Process for the production of bisphenol A

• US 5,382,712 A
• Filed: 04/18/1994
• Issued: 01/17/1995
• Est. Priority Date: 07/16/1991
• Status: Expired due to Term

• Current Assignee: Mitsubishi Chemical Corporation (Mitsubishi Chemical Group Corp.)
• Original Assignee: Chiyoda Corporation (Mitsubishi Corporation)
• Inventors: Yasui, Makoto, Inaba, Ryuichi, Onda, Nobuhiro, Nishijima, Hiroaki, Shindo, Akio, Imazeki, Takashi, Kukidome, Athumi, Shimogawara, Kaoru, Sakashita, Kouji, Maejima, Tetsuo, Watanabe, Tsuneo, Asaoka, Sachio, Yoneda, Noriyuki, Moriya, Nobuo
• Primary Examiner(s): LONE, WERREN
• Application Number:
  US08/229,348
• Time in Patent Office: 274 Days
• Field of Search: 568/724, 568/723, 568/727, 568/728
• US Class Current: 568/724
• CPC Class Codes: C07C 37/685 Processes comprising at least two steps in series
• CPC Class Codes: C07C 37/70 by physical treatment
• CPC Class Codes: C07C 37/84 by crystallisation
• CPC Class Codes: C07C 39/16 Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes

Abstract

High quality bisphenol A is produced from a neutral crystalline adduct of bisphenol A and phenol by fusing the adduct in an atmosphere having a maximum oxygen content of 0.005% by volume, followed by evaporation of liberated phenol. The crystalline adduct may be mixed with an aliphatic carboxylic acid before the fusion to reduce the coloring of the product. When an acidic crystalline adduct is used, the use of a strong alkali salt of an aliphatic carboxylic acid is suitably used. Interior surfaces of the apparatuses for carrying out the fusion and evaporation are desirably washed with an organic solvent to remove oxygen therefrom. The evaporation of phenol is suitably performed by two stage steam stripping wherein a used stripping gas obtained in the second stage is employed as a stripping gas in the first stage while steam is used as the stripping gas in the second stage.

Claims

1. A process of producing bisphenol A, comprising the steps of:

providing a crystalline adduct of bisphenol A and phenol which has an APHA color of not greater than 15 and which shows a pH of 4.9-5.5 when dissolved in an aqueous methanol solution having a pH of 5;

mixing said adduct with an aliphatic carboxylic acid to obtain a mixture containing 1-100 ppm of the aliphatic carboxylic acid based on the weight of said adduct; and

heating said mixture at a temperature of 130°

-200°

C. under a reduced pressure to vaporize and remove phenol from said mixture and thereby leave bisphenol A.

2. A process as claimed in claim 1 wherein said aliphatic carboxylic acid is selected from the group consisting of formic acid, glycollic acid, oxalic acid, citric acid, lactic acid, malic acid, glyceric acid and tartaric acid.

3. A process as claimed in claim 1, wherein said crystalline adduct has been subjected to recrystallization from phenol and washed with purified phenol.

4. A process of producing bisphenol A, comprising the steps of:

providing a crystalline adduct of bisphenol A and phenol which has an APHA color of not greater than 15, which contains a strong acid and which shows a pH of smaller than 5 but not smaller than 4 when dissolved in an aqueous methanol solution having a pH of 5;

mixing said adduct with a salt of an aliphatic carboxylic acid to obtain a mixture, said salt being used in an amount so that said mixture shows a pH of about 5 when dissolved in an aqueous methanol solution having a pH of 5; and

heating said mixture at a temperature of 130°

-200°

C. under a reduced pressure to vaporize and remove phenol from said mixture and thereby leave bisphenol A.

5. A process as claimed in claim 4 wherein said aliphatic carboxylic acid salt is an alkali metal, alkaline earth metal or ammonium salt of an acid selected from the group consisting of formic acid, glycollic acid, oxalic acid, citric acid, lactic acid, malic acid, glyceric acid and tartaric acid.

6. A process as claimed in claim 4, wherein said crystalline adduct has been subjected to recrystallization from phenol and washed with purified phenol.