Layer thickness gradient control in multilayer polymeric bodies

• US 5,389,324 A
• Filed: 06/07/1993
• Issued: 02/14/1995
• Est. Priority Date: 06/07/1993
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Wisniewski, David M., Ramanathan, Ravi, Lewis, Ray A., Schrenk, Walter J.
• Primary Examiner(s): THURLOW, JEFFERY
• Application Number:
  US08/072,255
• Time in Patent Office: 617 Days
• Field of Search: 264/171, 264/245, 264/1.6, 264/1.3, 264/1.9, 425/131.1, 425/133.5, 425/462
• US Class Current: 264/173.12
• CPC Class Codes: B29C 2948/926 Flow or feed rate
• CPC Class Codes: B29C 2948/92647 Thickness
• CPC Class Codes: B29C 2948/92704 Temperature
• CPC Class Codes: B29C 48/07 Flat, e.g. panels
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/307 specially adapted for bringing together components, e.g. melts within the die
• CPC Class Codes: B29C 48/92 Measuring, controlling or regulating
• CPC Class Codes: B29K 2995/003 Reflective
• CPC Class Codes: G02B 5/287 comprising at least one layer of organic material

Abstract

Methods and apparatus for generating, and then precisely controlling, layer thickness gradients in multilayered polymeric reflective bodies are provided. The creation of such gradients is useful in tailoring multilayer bodies to reflect and/or transmit desired wavelengths of light. Both thermal and mechanical methods, as well as combinations thereof, are used.

Claims

1. A method for generating a layer thickness gradient within a multilayer polymeric body comprising the steps of:

providing separate streams of at least first and second heat plastified polymeric materials;

dividing each of said streams into a plurality of first substreams and a plurality of second substreams;

controlling the respective flow rates of said polymeric materials in said substreams to provide a differential in the volume of polymeric materials flowing through each of said substreams; and

combining said substreams into a composite stream having said plurality of first and second substreams interdigitated into overlapping generally planar layers with substantially parallel layer interfaces to form said multilayer body, said layers formed from the substream having the greater volumetric flow rate being thicker than said layers formed from the substream having the lesser volumetric flow rate to form a gradient in layer thicknesses.

2. The method of claim 1 in which the flow rate of said polymeric materials is controlled by controlling the temperature of at least some of said plurality of first and second substreams to provide a temperature differential among at least some of said substreams, thereby controlling the flow of polymeric materials in said substreams.

3. The method of claim 2 in which said plurality of first and second substreams are grouped into at least two zones, and the temperature of each zone is separately controlled.

4. The method of claim 2 in which said temperature differential is at least 5°

F.

5. The method of claim 2 including the steps of providing a third stream of heat plastified thermoplastic material to the exterior surfaces of said composite stream to form skin layers and forming the composite stream and skin layers into said multilayer polymeric body.

6. The method of claim 1 in which the flow rate of at least some of said polymeric materials in said plurality of first and second substreams is controlled by modifying the path lengths of said plurality of first and second substreams.

7. The method of claim 6 in which said path lengths are linearly varied.

8. The method of claim 6 in which said path lengths are varied in a step-wise fashion.

9. The method of claim 6 in which the flow rate in all of said plurality of first and second substreams is simultaneously controlled.

10. The method of claim 6 including the steps of providing a third stream of heat plastified thermoplastic material to the exterior surfaces of said composite stream to form skin layers and forming the composite stream and skin layers into said multilayer polymeric body.

11. The method of claim 1 in which the flow rate of at least some of said polymeric materials in said plurality of first and second substreams is controlled by modifying the path widths of said plurality of first and second substreams.

12. The method of claim 1 in which the flow rate of at least some of said polymeric materials in said plurality of first and second substreams is controlled by modifying the path heights of said plurality of first and second substreams.

13. A method for generating a layer thickness gradient within a multilayer polymeric body comprising the steps of:

providing separate streams of at least first and second heat plastified polymeric materials;

dividing each of said streams into a plurality of first substreams and a plurality of second substreams and then combining said plurality of first and second substreams into a first composite stream having said first and second substreams interdigitated into overlapping generally planar layers having substantially parallel layer interfaces;

separating said composite stream along an axis parallel to said planar layers into a plurality of branch streams;

manipulating at least one of said branch streams to increase the number of layers in said branch stream and thereby decrease their thicknesses; and

recombining said branch streams into a second composite stream having overlapping generally planar layers having an increased number of substantially parallel layer interfaces to form said body, said layers having a gradient in thicknesses resulting from said manipulation of at least one of said branch streams.

14. The method of claim 13 including the steps of providing a third stream of heat plastified thermoplastic material to the exterior surfaces of said second composite stream to form skin layers and forming the second composite stream and skin layers into said multilayer polymeric body.

15. A method for generating a layer thickness gradient within a multilayer polymeric body comprising the steps of:

providing separate streams of at least first and second heat plastified polymeric materials;

dividing each of said streams into a plurality of first substreams and a plurality of second substreams and then combining said plurality of first and second substreams into a first composite stream having said first and second substreams interdigitated into overlapping generally planar layers having substantially parallel layer interfaces;

separating said composite stream along an axis perpendicular to said planar layers into a plurality of branch streams;

manipulating at least one of said branch streams to increase the number of layers in said branch stream and thereby decrease their thicknesses; and

recombining said branch streams into a second composite stream having overlapping generally planar layers having an increased number of substantially parallel layer interfaces to form said body, said layers having a gradient in thicknesses resulting from said manipulation of at least one of said branch streams.

16. The method of claim 15 including the steps of providing a third stream of heat plastified thermoplastic material to the exterior surfaces of said second composite stream to form skin layers and forming the second composite stream and skin layers into said multilayer polymeric body.

17. An apparatus for generating a layer thickness gradient within a multilayer polymeric body comprising:

means for providing at least first and second streams of heat plastified polymeric materials;

means for dividing said at least first and second streams into a plurality of first substreams and a plurality of second substreams;

means for controlling the respective flow rates of said polymeric materials in said plurality of first and second substreams to provide a differential in the volume of polymeric materials flowing through each of said substreams; and

means for combining said substreams into a composite stream having said plurality of first and second substreams interdigitated into overlapping generally planar layers with substantially parallel layer interfaces to form said multilayer body, said layers formed from the substream having the greater volumetric flow rate being thicker than said layers formed from the substream having the lesser volumetric flow rate to form a gradient in layer thicknesses.

18. The apparatus of claim 17 in which said means for controlling the flow rate of said polymeric materials comprise means for heating at least some of said plurality of first and second substreams to provide a temperature differential among at least some of said substreams.

19. The apparatus of claim 17 in which said means for controlling the flow rate of said polymeric materials comprise a feedblock containing flow passages for each of said plurality of first and second substreams, said flow passages having varying lengths as measured from the points at which said plurality of substreams enter said passages until said substreams are discharged from said passages.

20. The apparatus of claim 19 in which the lengths of said flow passages are varied linearly.

21. The apparatus of claim 19 in which the lengths of said flow passages are varied in a step-wise fashion.

22. The apparatus of claim 17 in which said means for controlling the flow rate of said polymeric materials comprise a feedblock containing flow passages for each of said plurality of first and second substreams, said flow passages having varying widths as measured from the points at which said plurality of substreams enter said passages until said substreams are discharged from said passages.

23. The apparatus of claim 17 in which said means for controlling the flow rate of said polymeric materials comprise a feedblock containing flow passages for each of said plurality of first and second substreams, said flow passages having varying heights as measured from the points at which said plurality of substreams enter said passages until said substreams are discharged from said passages.

24. An apparatus for generating a layer thickness gradient within a multilayer polymeric body comprising:

means for providing at least first and second streams of heat plastified polymeric materials;

means for dividing said at least first and second streams into a plurality of first substreams and a plurality of second substreams;

means for combining said substreams into a composite stream having said plurality of first and second substreams interdigitated into overlapping generally planar layers with substantially parallel layer interfaces to form said multilayer body;

means for separating said composite stream into a plurality of branch streams;

means for manipulating at least one of said branch streams to increase the number of layers in said branch stream and thereby decrease their thicknesses; and

means for recombining said branch streams into a second composite stream having overlapping generally planar layers having an increased number of substantially parallel layer interfaces to form said body, said layers having a gradient in thicknesses resulting from said manipulation of at least one of said branch streams.

25. The apparatus of claim 24 in which said means for separating said composite stream separate said composite stream along an axis perpendicular to said planar layers.

26. The apparatus of claim 25 in which said combining means comprise a feedblock containing flow passages for each of said plurality of first and second substreams, and said separating means comprise a plurality of vertically-oriented vanes.

27. The apparatus of claim 24 in which said means for separating said composite stream separate said composite stream along an axis parallel to said planar layers.

28. The apparatus of claim 27 in which said combining means comprise a feedblock containing flow passages for each of said plurality of first and second substreams, and said separating means comprise a plurality of horizontally-oriented vanes.