Lubricating oils

• US 5,372,703 A
• Filed: 04/12/1993
• Issued: 12/13/1994
• Est. Priority Date: 12/26/1989
• Status: Expired due to Term

• Current Assignee: Nippon Mitsubshi Oil Corporation
• Original Assignee: Nippon Oil Corporation (ENEOS Holdings, Inc.)
• Inventors: Kamiya, Kouzou, Oshima, Kouichi, Ikemoto, Yuji, Honjo, Isao, Yoshida, Toshio, Ushio, Masaru, Takashima, Hiroyuki, Igarashi, Jinichi, Hirata, Masakuni, Okada, Mitsuo
• Primary Examiner(s): MYERS, HELANE ELEANORA
• Application Number:
  US08/047,040
• Time in Patent Office: 610 Days
• Field of Search: 208/14, 208/19, 208/96, 208/97, 208/58, 585/6.6, 585/13
• US Class Current: 208/58
• CPC Class Codes: C10M 101/02 Petroleum fractions
• CPC Class Codes: C10M 2203/10 Petroleum or coal fractions, e.g. tars, solvents, bitumen
• CPC Class Codes: C10M 2203/102 Aliphatic fractions

Abstract

Lubricant base oils are made up essentially of 2-15% by weight of a total aromatics content, greater than 60% by weight of isoparaffins and monocyclic naphthenes in total, more than 30% by weight of alkylbenzenes in the total aromatics content and smaller than 4% by weight of tricyclic and tetracyclic aromatics in the total aromatics content. The base oil has great viscosity index, small pour point, high oxidative stability and heat stability and sufficient capability to dissolve sludge.

Claims

1. A base oil for use in lubricants which comprises:

(a) 2-15% by weight of a total aromatics content;

(b) greater than 60% by weight of isoparaffins and monocyclic naphthenes in total in a saturates content;

(c) more than 30% by weight of alkylbenzenes in the total aromatics content; and

(d) less than 4% by weight of tricyclic and tetracyclic aromatics in the total aromatics content, whereby the base oil has a viscosity index greater than 105 and a pour point lower than -10°

C.,

said base oil being produced by the steps of;

hydrocracking a starting oil fraction to a cracking ratio of higher than 40% by weight in the presence of a hydrocracking catalyst at a total pressure of less than 150 kg/cm², at a temperature of 360°

-440°

C. and at a liquid hourly space velocity of less than 0.5 hr^-1, said starting oil fraction being a whole vacuum gas oil, a heavy vacuum gas oil resulting from mild hydrocracking of a whole vacuum gas oil, or a mixture thereof;

recovering an oil fraction as hydrocracked or a lubricating cut alone; and

dewaxing the thus recovered oil fraction prior to or subsequent to dearomatization.

2. A base oil as defined in claim 1, wherein the total aromatics content is 3-10% by weight.

3. A base oil as defined in claim 1, wherein the heavy vacuum gas oil is derived by vacuum distillation of a residual oil generated upon atmospheric distillation of crude oil.

4. A base oil as defined in claim 1, wherein the heavy vacuum gas oil boils at 360°

-530°

C.

5. A base oil as defined in claim 1, wherein said mild hydrocracking is carried out at a total pressure of less than 100 kg/cm² at a temperature of 370°

-450°

C. and at a liquid hourly space velocity of 0.5-4.0 hr^-1.

6. A base oil for lubricants, said base oil having a viscosity index greater than 105 and a pour point lower than -10°

C. and comprising (i) 3-10% by weight of total aromatics content and (ii) 90% by weight or more of total saturates content, wherein said base oil has

(a) an isoparaffins plus monocyclic naphthenes content of greater than 60% by weight of total saturates content,

(b) an alkylbenzenes content of more than 30% by weight of total aromatics content, and

(c) a tricyclic and tetracyclic aromatics content of less than 4% by weight of total aromatics content.

7. A process for producing a base oil for lubricants, which comprises:

(1) hydrocracking a starting oil fraction at a rate greater than 40% by weight in the presence of a hydrocracking catalyst at a total pressure of less than 150 kg/cm², at a temperature of 360°

-440°

C. and at a liquid hourly space velocity of less than 0.5 hr^-1, said starting oil fraction being a whole vacuum gas oil, a heavy vacuum gas oil resulting from mild hydrocracking of whole vacuum gas oil, or mixtures thereof;

(2) recovering an oil fraction as hydrocracked or as a lubricating cut alone; and

dewaxing and then dearomatizing said oil fraction or dearomatizing and then dewaxing said oil fraction, thereby obtaining a base oil having a viscosity index greater than 105 and a pour point lower than -10°

C. and comprising (i) 3-10% by weight of total aromatics content and (ii) 90% by weight or more of total saturates content, wherein said base oil has

(a) an isoparaffins plus monocyclic naphthenes content of greater than 60% by weight of total saturates content,

(b) an alkylbenzenes content of more than 30% by weight of total aromatics content, and

(c) a tricyclic and tetracyclic aromatics content of less than 4% by weight of total aromatics content.

8. A process according to claim 7;

wherein the dearomatization is effected in a volume ratio of solvent to oil fraction of less than 2 with furfural used as the solvent.

9. A process according to claim 7;

wherein a raffinate is obtained in a yield of greater than 85% by weight by the dearomatization.

10. A process according to claim 7;

wherein the dearomatization is effected in a volume ratio of solvent to oil fraction of less than 2 with N-methyl-2-pyrrolidone used as the solvent.

11. A process for producing a base oil for use in lubricants, which comprises:

(1) hydrocracking a starting oil fraction at a rate greater than 40% by weight in the presence of a hydrocracking catalyst at a total pressure of less than 150 kg/cm², at a temperature of 360°

-440°

C. and at a liquid hourly space velocity of less than 0.5 hr^-1, said starting oil fraction being a whole vacuum gas oil, a heavy vacuum gas oil resulting from mild hydrocracking of whole vacuum gas oil, or a mixture thereof;

(2) recovering an oil fraction as a hydrocracking lubricating cut alone; and

(3) dewaxing and then dearomatizing said oil fraction or dearomatizing and then dewaxing said oil fraction, thereby obtaining a base oil having a viscosity index greater than 105 and a pour point lower than -10°

C. and comprising (i) 3-10% by weight of total aromatics content and (ii) 90% by weight or more of total saturates content, wherein said base oil has

(a) an isoparaffins plus monocyclic naphthenes content of greater than 60% by weight of total saturates content,

(b) an alkylbenzenes content of more than 30% by weight of total aromatics content, and

(c) a tricyclic and tetracyclic aromatics content of less than 4% by weight of total aromatics content; and

wherein said base oil possesses one of the following requirements;

(d) a viscosity index greater than 105 and a pour point lower than -10°

C. as a 70 pale cut;

(e) a viscosity index greater than 115 and a pour point lower than -10°

C. as a SAE-10 cut;

(f) a viscosity index greater than 120 and a pour point lower than -10°

C. as an SAE-20 cut;

(g) a viscosity index greater than 120 and a pour point lower than -10°

C. as an SAE-30 cut.

12. A process according to claim 11;

wherein the dearomatization is effected in a volume ratio of solvent to oil fraction of less than 2 with furfural used as the solvent.

13. A process according to claim 11;

wherein a raffinate is obtained in a yield of greater than 85% by weight by the dearomatization.

14. A process according to claim 11;

wherein the dearomatization is effected in a volume ratio of solvent to oil fraction of less than 2 with N-methyl-2-pyrrolidone used as the solvent.