Catalyst carrier

• US 5,384,302 A
• Filed: 09/08/1993
• Issued: 01/24/1995
• Est. Priority Date: 09/08/1993
• Status: Expired due to Term

• Current Assignee: Norton Chemical Process Products Corporation
• Original Assignee: Norton Chemical Process Products Corporation
• Inventors: Wolford, James A., Szymanski, Thomas, Gerdes, William H., Remus, Donald J.
• Primary Examiner(s): KONOPKA, PAUL
• Application Number:
  US08/118,487
• Time in Patent Office: 503 Days
• Field of Search: 502/439, 502/355, 502/351, 423/628
• US Class Current: 502/439
• CPC Class Codes: B01J 21/04 Alumina
• CPC Class Codes: B01J 37/0009 Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst

Abstract

A catalyst carrier that is comprised of relatively large alpha alumina particles dispersed in matrix that comprises an alpha alumina formed in situ by a sol-gel process has excellent crush resistance while retaining good porosity and catalytic performance.

Claims

1. An alpha alumina based catalyst carrier having a crush strength of at least 5 pounds and a packing density of at least 38 pounds/cubic foot which comprises first and second alpha alumina components with a first alpha alumina component in the form of particles having an median crystallite size of from about 0.4 to about 4 microns providing from about 95 to about 40% of the total weight of alpha alumina in the carrier and a second alpha alumina component generated in situ by a sol-gel process and providing the balance of the alpha alumina in the carrier.

2. A catalyst carrier according to claim 1 in which the first alpha alumina component comprises a larger particle size component and a smaller particle size component in which the larger component provides from about 10 to about 90% by weight of the first component weight in the form of particles with a median particle size less than 4 and greater than 2.5 microns and a average crystallite size of from about 1.5 to about 2.5 microns, and a smaller component providing from about 90 to about 10% by weight of the first component in the form of particles with a median particle size greater than 4 and less than about 10 microns and an average crystallite size of from about 0.4 to about 0.8 micron.

3. A catalyst carrier according to claim 1 in which the second alpha alumina component is generated by a seeded sol-gel process.

4. A catalyst carrier according to claim 3 in which the sol-gel alumina is seeded with an effective amount of sub-micron alpha alumina seed.

5. A catalyst carrier according to claim 1 which further comprises from about 0.08 to about 0.5%, based on the weight of alumina in the carrier, of added titania.

6. A catalyst carrier according to claim 5 in which the titania has a surface area of at least 8 square meters per gram.

7. A catalyst carrier according to claim 1 comprising a pore volume of from about 0.3 to about 0.6 cc. Hg/gram.

8. A catalyst carrier according to claim 1 which further comprises a ceramic bond material in an amount that is from about 1 to about 3% of the weight of the alumina components, expressed as alpha alumina, in the carrier.

9. A catalyst carrier having a crush strength of at least 5 pounds and a settled pack density of at least 35 pounds/cubic foot which comprises first and second alpha alumina components;

wherein the first alpha alumina component has two constituents including;

i) a first constituent providing from about 40 to about 80% by weight of the first alpha alumina component and having a median particle size of from about 3 to about 4 microns; and

ii) a second constituent providing from about 20 to about 60% of the weight of the first alpha alumina component and having a median particle size of from about 4 to about 8 microns;

said first alpha alumina component providing from about 95 to about 65% of the total weight of alpha alumina in the carrier and;

a second alpha alumina component generated in situ by a sol-gel process and providing the balance of the alpha alumina in the carrier.

10. A catalyst carrier according to claim 9 which further comprises from about 0.05 to about 0.5 % by weight of titania.

11. A process for the production of a catalyst carrier which comprises:

i) forming a mixture comprising;

a. at least one alpha alumina component with an median particle size of from 3 to about 8 microns and;

b. a hydrated precursor of alpha alumina in an amount sufficient to provide from about 5 to about 60% by weight of the total weight of alpha alumina in the catalyst carrier product;

c. from about 5 to about 40%, based on the weight of the alpha alumina, of a burnout material; and

d. water in sufficient quantity to extrude the above mixture;

ii) extruding the mixture into the desired shapes; and

iii) firing to convert the precursor of alpha alumina to alpha alumina so as to produce a catalyst carrier in which alpha alumina particles with a median particle size of from about 3 to about 8 microns are dispersed in a matrix of alpha alumina derived from the precursor material.

12. A process according to claim 11 in which the precursor of alpha alumina comprises a boehmite.

13. A process according to claim 11 in which the precursor of alpha alumina comprises alumina trihydrate.

14. A process according to claim 11 in which the precursor of alpha alumina is seeded with sub-micron sized particles of alpha alumina in an amount that is from about 0.2 to about 5% by weight based on the total alumina weight, measured as alpha alumina, in the catalyst carrier.

15. A process according to claim 11 in which from about 0.05 to about 0.5% based on the total weight of alumina in the formulation expressed as alpha alumina, of titania is added to the mixture to be extruded.

16. A process according to claim 11 in which a ceramic bond material is added to the extrudable mixture in an amount that is from about 1 to about 3% of the weight of the alumina components, expressed as alpha alumina, in the mixture.

17. A process for the production of a catalyst carrier which comprises:

i) forming a mixture comprising;

a. an alpha alumina having a first component with a median particle size of from about 2 to about 4 microns and a second component with a median particle size of about 4 to about 8 microns;

b. a seeded, hydrated precursor of alpha alumina in an amount sufficient to provide from about 5 to about 60% by weight of the total weight of alpha alumina in the catalyst carrier product

c. from about 5 to about 40%, based on the weight of the alpha alumina, of a burnout material;

d. from about 1 to about 3% based on the weight of alumina in the composition expressed as alpha alumina, of a ceramic bond material;

e. from about 0.05 to about 0.5% by weight, based on the total alumina weight in the mixture expressed as alpha alumina, of titania; and

f. water in sufficient quantity to extrude the above mixture;

ii) extruding the mixture into the desired shape; and

iii) firing to convert the seeded precursor of alpha alumina to alpha alumina so as to produce a catalyst carrier in which alpha alumina particles with a median particle size of from about 3 to about 8 microns are dispersed in a matrix of alpha alumina derived from the seeded precursor material.

18. A process according to claim 17 in which the precursor of alpha alumina comprises a boehmite.

19. A process according to claim 17 in which the precursor of alpha alumina further comprises from about 10 to about 35% by weight of alumina trihydrate, measured as the alpha alumina equivalent, based on the total weight of alpha alumina in the carrier product.

20. A process according to claim 17 in which the precursor of alpha alumina is seeded with a sub-micron sized particles of alpha alumina in an amount that is from about 0.2 to about 5% by weight based on the total alumina weight, measured as alpha alumina, in the catalyst carrier.