Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution

• US 5,382,630 A
• Filed: 02/04/1993
• Issued: 01/17/1995
• Est. Priority Date: 09/30/1988
• Status: Expired due to Term

• Current Assignee: Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Original Assignee: Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: Welborn, Curtis H. Jr., Stehling, Ferdinand C., Speed, Charles S.
• Primary Examiner(s): Seccuro, Jr., Carman J.
• Application Number:
  US08/014,094
• Time in Patent Office: 712 Days
• Field of Search: 525/240
• US Class Current: 525/240
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 2205/025 containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
• CPC Class Codes: C08L 23/0815 Copolymers of ethene with aliphatic 1-olefins
• CPC Class Codes: C08L 23/16 Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
• CPC Class Codes: C08L 2314/06 Metallocene or single site catalysts
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

Abstract

Linear ethylene interpolymer blends are disclosed. The blends are made from components having a narrow molecular weight distribution (e.g. M_w /M_n ≦3) and a narrow composition distribution (e.g. CDBI>50%). The blend components in a blend can all have the same molecular weight but different comonomer contents, the same comonomer content but different molecular weights, or comonomer contents which increase with molecular weight. The blends have either M_w /M_n >3 or CDBI<50%, or both, and can be multimodal with respect to either or both molecular weight and/or comonomer content. The blends are generally free of blend components having both a higher average molecular weight and a lower average comonomer content than another blend component. The blends can have improved mechanical, physical and/or chemical properties.

Claims

1. A polymer blend composition comprising:

a plurality of linear ethylene interpolymer components comprising ethylene and at least one alpha-olefin comonomer, each component having a different average molecular weight, a Mw/Mn≦

3, a composition distribution breadth index of at least 50% and a density greater than or equal to 0.900 g/cm³ ;

the composition having a density greater than or equal to 0.900 g/cm³ and a Mw/Mn>

3;

wherein the composition is essentially free of components having a higher average molecular weight and a lower average comonomer content than that of any other components.

2. The composition of claim 1, wherein said composition has a density in the range of 0.900 to 0.94 g/cm³.

3. The composition of claim 1, wherein said components have an α

-olefin comonomer content in the range of 1 to 30 mole percent and an ethylene content in the range of 99 to 70 mole percent.

4. The composition of claim 1, wherein said components are selected from the group consisting of:

very low density linear polyethylenes; and

linear, low density polyethylenes.

5. The blend of claim 1, wherein the blend components have essentially the same comonomer content and different molecular weights.

6. The composition of claim 1, wherein the molecular weights and the comonomer contents of the components are both different.

7. The composition of claim 1, wherein the value of M.sub. /M_n for each component is less than or equal to 2.5.

8. The composition of claim 1, wherein the composition distribution breadth index for each component is greater than about 70%.

9. A polymer blend comprising:

a plurality of linear ethylene interpolymer components comprising ethylene and at least one alpha-olefin comonomer, each component having a different average molecular weight, a narrow molecular weight distribution such that Mw/Mn≦

3, a composition distribution breadth index of at least 50% and a density greater than or equal to 0.900 g/cm³ ; and

said components are selected from one of the groups consisting of;

(1) components having essentially the same average comonomer content but different average molecular weights; and

(2) components having different average molecular weights and comonomer contents; and

wherein said blend has a density greater than or equal to 0.900 g/cm³ and a Mw/Mn≦

3 wherein the blend is essentially free of blend components having both a higher average molecular weight and a lower average comonomer content than that of any other component and said blend has a density greater than or equal to 0.900 g/cm³.

10. The blend of claim 9, wherein the blend has a density of 0.900 to 0.94 g/cm³.

11. The blend of claim 9, wherein said components each have an average molar α

-olefin comonomer content of 1-30 percent.

12. The blend of claim 11, wherein said components include very low density, linear polyethylenes.

13. The blend of claim 11, wherein said components include linear, low density polyethylenes.

14. The blend of claim 9, wherein the number of said components is from 2 to 5.

15. The blend of claim 9, wherein the blend has plural modality with respect to molecular weight, comonomer content or both.

16. The blend of claim 11, wherein said α

-olefins have from 3 to about 12 carbon atoms.

17. The blend of claim 9 wherein each of said components have a Mw/Mn<

2.5 and a composition distribution breadth index in the range from 50 to 70%.

18. The blend of claim 17, wherein M_w /M_n ≦

2.0 for each component.

19. The blend of claim 17, wherein each component has a composition distribution breadth index in the range of from 50 to 90%.

20. A polymer blend composition comprising:

a plurality of ethylene interpolymers comprising ethylene and at least one α

-olefin comonomer, each of said components having a different average molecular weight, a Mw/Mn≦

3, a CDBI of at least 50% and a density greater than or equal to 0.900 g/cm³ ;

the composition having a density in the range of greater than or equal to 0.900 g/cm³ to 0.940 g/cm³ and a Mw/Mn≦

3;

wherein the composition is essentially free of blend components having both a higher average molecular weight and a lower average comonomer content than that of any other component.

21. The composition of claim 20 wherein said components have an α

-olefin comonomer content in the range of 1 to 30 mole percent and an ethylene content in the range of 99 to 70 mole percent.

22. The composition of claim 20 wherein said components have essentially the same comonomer content and different molecular weights.

23. The composition of claim 20 wherein said components have both a different molecular weight and comonomer content.

24. The composition of claim 20 wherein each of said components have a Mw/Mn less than or equal to 2.5.

25. The composition of claim 20 wherein each of said components have a CDBI greater than about 60%.

26. The composition of claim 20 wherein each of said components have a CDBI greater than 70%.

27. The composition of claim 20 wherein at least one of said components has a CDBI greater than 70%.

28. The composition of claim 20 wherein said components consist of at least one of the group of very low density linear polyethylenes and linear low density polyethylenes.

29. The composition of claim 20 wherein said components have a Mw/Mn≦

2.5 and a CDBI greater than 70%.

30. A polymer blend composition comprising:

a plurality of ethylene interpolymer components comprising ethylene and at least one α

-olefin comonomer, each of said components having a different average molecular weight, a Mw/Mn≦

3, a CDBI greater than 50% and a density greater than or equal to 0.900 g/cm³ ;

said composition having a density in the range of about 0.900 g/cm³ to about 0.940 g/cm³, a Mw/Mn>

3 and a CDBI greater than 50%;

wherein the composition is essentially free of said components having both a higher average molecular weight and a lower average comonomer content than that of any other component.

31. The composition of claim 30 wherein said components have an α

-olefin comonomer content in the range of 1 to 30 mole percent and an ethylene content in the range of 99 to 70 mole percent.

32. The composition of claim 30 wherein said components have essentially the same comonomer content and different molecular weights.

33. The composition of claim 30 wherein said components have both a different molecular weight and comonomer content.

34. The composition of claim 30 wherein each of said components have a Mw/Mn less than or equal to 2.5.

35. The composition of claim 30 wherein each of said components have a CDBI greater than about 60%.

36. The composition of claim 30 wherein each of said components have a CDBI greater than 70%.

37. A polymer blend composition comprising:

a plurality of linear ethylene interpolymer components comprising ethylene and at least one C₃ -C₁₂ α

-olefin comonomer, each of said interpolymers having a different average molecular weight, a Mw/Mn≦

3 and a CDBI greater than 50% and a density greater than or equal to 0.900 g/cm³ ;

a high density polyethylene component;

said composition having a density greater than or equal to 0.900 g/cm³, and a Mw/Mn≦

3;

wherein the composition is essentially free of said components having both a higher average molecular weight and a lower average comonomer content than that of any other component.

38. The composition of claim 37 wherein said interpolymer components have a CDBI of at least 60%.

39. The composition of claim 37 wherein at least one of said interpolymer components has a CDBI of at least 70%.

40. The composition of claim 37 wherein the composition has a density in the range of 0.900 g/cm³ to about 0.940 g/cm³.