Process for the production of bisphenol A

• US 5,371,304 A
• Filed: 04/18/1994
• Issued: 12/06/1994
• Est. Priority Date: 07/16/1991
• Status: Expired due to Term

• Current Assignee: Mitsubishi Chemical Corporation (Mitsubishi Chemical Group Corp.)
• Original Assignee: Chiyoda Corporation (Mitsubishi Corporation)
• Inventors: Kukudome, Athumi, Shimogawara, Karou, Yasui, Makoto, Watanabe, Tsuneo, Inaba, Ryuichi, Asaoka, Sachio, Yoneda, Noriyuki, Onda, Nobuhiro, Nishijima, Hiroaki, Shindo, Akio, Moriya, Nobuo, Imazeki, Takashi, Sakashita, Kouji, Maejima, Tetsuo
• Primary Examiner(s): LONE, WERREN
• Application Number:
  US08/228,871
• Time in Patent Office: 232 Days
• Field of Search: 568/722, 568/723, 568/724, 568/749
• US Class Current: 568/724
• CPC Class Codes: C07C 37/685 Processes comprising at least two steps in series
• CPC Class Codes: C07C 37/70 by physical treatment
• CPC Class Codes: C07C 37/84 by crystallisation
• CPC Class Codes: C07C 39/16 Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes

Abstract

High quality bisphenol A is produced from a neutral crystalline adduct of bisphenol A and phenol by fusing the adduct in an atmosphere having a maximum oxygen content of 0.005% by volume, followed by evaporation of liberated phenol. The crystalline adduct may be mixed with an aliphatic carboxylic acid before the fusion to reduce the coloring of the product. When an acidic crystalline adduct is used, the use of a strong alkali salt of an aliphatic carboxylic acid is suitably used. Interior surfaces of the apparatuses for carrying out the fusion and evaporation are desirably washed with an organic solvent to remove oxygen therefrom. The evaporation of phenol is suitably performed by two stage steam stripping wherein a used stripping gas obtained in the second stage is employed as a stripping gas in the first stage while steam is used as the stripping gas in the second stage.

Claims

1. A process of producing bisphenol A, comprising the steps of:

providing a crystalline adduct of bisphenol A and phenol which has an APHA color of not greater than 15 and which shows a pH of 4.9-5.5 when dissolved in an aqueous methanol solution having a pH of 5;

melting said adduct in an atmosphere having an oxygen concentration of 0.005% by volume or less to obtain a melted adduct; and

vaporizing and removing phenol from said melted product to leave bisphenol A.

2. A process of producing bisphenol A, wherein a crystalline adduct of bisphenol A and phenol having an APHA color of not greater than 15 is fed to a melting zone to melt said adduct and the melted adduct is introduced into a separation zone to separate the melted adduct into phenol and bisphenol A by evaporation of the phenol from said melted adduct, said process being characterized in that the interior surfaces of said melting zone and said separation zone which are to be contacted with said melted adduct or the phenol separated from said melted adduct are previously washed with an organic solvent for the removal of oxygen gas entrapped in said interior surfaces so that the interior surfaces have an oxygen content of 10 mmoles or less per 1 m² thereof.

3. A process as claimed in claim 2, wherein said crystalline adduct has been washed with purified phenol which has been obtained by a method including the steps of contacting raw material phenol with a strong-acid ion exchange resin to obtain treated phenol, and distilling said treated phenol to obtain purified phenol as distillate.

4. A process of producing bisphenol A, wherein a melted crystalline adduct of bisphenol A and phenol having an APHA color of not greater than 15 is introduced into a separation zone to separate the melted adduct into phenol and bisphenol A by evaporation of the phenol from said melted adduct, said process being characterized in that said separation zone is provided with a member for increasing the area of the surface with which said melted crystalline adduct is to be contacted, and that the interior surface of said separation zone and the surface of said member are previously treated for the removal of oxygen gas entrapped thereon so that the inside surface of said separation zone and the surface of said member have an oxygen content of 10 mmoles or less per 1 m² thereof.

5. A process as claimed in claim 4, wherein said separation zone is composed of two, first and second evaporation towers and wherein said melted adduct is heated in said first evaporation tower to remove a portion of the phenol by vaporization thereof without using steam and is subsequently heated in said second evaporation tower while feeding steam to said second evaporation tower to remove the remainder of phenol by vaporization thereof.

6. A process as claimed in claim 4, wherein said member is a packing material.