Method and apparatus for sequestering carbon dioxide in the deep ocean or aquifers

• US 5,397,553 A
• Filed: 10/05/1992
• Issued: 03/14/1995
• Est. Priority Date: 10/05/1992
• Status: Expired due to Fees

• Current Assignee: Electric Power Research Institute Incorporated
• Original Assignee: Electric Power Research Institute Incorporated
• Inventors: Spencer, Dwain F.
• Primary Examiner(s): Warden, Robert J.
• Assistant Examiner(s): MCKANE, ELIZABETH L
• Application Number:
  US07/956,520
• Time in Patent Office: 890 Days
• Field of Search: 422/243, 422/211, 55/68, 48/190
• US Class Current: 422/243
• CPC Class Codes: B09B 1/002 Sea dumping
• CPC Class Codes: F17C 1/007 Underground or underwater storage
• CPC Class Codes: F17C 11/00 Use of gas-solvents or gas-sorbents in vessels absorbing compositions for acetylene C10L3/04; absorbing compositions for hydrogen C01B3/0005
• CPC Class Codes: F17C 2205/0323 Valves
• CPC Class Codes: F17C 2205/0352 Pipes
• CPC Class Codes: F17C 2221/013 Carbone dioxide
• CPC Class Codes: F17C 2221/03 Mixtures
• CPC Class Codes: F17C 2223/0123 gaseous, e.g. CNG, GNC
• CPC Class Codes: F17C 2225/0169 subcooled
• CPC Class Codes: F17C 2225/0184 Liquids and solids
• CPC Class Codes: F17C 2225/033 Small pressure, e.g. for liquefied gas
• CPC Class Codes: F17C 2225/035 High pressure, i.e. between 10 and 80 bars
• CPC Class Codes: F17C 2225/044 at several points, e.g. with a device for recondensing gas
• CPC Class Codes: F17C 2227/0121 by gravity
• CPC Class Codes: F17C 2227/0135 Pumps
• CPC Class Codes: F17C 2227/0157 Compressors
• CPC Class Codes: F17C 2227/0351 using seawater
• CPC Class Codes: F17C 2227/0383 outside the vessel
• CPC Class Codes: F17C 2227/039 on the pipes
• CPC Class Codes: F17C 2260/044 Avoiding pollution or contamination
• CPC Class Codes: F17C 2265/025 : different fluids
• CPC Class Codes: F17C 2270/0128 : Storage in depth
• CPC Class Codes: F17C 2270/0155 : by using natural cavities
• CPC Class Codes: Y02C 20/40 : of CO2

Abstract

Disclosed is a system for sequestering carbon dioxide by combining sub-cooled carbon dioxide gas phase and liquid water (fresh or salt) in a reactor to form carbon dioxide clathrates in a continuous process at pressures from 3 to 20 atmospheres. The seawater feed for the clathrate reactor is pumped to the surface from a depth of approximately 1000 meters. A slip stream of the reactor feed water is used to pre-cool the carbon dioxide gases. The pre-cooled gaseous, or liquid carbon dioxide and the reactor surfaces are then sub-cooled by refrigeration to temperatures of -40° C. to 0° C., which is typically only 5° to 45° C. below ambient sea water temperatures at depths of 1000 meters. Forming clathrates in this manner is considerably less energy-intensive than CO₂ compression and liquefaction at high pressures.

Claims

1. A system for sequestering carbon dioxide in deep water comprising:

a. a source of gaseous carbon dioxide;

b. a source of seawater at a depth of greater than 500 meters and a temperature of about 0°

to 10°

C.

c. a compressor in fluid communication with said gaseous carbon dioxide for compressing said carbon dioxide;

d. a heat exchanger in fluid communication with said compressor for receiving and precooling said compressed carbon dioxide;

e. a refrigeration unit in fluid communication with said heat exchanger for receiving and subcooling said precooled, compressed carbon dioxide to at temperature between approximately 0°

C. and -30°

C.;

e. a clathrate reactor vessel in fluid communication with said refrigeration unit for receiving said sub-cooled carbon dioxide from said refrigeration unit;

f. means for transporting and splitting said cold seawater into first and second streams, said first stream to feed said clathrate reactor for production of clathrates and said second stream for precooling said carbon dioxide and transporting said clathrates as a slurry to depths greater than 500 meters;

g. means for mixing said subcooled carbon dioxide and said seawater in said clathrate reactor vessel thereby forming clathrates; and

h. means for transporting said clathrates to a depth greater than 500 meters in said seawater;

whereby said seawater is used to precool gaseous carbon dioxide which is then subcooled and mixed with cold seawater to form clathrates which are deposited in the deep water at a depth greater than 500 meters to sequester said carbon dioxide.

2. A system for sequestering carbon dioxide in deep water as recited in claim 1 wherein said reactor uses cross-flow nozzles to mix said carbon dioxide and said water.

3. A system for sequestering carbon dioxide in deep water as recited in claim 1 wherein said reactor uses counter-flow nozzles to mix said carbon dioxide and said water.

4. A system for sequestering carbon dioxide in deep water as recited in claim 1 wherein said subcooled carbon dioxide gas is sonically preconditioned before it is admitted to said reactor.

5. A system for sequestering carbon dioxide in deep water as recited in claim 1 wherein said subcooled carbon dioxide gas is preconditioned with infrared radiation before it is admitted to said reactor.

6. A system for sequestering carbon dioxide in deep water as recited in claim 1 wherein said means for transporting said clathrates from said reactor further comprise a pressure lock chamber.

7. A system for sequestering carbon dioxide in deep water as recited in claim 1 wherein said means for transporting said clathrates into deep water further comprise a deep water discharge pipe with circulating seawater flowing therethrough, said pipe connected to a mixing chamber receiving said clathrates whereby said clathrates mix with said flowing circulating seawater and are carded to deep water for discharge.

8. A system for sequestering carbon dioxide in deep water as recited in claim 7 wherein said circulating water is supplied from said second stream of incoming seawater after flowing through said heat exchanger,

9. A system for sequestering carbon dioxide in deep water as recited in claim 1 further comprising means for transporting said first stream of seawater to said refrigeration unit for subcooling said seawater to approximately 0°

C. and means for transporting said subcooled seawater from said refrigeration unit to said reactor whereby subcooled carbon dioxide and subcooled seawater are mixed in said reactor to form clathrates.