Slitted absorbent members for aqueous body fluids formed of expandable absorbent materials

• US 5,397,316 A
• Filed: 06/25/1993
• Issued: 03/14/1995
• Est. Priority Date: 06/25/1993
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Andes, William S., Roe, Donald C., Young, Gerald A., LaVon, Gary D., Taylor, Gregory W.
• Primary Examiner(s): Green, Randall L.
• Assistant Examiner(s): ZUTTARELLI, ANTHONY
• Application Number:
  US08/082,861
• Time in Patent Office: 627 Days
• Field of Search: 604/358, 604/368, 604/369, 604/359, 604/360, 604/378, 604/370, 604/374, 604/375, 604/382, 604/385.1, 602/46, 602/47
• US Class Current: 604/369
• CPC Class Codes: A61F 13/535 inhomogeneous in the plane of the pad, e.g. core absorbent layers being of different sizes A61F13/5323, A61F13/537 take precedence
• CPC Class Codes: A61F 13/5376 characterised by the performance of the layer, e.g. acquisition rate, distribution time, transfer time
• CPC Class Codes: A61F 2013/15325 Stress relaxation or compression recovery
• CPC Class Codes: A61F 2013/15357 Stiffness, e.g. Taber rigidity
• CPC Class Codes: A61F 2013/15422 Density
• CPC Class Codes: A61F 2013/15487 Capillary properties, e.g. wicking
• CPC Class Codes: A61F 2013/15495 pore dimension
• CPC Class Codes: A61F 2013/1552 with specific diffusion velocity
• CPC Class Codes: A61F 2013/49079 as backbone-shape
• CPC Class Codes: A61F 2013/530007 being made from pulp
• CPC Class Codes: A61F 2013/530131 being made in fibre but being not pulp
• CPC Class Codes: A61F 2013/530481 having superabsorbent materials, i.e. highly absorbent polymer gel materials
• CPC Class Codes: A61F 2013/530489 being randomly mixed in with other material
• CPC Class Codes: A61F 2013/530817 being open cells
• CPC Class Codes: A61F 2013/530839 being hydrophilic
• CPC Class Codes: A61F 2013/530854 being collapsed or collapsible foam
• CPC Class Codes: A61F 2013/530861 having slit regions
• CPC Class Codes: A61F 2013/53721 with capillary means
• CPC Class Codes: A61F 2013/53765 characterized by its geometry

Abstract

This application relates to the use of slitted regions in absorbent members formed of absorbent materials that remain relatively thin until wetted with such fluids. Suitable materials include presently preferred varieties of polymeric foam materials. Single and multi-layered absorbent members incorporating slitted regions are disclosed, as well as the use of pre-formed cup-shaped slits for enhanced initial fluid acquisition. Such slitted regions in combination with planar expansion properties enable the absorbent members to respond dynamically to various fluid loading conditions to create useful structural features. The slitted regions, in combination with absorbent materials having expansion potential in at least one direction within the plane of the absorbent member, cause the slitted regions to buckle and/or deform out of the plane of the absorbent member, thereby causing the slit surfaces to displace angularly and/or translationally with respect to one another. This more fully exposes the slit surfaces to the incoming fluid for improved acquisition capabilities. The use of pre-formed cup-shaped slits enables the absorbent member to more quickly capture and absorb aqueous body fluids, and is particularly useful for containment and dewatering of moist or runny fecal material and higher viscosity fluids and/or those having a higher concentration of particulate material therein such as blood, menses, or wound fluids.

Claims

1. An absorbent member having a peripheral region and a deposition region contiguous with said peripheral region and laterally surrounded by said peripheral region, the absorbent member comprising:

(a) at least one layer of absorbent material which, upon contact with aqueous body fluids, expands and absorbs said aqueous body fluids, said absorbent material comprising a hydrophilic, flexible structure of interconnected open spaces, said layer having an upper surface and a lower surface, said upper surface and said lower surface defining a planar direction and a normal direction perpendicular to said planar direction, said absorbent material being expandable in at least one direction within said planar direction in response to absorption of said aqueous body fluid into said interconnected open spaces; and

(b) at least one slitted region comprising at least one slit extending at least partially through said layer, said slit comprising at least two slit surfaces which are displaceable with respect to one another when said aqueous body fluid is introduced into said deposition region and absorbed into said interconnected open spaces such that said slit opens and exposes said slit surfaces, the displacement of said slit surfaces being substantially reversible when said aqueous body fluid is removed from said interconnected open spaces and said absorbent material returns to an unexpanded state.

14. The absorbent member of claim 1, wherein said absorbent member includes at least two layers of said absorbent material, and wherein said slitted region comprises at least one slit extending at least partially through at least one of said layers.

15. The absorbent member of claim 14, wherein said absorbent member comprises at least one layer provided with at least one slitted region and at least one layer which remains unslitted.

16. The absorbent member of claim 14, wherein said absorbent member includes at least one layer of hydrophilic fibrous material.

2. An absorbent member having a peripheral region and a deposition region contiguous with said peripheral region and laterally surrounded by said peripheral region, the absorbent member comprising:

(a) at least one layer of absorbent material which, upon contact with aqueous body fluids, expands and absorbs said aqueous body fluids, said absorbent material comprising a collapsed polymeric foam material, said polymeric foam material comprising a hydrophilic, flexible structure of interconnected open cells, said layer having an upper surface and a lower surface, said upper surface and said lower surface defining a planar direction and a normal direction perpendicular to said planar direction, said absorbent material being expandable in at least one direction within said planar direction, said polymeric foam material having;

(i) a specific surface area per foam volume of at least about 0.025 m² /cc;

(ii) at least about 0.1% by weight of a toxicologically acceptable hygroscopic, hydrated salt incorporated therein;

(iii) in its collapsed state, an expansion pressure of about 30 kPa or less; and

(iv) in its expanded state, a density when saturated at 88°

F. (31.1°

C.) to its free absorbent capacity with synthetic urine having a surface tension of 65±

5 dynes/cm of from about 10% to about 50% of its dry basis density in its collapsed state; and

(b) at least one slitted region comprising at least one slit extending at least partially through said layer, said slit comprising at least two slit surfaces which are displaceable with respect to one another when said aqueous body fluid is introduced into said deposition region;

whereby when said aqueous body fluid is introduced into said deposition region, at least a portion of said slitted region expands more rapidly than and to a greater degree than surrounding regions of said layer, and whereby at least a portion of said slitted region becomes deformed and buckled in said normal direction, thus causing said slit to open and expose said slit surfaces to said aqueous body fluid for more rapid acquisition.

3. The absorbent member of claim 2, wherein said polymeric foam material has a specific surface area per foam volume of at least about 0.05 m² /cc and a residual water content of at least about 4% by weight in its collapsed state.

4. The absorbent member of claim 3, wherein said polymeric foam material has:

(a) a capillary suction specific surface area of from about 0.7 to about 8 m² /g;

(b) from about 0.1 to about 8% by weight of calcium chloride, and from about 0.5 to about 20% by weight of a nonionic oil-soluble emulsifier incorporated therein to render the surface of the foam structure hydrophilic;

(c) in its collapsed state;

(i) a residual water content of from about 4 to about 30% by weight;

(ii) a dry basis density of from about 0.05 to about 0.4 g/cm³ ;

(d) in its expanded state;

(i) a pore volume of from about 12 to about 100 mL/g;

(ii) a resistance to compression deflection of from about 2 to about 80% when saturated at 88°

F. (31.1°

C.) to its free absorbent capacity with synthetic urine having a surface tension of 65±

5 dynes/cm;

(iii) a number average cell size of from about 5 to about 50 microns.

5. The absorbent member of claim 4, wherein said polymeric foam material has:

(a) a capillary suction specific surface area of from about 1.5 to about 6 m² /g;

(b) from about 3 to about 6% by weight of calcium chloride and from about 5 to about 12% by weight sorbitan laurate incorporated therein;

(c) in its collapsed state;

(i) a residual water content of from about 5 to about 15% by weight;

(ii) a dry basis density of from about 0.1 to about 0.2 g/cm³ ;

(iii) an expansion pressure of from about 7 to about 20 kPa;

(d) in its expanded state;

(i) a pore volume of from about 25 to about 50 mL/g;

(ii) a resistance to compression deflection of from about 5 to about 40%;

(iii) a number average cell size of from about 5 to about 35 microns;

(iv) a density when saturated with said synthetic urine of from about 10 to about 30% of its dry basis density in its collapsed state.

6. An absorbent member having a peripheral region and a deposition region contiguous with said peripheral region and laterally surrounded by said peripheral region, the absorbent member comprising:

(a) at least one layer of absorbent material which, upon contact with aqueous body fluids, expands and absorbs said aqueous body fluids, said absorbent material comprising a hydrophilic, flexible structure of interconnected open spaces, said layer having an upper surface and a lower surface, said upper surface and said lower surface defining a planar direction and a normal direction perpendicular to said planar direction, said absorbent material being expandable in at least one direction within said planar direction in response to absorption of said aqueous body fluid into said interconnected open spaces; and

(b) at least one slitted region comprising at least one slit extending at least partially through said layer, said slit comprising at least two slit surfaces which are displaceable with respect to one another when said aqueous body fluid is introduced into said deposition region and absorbed into said interconnected open spaces, said slit surfaces having an initial orientation prior to introduction of said aqueous body fluid wherein said slit surfaces are substantially non-parallel and form an open receiving channel for enhanced acquisition of said aqueous body fluid into said interconnected open spaces.

7. The absorbent member of claim 6, wherein said absorbent material comprises a collapsed polymeric foam material, said polymeric foam material comprising a hydrophilic, flexible structure of interconnected open cells.

8. The absorbent member of claim 7, wherein said polymeric foam material has an expansion potential in at least one direction within said planar direction of at least 5%.

9. The absorbent member of claim 7, wherein said polymeric foam material has an expansion potential in at least two mutually orthogonal directions within said planar direction of at least 3%.

10. An absorbent member having a peripheral region and a deposition region contiguous with said peripheral region and laterally surrounded by said peripheral region, the absorbent member comprising:

(a) least one layer of absorbent material which, upon contact with aqueous fluids expands and absorbs said aqueous body fluids, said absorbent material comprising a hydrophilic, flexible structure of interconnected open spaces, said layer having an upper surface and a lower surface, said upper surface and said lower surface defining a planar direction and a normal direction perpendicular to said planar direction, said absorbent material being expandable in at least one direction within said planar direction in response to absorption of said aqueous body fluid into said interconnected open spaces; and

(b) at least one slitted region comprising at least one slit extending at least partially through said layer, said slit comprising at least two slit surfaces which are displaceable with respect to one another when said aqueous body fluid is introduced into said deposition region and absorbed into said interconnected open spaces such that said slit opens and exposes said slit surfaces to said aqueous body fluid for enhanced acquisition of said aqueous body fluid into said interconnected open spaces.

11. The absorbent member of claim 10, wherein said slit surfaces are displaceable with respect to one another in said normal direction.

12. The absorbent member of claim 10, wherein said slit surfaces are angularly displaceable with respect to one another.

13. The absorbent member of claim 10, further comprising an unslitted region at least partially surrounding said slitted region and extending outwardly from said slitted region.

17. The absorbent member of claim 10, wherein said absorbent material comprises a collapsed polymeric foam material, said polymeric foam material comprising a hydrophilic, flexible structure of interconnected open cells.

18. The absorbent member of claim 17, wherein said polymeric foam material has an expansion potential in at least one direction within said planar direction of at least 5%.

19. The absorbent member of claim 17, wherein said polymeric foam material has an expansion potential in at least two mutually orthogonal directions within said planar direction of at least 3%.

20. The absorbent member of claim 17, wherein said polymeric foam material has an expansion potential in a direction parallel to the direction of said slit.

21. The absorbent member of claim 17, wherein said polymeric foam material has an expansion potential in a direction perpendicular to the direction of said slit.

22. The absorbent member of claim 17, wherein said polymeric foam material has an expansion potential both parallel and perpendicular to the direction of said slit.