell is fed with an reactant gas by a compressor driven by parasitic power drawn from the fuel cell. The method is carried out by determining that the output current of the fuel cell has changed, and changing one or more or the pressure, the mass flow rate and the reactant utilization ratio of the reactant in the fuel cell, thereby changing the amount of the parasitic power drawn from the electrical power output to drive the compressor.

Claims

1. A method for regulating the utilization of a reactant gas in an electric power generation system comprising at least one fuel cell, an input to said fuel cell of a reactant gas comprising at least one reactant constituent, and an output from said fuel cell of the reactant gas and an electrical output characterized by a voltage and a current, said method comprising the steps of:

A. selecting for said fuel cell a reactant utilization ratio, said ratio defined as the amount of the reactant constituent delivered to said reactant input per unit time divided by the amount of the reactant constituent consumed in said fuel cell per unit time;

B. determining a mass flow rate of the reactant gas through the fuel cell which will provide the selected reactant utilization ratio;

C. measuring the actual mass flow rate of the reactant gas at the reactant gas input and the output current of said fuel cell; and

D. regulating the mass flow rate of the reactant gas at the reactant gas output of said fuel cell, responsive to the output current and the mass flow rate measured at said reactant gas input, to maintain said determined mass flow rate.

2. The method of claim 1, wherein said reactant constituent is oxygen.

3. The method of claim 1, wherein said reactant gas is air.

4. The method of claim 1, wherein said reactant constituent is hydrogen.

5. The method of claim 1, wherein said reactant gas is selected from the group consisting of hydrogen gas, natural gas reformate, methanol reformate, combinations thereof, and recycled products thereof.

6. The method of claim 1, comprising the further step of recycling at least a portion of the reactant constituent received at said fuel cell output to said fuel cell input.

7. A method of providing a substantially constant output voltage, notwithstanding output current variations, in an electric power generation system comprising at least one fuel cell, an input to said fuel cell of a reactant gas, and an electrical output characterized by a voltage and a current, said method comprising the steps of:

A. selecting a nominal output voltage for said fuel cell,

B. at least periodically determining the actual voltage delivered by the electrical output of said fuel cell, and

C. regulating the pressure of the reactant gas in said fuel cell, in response to the voltage of the electrical output, so said nominal voltage is maintained at the electrical output.

8. The method of claim 7, comprising the further step of regulating the temperature of said fuel cell, in response to the voltage of the electrical output, so said nominal voltage is maintained at the electrical output.

18. The method of claim 7, comprising the further step of periodically determining the actual current delivered by the electrical output of said fuel cell.

19. The method of claim 7, comprising the further step of regulating the pressure of the reactant gas in said fuel cell, in response to the current of the electrical output, so said nominal voltage is maintained at the electrical output.

20. The method of claim 7, comprising the farther step of regulating the temperature of said fuel cell, in response to the current of the electrical output, so said nominal voltage is maintained at the electrical output.

9. A method of minimizing the parasitic power drain in an electric power generation system comprising at least one fuel cell having a variable electrical power output, a reactant gas input to said fuel cell, and a compressor driven by parasitic power drawn from said electrical power output for pressurizing the reactant gas within said fuel cell, said method comprising the steps of:

A. determining that the output current of said fuel cell has changed, and

B. changing the mass flow rate while maintaining substantially constant the pressure and reactant utilization ratio of the reactant in said fuel cell, in response to changes in said output current, thereby changing the amount of said parasitic power drawn from said electrical power output to drive said compressor.

10. The method of claim 9, wherein step (B) comprises changing the pressure and the mass flow rate while maintaining constant the reactant utilization ratio of the reactant in said fuel cell, in response to changes in said output current, thereby changing the amount of said parasitic power drawn from said electrical power output to drive said compressor.

11. The method of claim 9, wherein step (B) comprises changing the pressure, the mass flow rate and the reactant utilization ratio of the reactant in said fuel cell, in response to changes in said output current, thereby changing the amount of said parasitic power drawn from said electrical power output to drive said compressor.

12. A variable power output electric power generation system comprising:

A. at least one fuel cell including an input of a reactant gas comprising a reactant constituent, an output of the reactant gas, and apparatus for reacting the reactant constituent to produce as an output electric power characterized by a voltage and a current;

B. apparatus for determining a mass flow rate of the reactant gas which will provide a desired reactant constituent utilization ratio, said ratio defined as the amount of said reactant constituent delivered to said reactant gas input per unit time divided by the amount of the reactant constituent consumed in said fuel cell per unit time;

C. a current sensor for measuring the output current of said fuel cell, said sensor generating a measured current signal;

D. a mass flow rate sensor at the reactant gas input of said fuel cell for measuring the mass flow rate of the reactant gas, said mass flow rate sensor generating a measured flow rate signal; and

E. a valve at said reactant gas output of said fuel cell for maintaining the determined mass flow rate of the reactant gas, said valve responsive to said measured current signal and said measured mass flow rate signal.

13. The power generation system of claim 12, wherein water vapor is present in the reactant gas as it exits the reactant gas output, and further comprising recovery apparatus provided downstream of said reactant gas output for recovering water from the reactant stream, and wherein said valve at said reactant gas output is located downstream of said recovery apparatus.

14. A voltage-regulated, variable-current electric power generation system comprising:

A. at least one fuel cell including a reactant gas input and an electrical output characterized by a voltage and a current;

B. apparatus responsive to the output voltage of said fuel cell for determining a pressure of the reactant gas in said fuel cell which will maintain the output voltage of said system at a predetermined level; and

C. apparatus for substantially maintaining the determined pressure of the reactant gas in said fuel cell.

21. The system of claim 14, further comprising an apparatus responsive to the output current of said fuel cell for determining pressure of the reactant gas in said fuel cell which will maintain the output voltage of said system.

22. The system of claim 14, further comprising an apparatus responsive to the output voltage of said fuel cell for determining a temperature of the reactant gas in said fuel cell which will maintain the output voltage of said system.

23. The system of claim 14, further comprising an apparatus responsive to the output current of said fuel cell for determining a temperature of the reactant gas in said fuel cell which will maintain the output voltage of said system.

15. A variable power output electric power generation system comprising:

A. at least one fuel cell having a reactant gas input and an electrical output characterized by a voltage and a current;

B. a compressor driven by parasitic power drawn from said electrical power output for pressurizing the reactant gas within said fuel cell; and

C. apparatus for changing one or more of the pressure, the mass flow rate and the reactant utilization ratio of the reactant gas in said fuel cell, in response to changes in said output current of said fuel cell, thereby changing the amount of said parasitic power drawn from said electrical power output to drive said compressor.

16. Apparatus for simultaneously regulating the mass flow rate and pressure of a reactant gas in an electric power generation system comprising at least one fuel cell having a reactant gas input for receiving a reactant gas and a reactant output for discharging the reactant gas and an electrical output characterized by a voltage and a current, said apparatus comprising:

A. apparatus for maintaining the reactant gas at a predetermined pressure at said reactant gas input;

B. apparatus for measuring said output current;

C. apparatus for measuring the mass flow rate of the reactant gas at said reactant gas input; and

D. apparatus for regulating the mass flow rate of the reactant gas at the reactant output of said fuel cell, responsive to said measured output current and said measured mass flow rate.

17. A method for regulating the utilization of a reactant gas in an electric power generation system comprising at least one fuel cell, an input to said fuel cell of a reactant gas comprising at least one reactant constituent, and an output from said fuel cell of the reactant gas and an electrical output characterized by a voltage and a current, said method comprising the steps of:

A. selecting for said fuel cell a reactant utilization ratio, said ratio defined as the amount of the reactant constituent delivered to said reactant input per unit time divided by the amount of the reactant constituent consumed in said fuel cell per unit time;

B. determining a mass flow rate of the reactant gas through the fuel cell which will provide the selected reactant utilization ratio;

C. measuring the actual mass flow rate of the reactant gas at the reactant gas input and the output current of said fuel cell;

D. regulating the mass flow rate of the reactant gas at the reactant gas output of said fuel cell, responsive to the output current and the mass flow rate measured at said reactant gas input, to maintain said determined mass flow rate; and

E. maintaining the reactant gas within said fuel cell.