Resin compositions for laser marking

• US 5,373,039 A
• Filed: 05/25/1993
• Issued: 12/13/1994
• Est. Priority Date: 05/29/1992
• Status: Expired due to Term

• Current Assignee: Sabic Innovative Plastics IP BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company
• Inventors: Sakai, Kenichi, Kato, Hideki, Kitamura, Takuro
• Primary Examiner(s): Morgan, Kriellion S.
• Application Number:
  US08/066,797
• Time in Patent Office: 567 Days
• Field of Search: 430/292, 430/298, 522/75, 522/78, 524/100, 524/173, 524/259, 524/424
• US Class Current: 524/100
• CPC Class Codes: B41M 5/267 Marking of plastic artifacts, e.g. with laser
• CPC Class Codes: C08K 3/04 Carbon
• CPC Class Codes: C08K 5/0008 Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59

Abstract

A resin composition suitable for marking with a laser and a method for laser marking said resin are provided. The resin composition comprises a thermoplastic resin, one or more compounds selected from the group consisting essentially of (i) tetrazole compounds, and (ii) sulfonylhydrazide, nitroso and azo compounds having a decomposition temperature of at least 210° C., and carbon black.

Claims

1. A resin composition for laser marking, comprising:

[A] a thermoplastic resin.

[B] one or more compounds selected from the group consisting essentially of tetrazole compounds, and also sulfonylhydrazide compounds, nitroso compounds and azo compounds having a decomposition temperature of 210°

C. or more, and

[C] carbon black.

2. A resin composition for laser marking according to claim 1, which composition contains also a flame-retarding agent.

3. A resin composition comprising

(A) a thermoplastic resin;

and

(B) one or more compounds selected from the group consisting essentially of

(i) tetrazole compounds,

(ii) sulfonylhydrazide, nitroso and azo compounds having a decomposition temperature of 210°

C. or more, and

(C) carbon black.

4. A resin composition according to claim 3, wherein said thermoplastic resin is selected from the group consisting essentially of polyethylene terephthalate, polybutylene terephthalate, polycyclohexane terephthalate, polyphenylene oxide, polycarbonate, polyether imide, polystyrene, polyethylene, polypropylene, polyamide, polyvinyl chloride, polyacetal, fluororesins, acrylic resins, polysulfones, polyphenylene sulfides, methylpentene resins, and mixtures thereof.

5. A resin composition according to claim 3, wherein said tetrazole compound is selected from the group consisting essentially of substituted 1H-tetrazole compounds, substituted 2H-tetrazole compounds, and the metal salts of said substituted compounds.

6. A resin composition according to claim 5 wherein said tetrazole compound is selected from the group consisting essentially of the calcium salt of tetrazole, the calcium salt of 5-amino-1H-tetrazole, the calcium and barium salts of 5-methyl-1H-tetrazole, and the calcium salt of 5,5'"'"'-bis-1H-tetrazole.

7. A resin composition according to claim 5 wherein said tetrazole compound comprises from about 0.001 to about 10 parts by weight per 100 parts by weight of the thermoplastic resin.

8. A resin composition according to claim 3 further comprising a flame retardant.

9. A resin composition according to claim 8, wherein said flame retardant is selected from the consisting essentially of brominated imides, brominated polycarbonates, brominated epoxy compounds, brominated bisphenol A compounds, brominated polyphenylene oxides, triphenylphosphates and Sb₂ O₃.

10. A resin composition according to claim 3 further comprising a reinforcing agent.

11. A resin composition according to claim 10 wherein said reinforcing agent is selected from the group consisting essentially of glass fibers, carbon fibers and aramid fibers.

12. A resin composition according to claim 10 wherein said reinforcing agent comprises 0 to 100 parts by weight per 100 parts by weight of the thermoplastic resin.

13. A method of marking a resin composition the steps of preparing a resin composition of

(A) a thermoplastic resin,

(B) one or more compounds selected from the group consisting essentially of

(i) tetrazole compounds, and

(ii) sulfonylhydrazide, nitroso and azo compounds having a decomposition temperature of 210°

C. or more, and

(C) carbon black, and irradiating at least a portion of a surface of the resin composition with a laser.

14. A method according to claim 13 wherein said laser is selected from the group consisting essentially of CO₂ lasers and YAG lasers.