Ambient curing water-borne compositions comprising half esters of anhydride polymers crosslinked by epoxies

• US 5,367,004 A
• Filed: 11/17/1992
• Issued: 11/22/1994
• Est. Priority Date: 11/17/1992
• Status: Expired due to Fees

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Lock, Michele R., Barsotti, Robert J., Harper, Lee R.
• Primary Examiner(s): Bleutge, John C.
• Assistant Examiner(s): WILSON, DONALD R
• Application Number:
  US07/977,864
• Time in Patent Office: 735 Days
• Field of Search: 523/414, 523/417, 523/439, 525/117
• US Class Current: 523/414
• CPC Class Codes: B05D 2401/20 Aqueous dispersion or solution
• CPC Class Codes: B05D 2451/00 Type of carrier, type of coating (Multilayers)
• CPC Class Codes: B05D 7/53 Base coat plus clear coat type
• CPC Class Codes: C08K 5/1515 Three-membered rings
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 33/06 of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
• CPC Class Codes: C08L 43/04 Homopolymers or copolymers of monomers containing silicon
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: C08L 75/04 Polyurethanes
• CPC Class Codes: C09D 133/064 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
• CPC Class Codes: C09D 143/04 Homopolymers or copolymers of monomers containing silicon

Abstract

An ambient cured aqueous coating composition useful for maintenance coatings for architectural structures or for a finish or refinish for automobiles and trucks. The film-forming binder comprises a neutralized half-ester product of an acrylic polymer having at least two reactive anhydride groups and an epoxy-containing, optionally silane-containing crosslinker. The composition may be used as a mulit-package system. The composition is characterized by improved environmental resistance and excellent clarity and appearance, particularly for clearcoats.

Claims

1. A coating composition, in the form of a multipackage system, for producing a clearcoat, said coating composition comprising 20-80% by weight of reactive binder components and 80-20% by weight of an aqueous liquid carrier comprising at least 60% by weight water;

wherein the binder comprises;

(a) 25-90% by weight, based on the weight of the binder, of a half-ester product of an acrylic copolymer having at least two reactive anhydride groups and comprising polymerized monomers of an ethylenically unsaturated arthydride or an ethylenically unsaturated dicarboxylic acid, which has been converted to an anhydride, and polymerized monomers selected from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-100,000, wherein equal to or greater than 90% of the arthydride groups on said acrylic copolymer have been half-esterifed by reaction with an alcohol;

(b) 5-50% by weight, based on the weight of the binder, of a glycidyl ether or ester or cycloaliphatic epoxy compound containing at least two reactive glycidyl groups;

(c) an effective amount of a base to neutralize the half-ester acrylic copolymer (a) above; and

(d) 0.1-8% by weight, based on the weight of binder, of a curing catalyst, wherein the components are selected such that the composition is capable of forming a clearcoat automotive refinish that can be cured at 10°

to 90°

C. after being applied, and wherein components (a) and (b) are kept separate in said multi-package system until shortly before application.

2. The coating composition of claim 1, wherein the base is a volatile amine in an amount to solubilize or disperse the half ester product into the aqueous liquid carrier.

3. The coating composition of claim 1, wherein the catalyst is a non-volatile tertiary amine catalyst.

4. The coating composition of claim 1, further comprising a an acrylic latex and/or a waterborne urethane dispersion or emulsion.

6. The coating compostion of claim 1, further comprising a polyester urethane.

7. The coating composition of claim 1, in which the half ester product is an acrylic polymer comprising polymerized monomers of styrene, alkyl methacrylates and/or alkyl acrylates having 2-4 carbon atoms in the alkyl group, and the half ester of an ethylenically unsaturated arthydride or ethylenically unsaturated dicarboxylic acid which has been converted to an arthydride.

8. The coating composition of claim 1 in which component (a) is the half ester product of an anhydride functional acrylic copolymer comprising polymerized monomers of alkyl acrylate and/or alkyl methacrylate, each akyl having 1-12 carbon atoms, and maleic arthydride.

9. The composition of claim 6, wherein the polyester urethane is the reaction product of a hydroxyl terminated polyester and a polyisocyanate.

10. The coating composition of claim 6, in which the polyester urethane has an acid number of 20 to 120.

11. The coating composition of claim 1, further comprising an acid functional polymer formed by polymerizing monomers of alkyl methacrylates or alkyl acrylates or hydroxy alkyl acrylates or hydroxy alkyl methacrylates or mixtures thereof, where the alkyl groups have 1-12 carbon atoms and ethylenically unsaturated acids.

12. The coating composition of claim 1, further comprising a half ester, in addition to component (a), which is the reaction product of a alcohol or glycol and a monomeric anhydride of a dicarboxylic acid.

13. A substrate coated with a cured layer of the composition of claim 1.

14. The substrate of claim 13, wherein said substrate is plastic or metal.

5. The coating composition of claim I in which the glycidyl component is selected from the group consisting of a polyglycidyl ether of low molecular weight polyol, an epoxy resin of epichlorohydrin and bisphenol A, a polyglycidyl ester of poly carboxylic acid, a polyglycidyl ether of isocyanurate, a glycidyl methacrylate or glycidyl acrylate containing acrylic polymer, and mixtures of any of the above.