Supercritical water oxidation reactor with wall conduits for boundary flow control

• US 5,387,398 A
• Filed: 12/03/1993
• Issued: 02/07/1995
• Est. Priority Date: 12/03/1993
• Status: Expired due to Fees

• Current Assignee: Aerojet General
• Original Assignee: Aerojet-General Corporation (L3Harris Technologies, Inc.)
• Inventors: Mueggenburg, H. Harry, Young, Marvin F., Rousar, Donald C.
• Primary Examiner(s): Warden, Robert J.
• Assistant Examiner(s): Carpenter, Robert
• Application Number:
  US08/162,582
• Time in Patent Office: 431 Days
• Field of Search: 422/168, 422/176, 422/182, 422/224, 422/241, 422/129, 366/337, 366/340, 137/896, 239/555, 60/258, 60/305
• US Class Current: 422/168
• CPC Class Codes: B01J 19/2415 Tubular reactors
• CPC Class Codes: B01J 2219/00155 using insulating materials or refractories
• CPC Class Codes: B01J 2219/00159 controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
• CPC Class Codes: B01J 2219/00164 controlling the flow
• CPC Class Codes: B01J 3/008 Processes carried out under supercritical conditions
• CPC Class Codes: B01J 3/042 in the form of a tube
• CPC Class Codes: C02F 11/086 in the supercritical state
• CPC Class Codes: Y02P 20/54 using solvents, e.g. supercritical solvents or ionic liquids

Abstract

A reactor tube for supercritical water oxidation is designed to supply a thin, continuous layer of water along the inner surface of the reaction zone by a wall lining formed of laminated platelets individually etched and superimposed to form an array of engineered fluid passages through the wall. Each passage includes a flow metering channel of closely controlled configuration to impose a preselected level of resistance to water flowing through it, plus a distribution section which distributes the water emerging from the flow metering channel over the length of a slot-shaped exit port. The exit port is arranged in conjunction with neighboring exit ports in an array over the inner surface of the reactor such that the emerging water forms a continuous film over the surface, thereby protecting the surface from corrosion and salts deposition from the supercritical reaction medium.

Claims

1. A reactor tube for supercritical water oxidation, comprising:

a source of water, an elongate tube having a tube wall comprised of a laminate of platelets, each platelet less than about 0.100 inch in thickness and etched in a pattern such that the etched regions of all platelets overlap to form a plurality of flow passages communicating the exterior of said tube wall with the interior thereof, each said flow passage defining a direction of flow toward said interior and each said flow passage comprising;

a flow metering channel of substantially uniform cross section and elongate and unbranched in shape, the length and cross section of said flow metering channel selected to offer a preselected resistance to flow therethrough, said flow metering channel in fluid communication with said source of water, and

a distribution section to receive water emerging from said flow metering channel and causing said water to flow in directions parallel to said tube wall, said distribution section having a cross section expanding in said direction of flow and terminating in an elongate exit port which is transverse relative to lift elongate tube and shaped to direct said water to flow in a sheet along the interior of said tube wall, said distribution section containing flow diverters to distribute said water substantially uniformly over the width of said elongate exit port,

the elongate exit ports of all said flow passages being arranged to supply water along the interior of said tube wall in a substantially continuous film.

2. A reactor tube in accordance with claim 1 in which said expanding cross section of said distribution section expands said cross section by a cross section area ratio of at least about 10:

1.

3. A reactor tube in accordance with claim 1 in which said expanding cross section of said distribution section expands said cross section by a cross section area ratio of from about 10:

1 to about 50;

1.

4. A reactor tube in accordance with claim 1 in which said flow metering channel has a cross section of less than about 1×

10^-3 square inch.

5. A reactor tube in accordance with claim 1 in which said flow metering channel has a cross section of from about 0.01×

10^-3 square inch to about 1×

10^-3 square inch.

6. A reactor tube in accordance with claim 1 in which said flow metering channel has a cross section of from about 0.01×

10^-3 square inch to about 0.20×

10^-3 square inch.

7. A reactor tube in accordance with claim 1 in which said flow metering channel has a length of from about 0.01 inch to about 3 inches.

8. A reactor tube in accordance with claim 1 in which said flow metering channel has a length of from about 0.1 inch to about 2 inches.

9. A reactor tube in accordance with claim 1 in which said flow metering channel has at least one change of direction of at least 90°

.

10. A reactor tube in accordance with claim 1 in which said flow metering channel has from one to ten changes of direction of at least 90°

.

11. A reactor tube in accordance with claim 1 in which each platelet of said laminate is less than about 0.025 inch in thickness.

12. A reactor tube in accordance with claim 1 in which said platelets of said laminate range in thickness from about 0.001 inch to about 0.025 inch.

13. A reactor tube in accordance with claim 1 in which each said elongate exit port is rectangular in shape with its longest dimension circumferentially oriented relative to said elongate tube, and said longest dimension is from about 0.003 to about 0.3 times the circumference of said tube.

14. A reactor tube in accordance with claim 13 in which said longest dimension is from about 0.01 to about 0.1 times the circumference of said tube.

15. A reactor tube in accordance with claim 13 in which said longest dimension is from about 0.05 inch to about 0.5 inch.

16. A reactor tube in accordance with claim 13 in which said longest dimension is from about 0.1 inch to about 0.3 inch.

17. A reactor tube in accordance with claim 1 in which said laminate is less than about 0.3 inch in thickness.

18. A reactor tube in accordance with claim 1 in which said laminate is from about 0.03 inch to about 0.3 inch in thickness.

19. A reactor tube in accordance with claim 1 in which said laminate is from about 0.05 inch to about 0.2 inch in thickness.

20. A reactor tube in accordance with claim 1 in which said elongate tube has an inner diameter of from about 0.5 inch to about 5 inches, and said elongate exit ports are spaced from each other along the axis of said elongate tube by a distance of from about 0.1 inch to about 1.0 inch.

21. A reactor tube in accordance with claim 1 in which said elongate tube has an inner diameter of from about 1 inch to about 3 inches, and said elongate exit ports are spaced from each other along the axis of said elongate tube by a distance of from about 0.25 inch to about 0.6 inch.

22. A reactor tube in accordance with claim 1 in which a flow direction through each of said flow passages is defined as the direction from said flow metering channel to said distribution section, and each of said flow passages further comprises a plurality of filtering channels arranged in parallel, upstream of said flow metering channel according to said flow direction, each said filtering channel having a cross section substantially equal to or less than that of said flow metering channel and all discharging into said flow metering channel.

23. A reactor tube in accordance with claim 1 in which said flow metering channels vary in shape among said flow passages such that said preselected resistance to flow varies axially along said elongate tube.

24. A reactor tube in accordance with claim 23 in which at least a portion of said flow metering channels each contain at least one change of direction of at least 90°

, and said flow metering channels vary in at least one member selected from the group consisting of length and number of changes of direction.

25. A reactor tube in accordance with claim 23 in which at least a portion of said flow metering channels each contain at least one change of direction of at least 90°

, and said flow metering channels vary in both length and number of changes of direction.