Three-dimensional printing techniques

• US 5,387,380 A
• Filed: 06/05/1992
• Issued: 02/07/1995
• Est. Priority Date: 12/08/1989
• Status: Expired due to Term

• Current Assignee: Massachusetts Institute of Technology, Merck & Co., Inc.
• Original Assignee: Massachusetts Institute of Technology
• Inventors: Lauder, Alan, Lee, Sang-Joon J., Michaels, Steven P., Tuerck, Harald, Bredt, James F., Fan, Tailin, Curodeau, Alain, Cima, Michael, Brancazio, David, Sachs, Emanuel, Khanuja, Satbir
• Primary Examiner(s): THEISEN, MARY LYNN F
• Application Number:
  US07/894,100
• Time in Patent Office: 977 Days
• Field of Search: 264/63, 264/69, 264/71, 264/109, 264/113, 264/123, 264/128, 264/308, 425/130, 425/218, 425/425, 222/171
• US Class Current: 264/69
• CPC Class Codes: B05C 19/04 the particulate material being projected, poured or allowed to flow onto the surface of the work B05C19/02 takes precedence; involving spraying or electrostatic projection B05B B05C19/005 takes precedence
• CPC Class Codes: B22F 10/14 by jetting of binder onto a bed of metal powder
• CPC Class Codes: B22F 10/16 by embedding the binder within the powder bed
• CPC Class Codes: B22F 10/68 Cleaning or washing
• CPC Class Codes: B22F 12/226 for rotary motion
• CPC Class Codes: B22F 12/38 Housings, e.g. machine housings
• CPC Class Codes: B22F 12/50 Means for feeding of material, e.g. heads
• CPC Class Codes: B22F 12/57 Metering means
• CPC Class Codes: B22F 12/63 Rollers
• CPC Class Codes: B22F 12/67 Blades
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: B22F 3/004 Filling molds with powder feeding material to presses in general B30B15/302
• CPC Class Codes: B28B 1/001 Rapid manufacturing of 3D objects by additive depositing, agglomerating or laminating of material selective deposition modelling of metallic powder B22F10/00; rapid manufacturing of 3D objects in general and in particular of plastics B29C64/00
• CPC Class Codes: B29C 41/006 using an electrostatic field for applying the material
• CPC Class Codes: B29C 41/12 Spreading-out the material on a substrate , e.g. on the surface of a liquid
• CPC Class Codes: B29C 41/36 Feeding the material on to the mould, core or other substrate
• CPC Class Codes: B29C 64/165 using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
• CPC Class Codes: B29C 67/02 Moulding by agglomerating B29C67/20 takes precedence
• CPC Class Codes: B29C 67/04 Sintering combined with compression B29C43/00
• CPC Class Codes: B29C 67/243 for making articles of definite length
• CPC Class Codes: B33Y 10/00 : Processes of additive manufacturing
• CPC Class Codes: B33Y 30/00 : Apparatus for additive manufacturing; Details thereof or accessories therefor
• CPC Class Codes: B41J 2/01 : Ink jet
• CPC Class Codes: B41J 2/085 : Charge means, e.g. electrodes
• CPC Class Codes: B41J 2/09 : Deflection means
• CPC Class Codes: G05B 2219/49013 : Deposit layers, cured by scanning laser, stereo lithography SLA, prototyping
• CPC Class Codes: H05K 2203/013 : Inkjet printing, e.g. for printing insulating material or resist using ink-jet printing to form a conductive pattern H05K3/125
• CPC Class Codes: H05K 2203/0522 : Using an adhesive pattern
• CPC Class Codes: H05K 3/102 : by bonding of conductive powder, i.e. metallic powder H05K3/12 takes precedence

Abstract

A process for making a component by depositing a first layer of a powder material in a confined region and then depositing a binder material to selected regions of the layer of powder material to produce a layer of bonded powder material at the selected regions. Such steps are repeated a selected number of times to produce successive layers of selected regions of bonded powder material so as to form the desired component. The unbonded powder material is then removed. In some cases the component may be further processed as, for example, by heating it to further strengthen the bonding thereof.

Claims

1. A process for making a component comprising the steps of

(1) depositing a preselected quantity of a powder material;

(2) spreading said powder material in a layer of preselected thickness over a predetermined confined region;

(3) applying a further material to selected regions of said layer of powder material which will cause said layer of powder material to become bonded at said selected regions;

(4) repeating steps (1), (2) and (3) a selected number of times to produce a selected number of successive layers, said further material causing said successive layers to become bonded to each other;

(5) removing unbonded powder material which is not at said one or more selected regions to provide the component.

2. A process as set forth in claim 1 wherein said powder comprises essentially spherical particles.

3. A process as set forth in claim 1 wherein said powder material is spread by an elongate roller traversed over said region.

4. A process as set forth in claim 3 wherein said roller is driven in rotation in a direction opposing the traversing motion.

5. A process as set forth in claim 3 wherein said roller is vibrated.

6. A process as set forth in claim 5 wherein said vibration includes a component normal to said layer.

7. A process as set forth in claim 5 wherein the vibration includes both a component which is longitudinal to said roller and a component which is normal to said layer.

8. A process as set forth in claim 1 wherein said powder material is spread by a doctor blade.

9. A process as set forth in claim 8 wherein said doctor blade is snowplow shaped to shear and roll excess deposited powder.

10. A process for making a component comprising the steps of

(1) depositing a layer of powder material;

(2) applying to selected interior regions of said layer of powder material a further material which will cause said layer of powder material to become bonded at said selected regions and applying said further material also to a preselected peripheral region of said layer which will cause the powder material in said preselected peripheral region to become bonded to form a container region;

(3) repeating steps (1) and (2) a selected number of time to produce a selected number of successive layers, said further material causing said successive layers to become bonded to each other;

(4) removing said bonded peripheral regions and removing unbonded powder material which is not at said one or more selected regions to provide the component.

11. A process as set forth in claim 10 in which said layer of powder is initially confined in an opening in a platen.

12. A process as set forth in claim 11 wherein previously printed layers are confined by the bonded peripheral region.

13. A process as set forth in claim 10 wherein previously printed layers are lowered prior to printing successive layers.

14. A process as set forth in claim 10 wherein previously printed layers are held stationary and successive layers are formed at successively higher levels.

15. A process for making a component comprising the steps of

(1) depositing a layer of a porous material having interconnected porosity, said layer being in the form of a preformed web comprising porous material temporarily held together by a first material;

(2) applying to one or more selected regions of said layer of porous material a further material which will cause said layer of porous material to become bonded at said one or more selected regions;

(3) repeating steps (1) and (2) a selected number of times to produce a selected number of successive layers, said further material causing said successive layers to become bonded to each other;

(4) removing both said porous material and said first material which are not at said one or more selected regions to provide the component.

16. A process as set forth in claim 15 wherein said preformed web comprises ceramic particles held together by an organic binder.

17. Apparatus for making a component, said apparatus comprising:

a hollow cylinder;

a piston which fits within said cylinder with peripheral clearance;

means for traversing said piston through said cylinder, said traversing means including means for guiding the travel of said piston independently of said cylinder;

means for spreading a layer of a powder material over said piston; and

means for applying a bonding material to selected regions of said layer of powder material.

18. Apparatus as set forth in claim 17 further comprising a compliant seal between said piston and said cylinder.

19. Apparatus as set forth in claim 18 wherein said seal is a fiber seal.

20. Apparatus as set forth in claim 17 wherein said guiding means is a linear bearing.

21. Apparatus as set forth in claim 20 wherein piston is mounted on one end of a plunger with said linear bearing at the other end and wherein said apparatus includes a bellows seal separating said piston from said bearing.

22. Apparatus for dispensing a train of a powder material, said apparatus comprising:

a sieve drum which is mounted for rotation around an axis which is inclined from the vertical, said drum having an opening at its upper end, the peripheral wall of said drum being perforate;

means for introducing a quantity of said powder material through said opening; and

means for rotating said drum around said axis to cause said powder material to be metered out through said peripheral wall.

23. Apparatus as set forth in claim 22 wherein said drum is closed at its lower end.

24. Apparatus as set forth in claim 22 further comprising a housing which peripherally encloses said drum and which provides a funnel like outlet at its bottom so that said housing collects and directs, through said outlet, powder material metered through the peripheral wall of said drum.

25. Apparatus as set forth in claim 24 further comprising means for traversing said drum and housing along one edge of a region over which a layer of said powder material is to be spread thereby to form a line of deposited powder material.

26. Apparatus as set forth in claim 25 further comprising means for spreading said line of deposited powder material across said region.

27. A process for making a component comprising the steps of

(1) depositing a layer of highly flowable powder material in a confined region;

(2) applying to said layer a linking material which, at least temporarily, reduces the flowability of said powder material;

(3) applying to selected regions of said layer a further material which will cause said layer of powder material to become bonded at said selected regions;

(4) repeating steps (1), (2) and (3) a selected number of times to produce a selected number of successive layers, said further material causing said successive layers to become bonded to each other;

(5) removing unbonded powder material which is not at said one or more selected regions to provide the component.

28. A process as set forth in claim 27 wherein said linking material is a liquid which links the particles of said powder material by surface tension without eliminating porosity of said layer and which can subsequently be removed to restore the flowability of the powder material in the unbonded regions of each of said layers.

29. A process as set forth in claim 27 wherein said powder material comprises essentially spherical metal particles.

30. A process as set forth in claim 28 wherein said linking material is applied as a fine spray or mist.

31. A process as set forth in claim 30 wherein said linking material is water.

32. A process as set forth in claim 29 wherein said further material is curable organic material.

33. A process as set forth in claim 32 wherein said organic material is burned away during sintering of said powder material.

34. A process as set forth in claim 33 wherein said further material is latex.

35. A process as set forth in claim 27 wherein said powder material comprises essentially spherical particles.

36. A process as set forth in claim 27 wherein said powder material is the product of a spray drying process which increases flowability.

37. A process as set forth in claim 27 wherein said layer is leveled by a doctor blade after step (2).

38. A process as set forth in claim 27 wherein said layer is compacted by a roller after being deposited.

39. A process as set forth in claim 27 wherein the particles of said powder material are coated with an adhesive material which is activated by said linking material.

40. A process as set forth in claim 39 wherein said adhesive material is a polymer which is activated by the application of a mist and can be dissolved by washing to remove the powder material in said unbonded regions in step (5).

41. A process as set forth in claim 40 wherein said mist is water.

42. A process as set forth in claim 27 wherein said linking material is a mixture of a highly volatile liquid and a less volatile liquid.

43. A process as set forth in claim 27 wherein said linking material is a mixture of methanol and octonol.

44. A process for making a component comprising the steps of

(1) depositing a layer of a powder material in a confined region, said powder material including a first material which, when activated, will temporarily link the particles of powder material to reduce flowability;

(2) activating said first material;

(3) applying a further material to selected regions of said layer of powder material which will cause said layer of powder material to become bonded at said selected regions;

(4) repeating steps (1), (2) and (3) a selected number of times to produce a selected number of successive layers, said further material causing said successive layers to become bonded to each other;

(5) removing both said first material and unbonded powder material which are not in said one or more selected regions thereby to provide the component.

45. A process as set forth in claim 44 wherein said first material is activated by the application of heat.

46. A process as set forth in claim 44 wherein said first material is activated by the application of a liquid mist.

47. A process for making a component comprising the steps of

(1) depositing in a confined region a layer of a powder material, said powder material including a material which will cause gellation of preselected colloidal suspensions;

(2) applying a preselected colloidal suspension to selected regions of said layer of powder material thereby to cause said layer of powder material to become bonded at said selected regions;

(3) repeating steps (1) and (2) a selected number of times to produce a selected number of successive layers, said further material causing said successive layers to become bonded to each other;

(4) removing unbonded powder material which is not at said one or more selected regions to provide the component.

48. A process as set forth in claim 47 wherein said colloidal suspension is an alkaline formulation of colloidal silica and said gellation causing material is an acid.

49. A process as set forth in claim 48 wherein said acid is granulated citric acid.

50. A process as set forth in claim 47 wherein said component is further treated by heating.

51. A process as set forth in claim 47 further comprising the step of sintering said component.

52. A process for making a component comprising the steps of

(1) depositing a preselected quantity of a powder material;

(2) spreading said powder material in a layer of preselected thickness over a predetermined confined region;

(3) compacting said layer to reduce its thickness;

(4) applying a further material to selected regions of said layer of powder material which will cause said layer of powder material to become bonded at said selected regions;

(5) repeating steps (1) through (4) a selected number of times to produce a selected number of successive layers, said further material causing said successive layers to become bonded to each other;

(6) removing unbonded powder material which is not at said one or more selected regions to provide the component.

53. A process as set forth in claim 52 wherein said layer is compacted by the application of pressure.

54. A process as set forth in claim 53 wherein said pressure is applied by a roller which is passed over said region.

55. A process as set forth in claim 52 wherein said layer is compacted by surface tension.

56. A process as set forth in claim 55 wherein said surface tension is produced by the application of a liquid to said layer of powder.

57. A process for making a component comprising the steps of

(1) placing a powder material in a sieve drum having a perforate peripheral wall;

(2) rotating and traversing said drum over a predetermined region thereby to deposit a layer of said powder material over said region;

(3) applying a further material to selected regions of said layer of powder material which will cause said layer of powder material to become bonded at said selected regions;

(4) repeating steps (1), (2) and (3) a selected number of times to produce a selected number of successive layers, said further material causing said successive layers to become bonded to each other;

(5) removing unbonded powder material which is not at said one or more selected regions to provide the component.

58. A process as set forth in claim 57 wherein the length of said drum is at least equal to the width of said region and wherein said drum is journaled for rotation around a horizontal axis.