Process for the production of bishenol A
First Claim
1. A process for condensing a gaseous mixture of steam, phenol and bisphenol A maintained at a pressure of 30 Torr or less, comprising the steps of:
- introducing said gaseous mixture into a first cooling zone maintained at a pressure of 30 Torr or less and such a temperature that said steam is prevented from condensing while a portion of said phenol is condensed, wherein said gas is brought into counter-current contact with a first liquid cooling medium to condense substantially all of said bisphenol A and part of said phenol and thereby obtain a mixed gas containing uncondensed steam and uncondensed phenol, said first liquid cooling medium being phenol or bisphenol A-containing phenol;
introducing said mixed gas into a second cooling zone maintained at a pressure of 30 Torr or less and such a temperature that substantially all of said mixed gas is condensed, wherein said gas is brought into counter-current contact with a second liquid cooling medium to condense substantially all of said mixed gas and thereby obtain a condensate-containing liquid, said second liquid cooling medium being an aqueous solution of phenol.
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Abstract
High quality bisphenol A is produced from a neutral crystalline adduct of bisphenol A and phenol by fusing the adduct in an atmosphere having a maximum oxygen content of 0.005 % by volume, followed by evaporation of liberated phenol. The crystalline adduct may be mixed with an aliphatic carboxylic acid before the fusion to reduce the coloring of the product. When an acidic crystalline adduct is used, the use of a strong alkali salt of an aliphatic carboxylic acid is suitably used. Interior surfaces of the apparatuses for carrying out the fusion and evaporation are desirably washed with an organic solvent to remove oxygen therefrom. The evaporation of phenol is suitably performed by two stage steam stripping wherein a used stripping gas obtained in the second stage is employed as a stripping gas in the first stage while steam is used as the stripping gas in the second stage.
20 Citations
3 Claims
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1. A process for condensing a gaseous mixture of steam, phenol and bisphenol A maintained at a pressure of 30 Torr or less, comprising the steps of:
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introducing said gaseous mixture into a first cooling zone maintained at a pressure of 30 Torr or less and such a temperature that said steam is prevented from condensing while a portion of said phenol is condensed, wherein said gas is brought into counter-current contact with a first liquid cooling medium to condense substantially all of said bisphenol A and part of said phenol and thereby obtain a mixed gas containing uncondensed steam and uncondensed phenol, said first liquid cooling medium being phenol or bisphenol A-containing phenol; introducing said mixed gas into a second cooling zone maintained at a pressure of 30 Torr or less and such a temperature that substantially all of said mixed gas is condensed, wherein said gas is brought into counter-current contact with a second liquid cooling medium to condense substantially all of said mixed gas and thereby obtain a condensate-containing liquid, said second liquid cooling medium being an aqueous solution of phenol. - View Dependent Claims (2, 3)
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Specification
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- Resources
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Current AssigneeMitsubishi Chemical Corporation (Mitsubishi Chemical Group Corp.)
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Original AssigneeChiyoda Corporation (Mitsubishi Corporation)
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InventorsYasui, Makoto, Watanabe, Tsuneo, Inaba, Ryuichi, Asaoka, Sachio, Yoneda, Noriyuki, Onda, Nobuhiro, Nishijima, Hiroaki, Shindo, Akio, Moriya, Nobuo, Imazeki, Takashi, Kukidome, Athumi, Shimogawara, Kaoru, Sakashita, Kouji, Maejima, Tetsuo
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Primary Examiner(s)LONE, WERREN
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Application NumberUS08/229,349Time in Patent Office274 DaysField of Search568/722, 568/723, 568/724, 568/749US Class Current568/722CPC Class CodesC07C 37/685 Processes comprising at lea...C07C 37/70 by physical treatmentC07C 37/84 by crystallisationC07C 39/16 Bis-(hydroxyphenyl) alkanes...
