Organosiloxane compositions yielding tough elastomeric materials

• US 5,371,163 A
• Filed: 11/02/1993
• Issued: 12/06/1994
• Est. Priority Date: 11/02/1993
• Status: Expired due to Term

• Current Assignee: Dow, Inc., Plasson Ma'Agan Michael Industries Limited
• Original Assignee: Dow, Inc.
• Inventors: Wilson, Steven W.
• Primary Examiner(s): Marquis, Melvyn I.
• Application Number:
  US08/144,366
• Time in Patent Office: 399 Days
• Field of Search: 528/15, 525/478
• US Class Current: 528/15
• CPC Class Codes: C08G 77/12 containing silicon bound to hydrogen C08G77/045 takes precedence
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08G 77/70 Siloxanes defined by use of the MDTQ nomenclature
• CPC Class Codes: C08L 2666/44 Silicon-containing compounds
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes

Abstract

Tough gels and elastomers are prepared using compositions curable by a platinum catalyzed hydrosilation reaction that are characterized by the presence of a chain extender containing two silicon-bonded hydrogen atoms per molecule and a cross-linking agent containing at least three silicon bonded hydrogen atoms or alkenyl radicals per molecule, with the proviso that the chain extender contains at least 80 percent of the silicon bonded hydrogen atoms present in the composition or, when said cross-linking agent contains alkenyl radicals, said chain extender contains at least 80 percent of the total moles of silicon bonded hydrogen and said alkenyl radicals.

Claims

1. A curable organosiloxane composition comprising

A. a first liquid polyorganosiloxane comprising terminal siloxane units of the formula R¹ R₂² SiO_1/2 and non-terminal organosiloxane units of the formula R₂³ SiO,

B. an amount sufficient to impart toughness to cured articles prepared from said composition of a chain extender selected from disiloxanes of the formula (R⁴ HSi)₂ O or liquid diorganohydrogensiloxy-terminated polyorganosiloxanes wherein the terminal units are of the formula HR₂⁴ SiO_1/2, and the non-terminal organosiloxane units are of tile formula R₂⁵ SiO where R¹ represents an alkenyl radical, and R², R³, R⁴ and R⁵ are individually selected from unsubstituted or substituted monovalent hydrocarbon radicals that are free of ethylenic unsaturation,

C. an amount sufficient to cure said composition of a cross-linking agent comprising a second polyorganosiloxane containing all average of at least three silicon-bonded hydrogen atoms or alkenyl radicals per molecule, where the remaining silicon-bonded organic groups are monovalent hydrocarbon radicals selected from the same group as R², and

D. an amount of a hydrosilation catalyst sufficient to promote curing of said composition,

wherein the number of silicon-bonded hydrogen atoms present in said chain extender constitute at least 80 percent of total number of silicon-bonded hydrogen atoms and alkenyl radicals present in the combination of said chain extender and said cross-linking agent, the molar ratio of silicon-bonded hydrogen atoms in said chain extender to alkenyl radicals present in said first polyorganosiloxane is from 0.8 to 1.2.

2. A composition according to claim 1 where the viscosity of said first polyorganosiloxane and said composition are from 0.1 to 10 Pa.s,

said chain extender is a liquid diorganohydrogensiloxy-terminated polyorganosiloxane,

R⁴ and R⁵ are selected from the group consisting of alkyl radicals containing from 1 to 10 carbon atoms, phenyl and 3,3,3-trifluoropropyl,

R¹ contains from 2 to 10 carbon atoms,

R² and R³ contain from 1 to 10 carbon atoms,

the siloxane units of said cross-linking agent are represented by the formula R⁶_a SiO.sub.(4-a)/2 where R⁶ is hydrogen or an unsubstituted or substituted monovalent hydrocarbon radical, with the proviso that R⁶ represents hydrogen or an alkenyl radical on at least three of said units per molecule, a is 0, 1, 2 or3 and the viscosity of said cross-linker is from 0.5 to 2 Pa.s at 25°

C., and

said hydrosilation catalyst is a metal from the platinum group of the periodic table or a compound of said metal.

3. A composition according to claim 2 where

each R^l is vinyl or 5-hexenyl,

R² is methyl,

one of the two R³ radicals on each silicon is methyl and the second is methyl, phenyl or 3,3,3-trifluoropropyl,

each R⁶ is individually selected from the group consisting of hydrogen, vinyl, 5 -hexenyl and methyl,

the viscosity of said chain extender is from 0,001 to 0.1 Pa.s, and

said catalyst is a platinum compound.

4. A composition according to claim 2 where said composition contains a filler selected from reinforcing silica or quartz and said chain extender contains at least 85 percent of the silicon-bonded hydrogen atoms present in said composition.