Depolymerization method for resource recovery from polymeric wastes

• US 5,369,215 A
• Filed: 08/16/1993
• Issued: 11/29/1994
• Est. Priority Date: 04/06/1992
• Status: Expired due to Fees

• Current Assignee: Ricoh Company Limited, S-P Reclamation, Inc.
• Original Assignee: S-P Reclamation, Inc.
• Inventors: Platz, Gerald A.
• Primary Examiner(s): VARGOT, MATHIEU D
• Application Number:
  US08/107,281
• Time in Patent Office: 470 Days
• Field of Search: 585/241, 264/37, 264/83, 264/238, 264/349, 264/233, 264/28, 264/130, 264/DIG. 69, 201/2.5, 241/DIG. 37, 425/DIG. 44
• US Class Current: 585/241
• CPC Class Codes: B29B 17/02 Separating plastics from other materials
• CPC Class Codes: B29L 2030/00 Pneumatic or solid tyres or parts thereof conveyor belts B29L2031/7092; drive belts B29L2031/7094; fourdrinier belts B29L2031/733
• CPC Class Codes: C07B 63/02 by treatment giving rise to a chemical modification
• CPC Class Codes: C07C 11/02 Alkenes
• CPC Class Codes: C07C 2527/232 Carbonates
• CPC Class Codes: C07C 4/22 by depolymerisation to the original monomer, e.g. dicyclopentadiene to cyclopentadiene
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling
• CPC Class Codes: Y10S 241/37 Cryogenic cooling
• CPC Class Codes: Y10S 264/912 From toroidal shapes, e.g. resilient tires
• CPC Class Codes: Y10S 425/044 Rubber mold

Abstract

Polymeric feedstocks, such as scrap or waste tires, rubber, and plastics, in a size range of -6 to +25 mesh are washed with an organic solvent to remove stabilizing additives which have migrated to the surface of the polymer particles, thus eliminating the stabilizers from participation in subsequent reactions and allowing the final production of more pure monomeric products. The polymer particles are exposed to ozone under conditions to cause stress cracking, fissuring and cleavage of the polymer feedstock particles. The ozonated polymer particles are depolymerized to produce one or more monomeric compounds, with the reaction taking place rapidly and occurring in the presence of a system of one or more catalysts which may be metallic salts. The depolymerization is accomplished under conditions of elevated temperatures and reduced pressure, the conditions being less severe than those conditions associated with thermal pyrolysis. The monomeric compounds are recovered by conventional means from otherwise waste polymers and are recycled. Other products of this invention may be collected and recycled or disposed of with no adverse impact on the environment.

Claims

1. A process for recovering a monomer from a vulcanized addition polymer feedstock formed at least from the monomer and from compounded additives, comprising the steps of:

(a) washing the addition polymer feedstock to remove the additives from the surface of the feedstock;

(b) exposing the washed feedstock to gaseous ozone under conditions sufficient to rupture chemical bonds formed during the vulcanization process of the addition polymer feedstock and thereby form one or more intermediate products;

(c) heating in the presence of a catalyst the mixture formed in step (b) to a temperature and for a time sufficient to depolymerize the addition polymer and form the monomer; and

(d) removing the monomer following its formation from the mixture.

2. The process of claim 1 wherein the washed addition polymer feedstock is exposed to a mixture of gaseous ozone and air.

3. The process of claim 2 wherein the mixture of gaseous ozone and air comprises about 0.01 percent by weight of gaseous ozone.

4. The process of claim 1 wherein the addition polymer feedstock is exposed to gaseous ozone under conditions to rupture cross-linked bonds of the addition polymer feedstock.

5. The process of claim 1 wherein the addition polymer feedstock comprises particles ranging in size from about -6 to +25 mesh.

6. The process of claim 1 wherein the reaction of step (c) is carded out at a temperature of between about 200°

C. and about 600°

C.

7. The process of claim 1 wherein the reaction temperature of step (c) is cycled between about 300°

C. and 550°

C.

8. The process of claim 1 wherein the depolymerization reaction takes place in the presence of a thermocatalytic catalyst.

9. The process of claim 1 wherein the depolymerization reaction takes place in the presence of thermocatalytic catalyst system which is a combination of metallic halides.

10. The process of claim 9 wherein the thermocatalytic catalyst system is a combination of magnesium dichloride and aluminum trichloride.

11. The process of claim 10 wherein the molar ratio of the magnesium dichloride and aluminum trichloride is between about 1:

1 and about 2;

1.

12. The process of claim 1 wherein the reaction of step (c) is carried out at a pressure from about 0.05 to about 0.25 atmospheres.

13. The process of claim 1 wherein the addition polymer feedstock is rubber reclaimed from used tires.

14. The process of claim 1 wherein the addition polymer feedstock is of polyolefin origin.

15. The process of claim 1 wherein the addition polymer feedstock is made up of a blend of addition copolymer feedstocks.