Composition and process for chromating metal surfaces

• US 5,395,655 A
• Filed: 08/27/1993
• Issued: 03/07/1995
• Est. Priority Date: 11/28/1990
• Status: Expired due to Fees

• Current Assignee: Henkel Corporation (Henkel AG & Co KGaA)
• Original Assignee: Henkel Corporation (Henkel AG & Co KGaA)
• Inventors: Hatano, Norifumi, Hasebe, Akihiko, Oyama Kazuyuki
• Primary Examiner(s): LUSIGNAN, MICHAEL R
• Application Number:
  US08/066,151
• Time in Patent Office: 557 Days
• Field of Search: 148/251, 148/253, 148/258, 427/388.4, 427/435, 524/5, 524/460
• US Class Current: 427/388.4
• CPC Class Codes: C23C 22/33 containing also phosphates

Abstract

A chromating treatment composition particularly suitable for preparing aluminum and stainless steel for clear coating comprises water, anions containing hexavalent chromium, trivalent chromium cations, phosphate ions, dry process finely divided silica, and acrylic and/or methacrylic acid polymer or copolymer in such amounts that:

(A) the concentration of the total of hexavalent and trivalent chromium atoms is in the range from 1 to 60 g/L;

(B) the (trivalent chromium atom)/(hexavalent chromium atom) weight ratio is in the range from 0.6 to 2.5;

(C) the (phosphate ion)/(total chromium atoms in hexavalent chromium ions and trivalent chromium ions) weight ratio is in the range from 0.5 to 4.5;

(D) the (dry process silica)/(total chromium atoms in hexavalent chromium ions and trivalent chromium ions) weight ratio is in the range from 0.1 to 5.0; and

(E) the ratio of the weight of the specified water soluble polymer in the composition to the weight of the chromium atoms in the total of the hexavalent chromium ions and trivalent chromium ions in the composition is in the range from 0.01 to 1.0.

Claims

1. A liquid composition consisting essentially of water, a source providing dissolved anions containing hexavalent chromium atoms, a source providing dissolved trivalent chromium cations, and a source of dissolved phosphate ions, and optionally, a reductant for hexavalent chromium, wherein the composition also contains dry process silica and water soluble polymer selected from the group consisting of polymers and copolymers of acrylic acid and methacrylic acid and:

(A) the concentration of the total of hexavalent and trivalent chromium atoms is in the range from 1 to 60 g/l;

(B) the (trivalent chromium atom)/(hexavalent chromium atom) weight ratio is in the range from 0.6 to 2.5;

(C) the (phosphate ion)/(total chromium atoms in hexavalent chromium ions and trivalent chromium ions) weight ration is in the range from 0.5 to 4.5;

(D) the (dry process silica)/(total chromium atoms in hexavalent chromium ions and trivalent chromium ions) weight ratio is in the range from 0.1 to 5.0; and

(E) the ratio of the weight of the specified water soluble polymer in the composition to the weight of the chromium atoms in the total of the hexavalent chromium ions and trivalent chromium ions in the composition is in the range from 0.01 to 1.0.

2. A process for treating a metal surface, comprising contacting the metal surface with a liquid composition of matter according to claim 1 and subsequently drying the surface so contacted, without any intermediate rinsing between contacting and drying.

3. A process according to claim 2, wherein the metal treated is aluminum or stainless steel.

4. A process according to claim 3 in which the contacting is for a sufficient time to deposit a coating containing from 5 to 60 milligrams of chromium per square meter of metal surface treated.

5. A process according to claim 2 in which the contacting is for a sufficient time to deposit a coating containing from 5 to 60 milligrams of chromium per square meter of metal surface treated.

6. A process according to claim 5, comprising an additional step of covering the contacted and dried surface with a clear organic based protective coating.

7. A process according to claim 4, comprising an additional step of covering the contacted and dried surface with a clear organic based protective coating.

8. A process according to claim 3, comprising an additional step of covering the contacted and dried surface with a clear organic based protective coating.

9. A process according to claim 2, comprising an additional step of covering the contacted and dried surface with a clear organic based protective coating.