Image-receiving element for thermal dye transfer method

• US 5,380,695 A
• Filed: 04/22/1994
• Issued: 01/10/1995
• Est. Priority Date: 04/22/1994
• Status: Expired due to Term

• Current Assignee: Yama Capital, LLC
• Original Assignee: Polaroid Corporation (PLR IP Holdings LLC)
• Inventors: Chiang, Yunn H., Gaudiana, Russell A.
• Primary Examiner(s): HESS, BRUCE H
• Application Number:
  US08/231,119
• Time in Patent Office: 263 Days
• Field of Search: 283/75, 283/109, 428/195, 428/203, 428/204, 428/500, 428/532, 428/913, 503/227
• US Class Current: 503/227
• CPC Class Codes: B41M 3/14 Security printing securities B42D25/29
• CPC Class Codes: B41M 5/40 characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography macromolecular ink- or dye-receptive coatings B41M5/52
• CPC Class Codes: B41M 5/42 Intermediate, backcoat, or covering layers B41M5/405 takes precedence; multilayer thermal transfer systems in general B41M5/38214
• CPC Class Codes: B42D 25/00 Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof printing processes to produce identification or security features B41M3/14
• CPC Class Codes: B42D 25/382 absorbing or reflecting infrared light
• CPC Class Codes: B42D 25/387 absorbing or reflecting ultraviolet light
• CPC Class Codes: B42D 25/45 Associating two or more layers
• CPC Class Codes: B42D 25/47 using adhesives
• CPC Class Codes: B42D 3/14 with column markers or line or heading indicators with devices for indicating a page
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 428/24868 Translucent outer layer
• CPC Class Codes: Y10T 428/24876 Intermediate layer contains particulate material [e.g., pigment, etc.]
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31971 Of carbohydrate

Abstract

An image-receiving element and a method of using same in the production of images by thermal dye transfer processing, the image-receiving element comprising a support, a polymeric security layer having a printed security layer, and an image-receiving layer for receiving dye by thermal transfer from a dye donor sheet, the polymeric security layer having cohesivity less than its adhesivity for each layer contiguous and the printed security pattern being destroyed by an attempted delamination of the image-receiving layer from the image-receiving element.

Claims

1. An image-receiving element for the production of a dye image by thermal dye transfer, the image-receiving element comprising in order:

a support sheet;

a polymeric cohesively destructible security layer having a printed security pattern comprising a patterning agent and a binder therefor; and

an image-receiving layer for receiving an image in dye by a thermal transfer from a dye donor sheet;

said polymeric cohesively destructible security layer pattern being characterized by a cohesivity less than the adhesivity of such layer for each layer contiguous thereto, said printed security pattern being destroyed by attempted delamination of said image-receiving layer from said image-receiving element.

2. The image-receiving element of claim 1 wherein said printed security pattern upon said attempted delamination is partitioned between respective cohesively failed portions of said destructible layer adhered to each of opposed layers contiguous to said destructible polymeric layer.

3. The image-receiving element of claim 2 wherein said printed security pattern is a fine-line printed pattern in a thickness of from 0.5 to 4μ

.

4. The image-receiving element of claim 3 wherein said binder for said patterning agent comprises a polymeric binder having adhesivity for each of said polymeric destructible layer and said image-receiving layer.

5. The image-receiving element of claim 4 wherein said binder comprises hydroxypropylcellulose.

6. The image-receiving element of claim 5 wherein said patterning agent comprises an IR-absorbing dye or a dye which fluoresces under ultraviolet irradiation.

7. The image-receiving element of claim 4 wherein said patterning agent comprises a colored pigment or dye.

8. The image-receiving element of claim 4 wherein said destructible security layer comprises styrenated acrylic polymer.

9. The image-receiving element of claim 8 wherein said image-receiving layer comprises polyvinyl chloride.

10. A method of preparing an identification document secure against tampering and including the steps of:

providing an image-receiving element comprising, in order, a support sheet;

a polymeric cohesively destructible security layer having a printed security pattern comprising a patterning agent and a binder therefor; and

an image-receiving layer for receiving an image in dye by a thermal transfer from a dye donor sheet;

said polymeric cohesively destructible security layer being characterized by a cohesivity less than the adhesivity of such layer for each layer contiguous thereto, and said security pattern being destroyed by attempted delamination of said image-receiving layer from said image-receiving element;

contacting the image-receiving layer of said image-receiving element with a dye donor sheet comprising a support and a thermally transferable dye;

imagewise transferring said dye of said dye donor sheet to the image-receiving layer of said image-receiving element, thereby to provide a dye image-bearing layer; and

separating said donor sheet and said image-bearing element from each other.

11. The method of claim 10 wherein said printed security pattern of said image-receiving element, upon said attempted delamination, is partitioned between respective cohesively failed portions of said destructible layer adhered to each of opposed layers contiguous to said destructible polymeric layer.

12. The method of claim 10 wherein said binder for said patterning agent comprises a polymeric binder having adhesivity for each of said polymeric destructible layer and said image-receiving layer.

13. The method of claim 10 wherein said binder comprises hydroxypropylcellulose.

14. The method of claim 13 wherein said patterning agent comprises a colored pigment or dye.

15. The method of claim 14 wherein said patterning agent comprises an IR-absorbing dye or a dye which fluoresces under ultraviolet irradiation.

16. The method of claim 15 wherein said destructible security layer comprises styrenated acrylic polymer.

17. The method of claim 16 wherein said image-receiving layer comprises polyvinyl chloride.

18. The method of claim 10 including the additional step of laminating a protective polymeric layer or sheet to said image-bearing surface.

19. The method of claim 18 wherein said protective polymeric layer or sheet comprises a sheet of polyvinyl chloride.