Casting epoxy resin, polythiol and releasing agent to form lens
First Claim
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1. A polysulfide based resin lens having a refractive index of 1.58 to 1.66, comprising forming a mixture consisting essentially of:
- a) at least one epoxy resin, which has at least two epoxy groups selected from the group consisting of (i) amine based epoxy resins, (ii) phenol based epoxy resins, (iii) alcohol based epoxy resins, (iv) epoxylated products of unsaturated compounds, (v) glycidyl ester based epoxy resins, (vi) urethane based epoxy resins, (vii) alicyclic epoxy resins, and (viii) heterocyclic ring-containing epoxy resins;
b) at least one polythiol compound which has at least two mercapto groups, selected from the group consisting of (i) aliphatic polythiols, (ii) aromatic polythiols, (iii) heterocyclic ring-containing polythiols, (iv) aliphatic polythiols containing sulfur atoms in addition to mercapto groups, (v) aromatic polythiols containing sulfur atoms in addition to mercapto groups and (vi) heterocyclic ring-containing polythiols containing sulfur atoms in addition to mercapto groups, the mole ratio of the mercapto groups in the polythiol compounds to the epoxy resin being from 0.2 to 1.2 moles of mercapto groups per mole of the sum of functional epoxy groups; and
c) at least one internal releasing agent selected from the group consisting of phosphoric acid esters, alkyl quaternary ammonium salts, silicon based nonionic surface active agents and fluorine based nonionic surface active agents, at a concentration of 1 to 10,000 ppm per the total weight of the epoxy resin and the polythiol compound, and then cast-polymerizing said mixture in a mold, and releasing a lens from the mold.
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Abstract
The present invention relates to a polysulfide based resin lens, comprising a mixture of at least one epoxy resin having at least two epoxy groups, and at least one polythiol compound having at least two mercaptan groups, and at least one internal release agent, which is cast polymerized, and the process for preparing the same.
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Citations
6 Claims
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1. A polysulfide based resin lens having a refractive index of 1.58 to 1.66, comprising forming a mixture consisting essentially of:
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a) at least one epoxy resin, which has at least two epoxy groups selected from the group consisting of (i) amine based epoxy resins, (ii) phenol based epoxy resins, (iii) alcohol based epoxy resins, (iv) epoxylated products of unsaturated compounds, (v) glycidyl ester based epoxy resins, (vi) urethane based epoxy resins, (vii) alicyclic epoxy resins, and (viii) heterocyclic ring-containing epoxy resins; b) at least one polythiol compound which has at least two mercapto groups, selected from the group consisting of (i) aliphatic polythiols, (ii) aromatic polythiols, (iii) heterocyclic ring-containing polythiols, (iv) aliphatic polythiols containing sulfur atoms in addition to mercapto groups, (v) aromatic polythiols containing sulfur atoms in addition to mercapto groups and (vi) heterocyclic ring-containing polythiols containing sulfur atoms in addition to mercapto groups, the mole ratio of the mercapto groups in the polythiol compounds to the epoxy resin being from 0.2 to 1.2 moles of mercapto groups per mole of the sum of functional epoxy groups; and c) at least one internal releasing agent selected from the group consisting of phosphoric acid esters, alkyl quaternary ammonium salts, silicon based nonionic surface active agents and fluorine based nonionic surface active agents, at a concentration of 1 to 10,000 ppm per the total weight of the epoxy resin and the polythiol compound, and then cast-polymerizing said mixture in a mold, and releasing a lens from the mold. - View Dependent Claims (2, 3, 4, 5, 6)
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Specification