UV-ray absorbing sandwich glass comprising a specific thermosetting resin composition

• US 5,372,887 A
• Filed: 02/02/1993
• Issued: 12/13/1994
• Est. Priority Date: 05/01/1989
• Status: Expired due to Term

• Current Assignee: Bridgestone Corporation
• Original Assignee: Bridgestone Corporation
• Inventors: Segawa, Masashi, Tanuma, Itsuo, Naito, Kazuo
• Primary Examiner(s): Nakarani, D. S.
• Assistant Examiner(s): LE, HOA T
• Application Number:
  US08/017,343
• Time in Patent Office: 679 Days
• Field of Search: 428/409, 428/422, 428/429, 428/441, 428/447, 428/522, 428/543, 428/913
• US Class Current: 428/409
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10688 Adjustment of the adherence to the glass layers
• CPC Class Codes: B32B 17/10788 containing ethylene vinylacetate
• CPC Class Codes: B32B 17/10862 using pressing-rolls
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 428/31 Surface property or characteristic of web, sheet or block
• CPC Class Codes: Y10T 428/31544 Addition polymer is perhalogenated
• CPC Class Codes: Y10T 428/31612 As silicone, silane or siloxane
• CPC Class Codes: Y10T 428/31645 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

A sandwich glass having high ultraviolet ray-absorbing ability is disclosed. This sandwich glass is produced by interposing a thermosetting resin between 2 glass plates to form a monolithic structure and thermosetting the resin layer, which thermosetting resin uses a benzophenone or benzotriazole series compound as an ultraviolet ray-absorbing agent in a thermosetting resin comprising an ethylene-vinyl acetate copolymer, an organic peroxide, an acryloxy group-, methacryloxy group- or allyl group-containing compound, a silane coupling agent and an ultraviolet ray-absorbing agent.

Claims

1. An ultraviolet ray-absorbing sandwich glass, comprising two glass plates and a cured resin layer interposed between the glass plates, said sandwich glass having been produced by interposing a thermosetting resin between two glass plates to form a monolithic structure, and thermosetting the resin layer interposed between the glass plates, said thermosetting resin being a homogeneous composition consisting essentially of:

(1) an ethylene-vinyl acetate copolymer,

(2) an organic peroxide,

(3) a member selected from the group consisting of an acryloxy group-containing compound, methacryloxy group-containing compound and allyl group-containing compound,

(4) a silane coupling agent, and

(5) 5 parts by weight or less of 2,2'"'"'-dihydroxy-4-methoxybenzophenone, based on 100 parts by weight of the ethylene-vinyl acetate copolymer.

2. An ultraviolet ray-absorbing sandwich glass according to claim 1, wherein said ethylene-vinyl acetate copolymer contains 15-50% by weight of vinyl acetate unit.

3. An ultraviolet ray-absorbing sandwich glass according to claim 2, wherein said ethylene-vinyl acetate copolymer contains 19-40% by weight of vinyl acetate unit.

4. An ultraviolet ray-absorbing sandwich glass according to claim 1, wherein said ethylene-vinyl acetate copolymer contains a member of the group consisting of acryloxy group-containing compound, methacryloxy group-containing compound and allyl group-containing compound as a curing aid in an amount of 50% by weight or less based on the amount of the ethylene-vinyl acetate copolymer.

5. An ultraviolet ray-absorbing type sandwich glass according to claim 4, wherein said member is selected from the group consisting of ester and amide of acrylic acid or methacrylic acid.

6. An ultraviolet ray-absorbing sandwich glass according to claim 1, wherein the silane coupling agent is contained in the resin as an adhesive force-improver of the resin to glass in an amount of 5 parts by weight or less based on 100 parts by weight of the ethylenevinyl acetate copolymer.

7. An ultraviolet ray-absorbing type sandwich glass according to claim 1, further comprising 5 parts by weight or less of a polymerization inhibitor selected from the group consisting of hydroquinone, hydroquinone monomethylether, p-benzoquinone and methylhydroquinone based on 100 parts by weight of the ethylene-vinyl acetate copolymer.