Epoxy based balancing compound and method for balancing a rotor utilizing an ultraviolet-curable epoxy resin composition

• US 5,384,339 A
• Filed: 03/09/1993
• Issued: 01/24/1995
• Est. Priority Date: 03/09/1993
• Status: Expired due to Term

• Current Assignee: Donn R. Starkey
• Original Assignee: Donn R. Starkey
• Inventors: Starkey, Donn R.
• Primary Examiner(s): Berman, Susan W.
• Application Number:
  US08/028,217
• Time in Patent Office: 686 Days
• Field of Search: 152/425, 156/64, 156/330, 522/24, 522/170, 522/3, 522/25, 522/31, 522/74, 522/77, 522/80, 522/81, 522/83
• US Class Current: 522/3
• CPC Class Codes: C08G 59/68 characterised by the catalysts used
• CPC Class Codes: H01B 3/40 epoxy resins

Abstract

A balancing compound comprising an epoxy resin, a photoinitiator in an effective amount to cure the resin at ambient temperatures upon the application of ultraviolet light (10 nm to 400 nm) of less than 40 watts per square centimeter in less than about 30 seconds, and a filler in an effective amount to give the compound a specific gravity above 1.1.

Claims

1. A method of balancing a rotor which comprises applying to the rotor a balancing composition which comprises an epoxy resin, a photoinitiator in an amount sufficient to cause cationic polymerization and cure said resin upon the application of ultraviolet light (about 10 nm to about 400 nm), and a filler in an amount to give said composition a specific gravity above 1.1, said filler not being ultraviolet light opaque and selected from a group consisting of quartz, silica, and the combination thereof, and exposing the balancing composition at ambient temperature to ultraviolet light of less than 40 watts per square centimeter for less than 30 seconds and curing said resin.

2. The method of claim 1 wherein said resin is selected from the group consisting of bisphenol-A, bisphenol-F, novolak, difunctional glycidol ester, and cycloaliphatic based epoxy resins, and combinations thereof.

3. The method of claim 1 wherein said resin consists of about 13% to about 90% weight of said composition.

4. The method of claim 1 wherein said composition further comprises a polyol up to about 100 parts per 100 parts of said resin.

5. The method of claim 4 wherein said polyol is chosen from the group consisting of polycaprolactone alcohols, polyether alcohols, polyester alcohols, other monofunctional alcohols, other difunctional alcohols, other trifunctional alcohols, and combinations thereof.

6. The method of claim 1 wherein said composition is homogeneous.

7. The method of claim 1 wherein, said photoinitiator is present from about 0.1 to about 4 parts per 100 of said resin.

8. The method of claim 1 wherein said photoinitiator initiator is selected from the groups consisting of onium salts, iron salts, and combinations thereof.

9. The method of claim 1 wherein said photoinitiator is selected from the group consisting of organic compounds having an acid component, wherein said acid component forms a Lewis acid during the resin curing process.

10. The method of claim 1 wherein said composition further comprises a wetting agent sufficient to reduce the surface energy of said resin to a level that said filler is wet with said resin.

11. The method of claim 10 wherein said wetting agent is selected from the group consisting of hydrocarbon, silicone, fluorochemical, and other surfactants and combinations thereof.

12. The method of claim 10 wherein said wetting agent is present in an amount from about 0.001 to about 1.0 parts per 100 of said resin.

13. The method of claim 1 further comprising a wetting agent in an amount sufficient to minimize refraction and reflection of ultraviolet light at the resin/filler interface.

14. The method of claim 1 wherein said filler is present in an amount sufficient to maintain said photoinitiator in suspension and said composition homogeneous.

15. The method of claim 14 wherein said filler is present in an amount less than 20 parts per 100 of said resin.

16. The method of claim 1 wherein said composition further comprises a catalyst which in combination with said photoinitiator will cure said resin at ambient temperatures upon the application of ultraviolet light of less than 40 watts per square centimeter in less than about 30 seconds.

17. The method of claim 16 wherein said catalyst is selected from the group consisting of copper salt and hydroperoxide catalysts and combinations thereof.

18. The method of claim 16 wherein said catalysts are present in an amount from about 0.01 to about 5 parts per 100 of said resin.

19. The method of claim 1 wherein said resin when cured is cross-linked through said epoxy groups.

20. The method of claim 1 wherein said composition has no slump at room temperature, is sufficiently tacky, adherent and cohesive to adhere to the rotor during dynamic testing before curing, said method comprising, prior to the step of exposing, the step of dynamically testing the rotor with said balancing composition in position thereon and adjusting the amount of balancing composition on the rotor to achieve balance.

21. The method of claims 20 wherein the amount and position of the balancing composition is adjusted and dynamic testing of the rotor is repeated until the desired degree of balance is attained before the resin is cured.

22. The method of claim 20 wherein said adjusting step includes adjusting both the amount and the position of the balancing composition on the rotor and dynamically retesting the rotor until the desired degree of balance is attained.

23. The method of claim 1 further comprising, after the step of exposing, the step of dynamically testing the rotor with the balancing composition in position thereon.

24. A method of balancing a rotor comprising applying to a rotor a balancing composition comprising an epoxy resin, a photoinitiator in an amount to cure said resin at ambient temperature upon the application of ultraviolet light (about 10 nm to about 400 nm) of less than 40 watts per square centimeter in less than about 30 seconds, and a filler in an amount to give said composition no slump at room temperature and a specific gravity above 1.1, the composition not being sufficiently tacky, adherent or cohesive to adhere to the rotor during dynamic testing before curing, curing said resin by exposing said composition to ultraviolet light of less than 40 watts per square centimeter for less than about 30 seconds, dynamically testing the rotor with the now cured balancing composition in position thereon, adding an additional amount of the balancing composition on the rotor to achieve the desired balance, if required, and then curing said additional resin.

25. The method of claim 24 wherein said adjusting step includes adjusting both the amount and position of the balancing composition on the rotor.

26. The method of claim 24 wherein said resin is chosen from the group consisting of bisphenol-A, bisphenol-F, novolak, difunctional glycidol ester, and cycloaliphatic based epoxy resins, organosilicon moners having a six member silicon dioxide ring, and sulfur containing moners having three and four member sulfur containing rings, and combinations thereof.

27. The method of claim 24 wherein said resin consists of about 13% to about 90% weight of said composition.

28. The method of claim 24 wherein said composition comprises a polyol up to about 100 parts per 100 parts of said resin.

29. The method of claim 28 wherein the Union Carbide R value of said polyol is less than 3.

30. The method of claim 28 wherein said polyol is selected from the group consisting of polycaprolactone alcohols, polyether alcohols, polyester alcohols, other monofunctional alcohols, other difunctional alcohols, other trifunctional alcohols, and combinations thereof.

31. The method of claim 24 wherein said filler is not ultraviolet light opaque.

32. The method of claim 24 wherein said filler is selected from the group consisting of quartz, silica, Pyrex, Flint and Crown glasses, and combinations thereof.

33. The method of claim 24 wherein said composition wets said filler.

34. The method of claim 24 wherein said composition is homogeneous.

35. The method of claim 24 further comprising a photoinitiator in an amount sufficient to cure said resin upon being exposed to ultraviolet light.

36. The method of claim 35 wherein said photoinitiator is present from about 0.1 to about 4 parts per 100 of said resin.

37. The method of claim 35 wherein said photoinitiator initiator is selected from the groups consisting of onium salts, iron salts and combinations thereof.

38. The method of claim 35 wherein said photoinitiator is selected from the group consisting of organic compounds having an acid component, wherein said acid component forms a Lewis acid during the resin curing process.

39. The method of claim 24 further comprising an effective amount of a photosensitizer to convert visible light into ultraviolet light.

40. The method of claim 24 wherein said photosensitizer is present in an amount less than 5.0 parts per 100 of said resin.

41. The method of claim 24 further comprising a wetting agent sufficient to reduce the surface energy of said resin to a level that said filler is wet with said resin.

42. The method of claim 41 wherein said wetting agent is selected from the group consisting of hydrocarbon, silicone, fluorochemical, and other surfactants and combinations thereof.

43. The method of claim 41 wherein said wetting agent is present in an amount from about 0.001 to about 1.0 parts per 100 of said resin.

44. The method of claim 41 further comprising a wetting agent in an amount sufficient to minimize refraction and reflection of ultraviolet light at the resin/filler interface.

45. The method of claim 24 wherein said filler is present in an amount sufficient to maintain said photoinitiator in suspension and said composition homogeneous.

46. The method of claim 45 wherein said fillers are chosen from the group consisting of quartz, silica, Pyrex, Flint and Crown glasses, and combinations thereof.

47. The method of claim 45 wherein said filler is present in an amount less than 20 parts per 100 of said resin,

48. The method of claim 24 further comprising a catalyst which in combination with said photoinitiator will cure said resin at ambient temperatures upon the application of ultraviolet light (about 10 nm to about 400 nm) of less than 40 watts per square centimeter in less than about 30 seconds.

49. The method of claim 48 wherein said catalyst is selected from the group consisting of copper salt and hydroperoxide catalysts and combinations thereof.

50. The method of claim 48 wherein said catalysts are present in an amount from about 0.01 to about 5 parts per 100 of said resin.

51. The method of claim 24 wherein said resin when cured is cross-linked through said epoxy groups.