Process for isolating contaminated soil

• US 5,370,478 A
• Filed: 09/01/1993
• Issued: 12/06/1994
• Est. Priority Date: 05/11/1993
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Noll, Mark R., Epps, David E., Bartlett, Craig L., Cline, Stephen P., Jurinak, Jeff J.
• Primary Examiner(s): Suchfield, George A.
• Application Number:
  US08/115,928
• Time in Patent Office: 461 Days
• Field of Search: 166/50, 166/245, 166/292, 405/128, 405/267, 588/252, 588/256
• US Class Current: 405/129.6
• CPC Class Codes: B09C 1/00 Reclamation of contaminated soil
• CPC Class Codes: B09C 1/08 chemically
• CPC Class Codes: B09C 2101/00 In situ
• CPC Class Codes: E02D 3/12 Consolidating by placing solidifying or pore-filling substances in the soil making piles E02D5/46; soil-conditioning or soil-stabilising materials C09K17/00; consolidation of ground around boreholes or wells E21B43/025

Abstract

Process for hydraulically guiding a layer of gellable grout solution (containing water-soluble Al or Fe salts, alkali metal silicates, or silica sols) to form a sealed confining layer beneath or around a contaminated zone beneath the water table which prevents both lateral and down-ward movement of contaminants or contaminated water.

Claims

1. A process for the in situ formation of continuous, substantially impermeable barriers in the saturated zone below the water table which comprises (a) injecting into a first location in said zone an aqueous stream which can be caused to form a gel, (b) removing groundwater at a second location in said zone which is spaced horizontally from said first location, and (c) causing said stream to gel, the combined effect of injection step (a) and groundwater removal step (b) being to cause said aqueous stream to proceed from said first location toward said second location;

said aqueous stream being an aqueous solution or sol having a viscosity and density similar to that of water, and a gelling time sufficiently long to allow subsurface migration from the point of injection to the point at which water is removed from said second location.

2. The process of claim 1 wherein said aqueous stream which is capable of forming a gel comprises a silica sol, a water solution of an alkali metal silicate, or a hydrolyzable water-soluble salt of iron or aluminum.

3. The process of claim 1 wherein said aqueous stream which is capable of forming a gel is pumped into one or more injection wells and groundwater is pumped out of extraction wells, thereby creating a hydraulic gradient between the injection and extraction wells thus allowing said stream which can be caused to form a gel to flow from the injection well to the extraction well creating a continuous fluid layer which is allowed to gel in situ to create a barrier.

4. The process of claim 1 wherein the injected solution, and the resultant chemically reactive gel barrier have a high affinity for, reaction with or adsorption of heavy metals from solution, thus giving said barrier the ability to reduce contaminant migration by permeability reduction and by the sorption and resultant retardation of metals in solution.

5. The process of claim 4 wherein heavy metals are lead, chromium, or zinc.

6. The process of claim 1 wherein said aqueous stream is substantially free of suspended material which will filter out of said stream as it passes through the soil in said saturated zone.

7. The process of claim 1 wherein said aqueous stream has a specific gravity in the range between 0.9 and 1.5, a viscosity in the range between 0.9 and 5.0 cp at a temperature above 4°

C., and a setting time in the range between 1 and 2000 hours.

8. The process of claim 1 wherein said aqueous stream comprises water-soluble metal salts which will gel upon hydrolysis, water solutions of alkali metal silicates, or silica sols.

9. The process of claim 1 wherein said aqueous stream comprises an aqueous solution or sol containing 1 to 70 weight percent of a non-aggregated coloidal silica sols having average particle diameters in the range between 4 and 100 nanometers and a pH in the range between 3 and 10.

10. The process of claim 9 wherein said solution or sol contains from 3.5 to 40 weight percent of a non-aggregated coloidal silica sol having average particle diameters in the range between 4 and 22 nanometers, a pH in the range between 5 and 9.5, and a gel time in the range between 10 and 1000 hours.

11. The process of claim 9 wherein said solution or sol contains from 4 to 10 weight percent of a non-aggregated coloidal silica sol having average particle diameters in the range between 4 and 12 nanometers, a pH in the range between 5.5 and 7.5, and a gel time in the range between 40 and 400 hours.

12. A process for the in situ formation of continuous, substantially impermeable barriers in the saturated zone below the water table which comprises (a) erecting substantially vertical walls which enclose contaminants contained in said zone;

(b) injecting water into the resulting enclosed zone at a first location above the bottom and adjacent to a portion of said walls, and removing water at a second location within said enclosed zone above the bottom and adjacent to an opposing portion of said walls which is spaced laterally from said first location so as to provide an upper stream of water;

(c) injecting an aqueous stream which can be caused to form a gel at a first location outside of said enclosed zone and above the bottom of said walls at a location which is spaced laterally from said first location which is within said enclosed zone, and removing water at a second location outside of said enclosed zone above the bottom and adjacent to an opposing portion of said walls which is spaced laterally from said first location outside of said walls so as to provide a gellable stream;

(d) injecting water at a third location outside of said enclosed zone and above the bottom of said walls at a location which is spaced laterally outward of said first location which is outside of said enclosed zone, and removing water at a fourth location outside of said enclosed zone and above the bottom and adjacent to an opposing portion of said walls which is spaced laterally outward of said second location outside of said walls so as to provide a lower stream of water;

said upper stream of water restraining movement of said gellable stream upwardly and said lower stream of water restraining movement of said gellable stream downwardly, thereby directing the flow of said gellable stream so as to provide a floor under the contaminants in said enclosed zone; and

(e) causing said gellable stream to gel so as to provide a continuous substantially impermeable barrier.