Non-toxic corrosion resistant conversion coating for aluminum and aluminum alloys and the process for making the same

• US 5,399,210 A
• Filed: 02/03/1993
• Issued: 03/21/1995
• Est. Priority Date: 09/03/1991
• Status: Expired due to Fees

• Current Assignee: Lockheed Corporation (Martin Marietta Corporation)
• Original Assignee: Lockheed Corporation (Martin Marietta Corporation)
• Inventors: Miller, Robert N.
• Primary Examiner(s): Silverberg, Sam
• Application Number:
  US08/015,112
• Time in Patent Office: 776 Days
• Field of Search: 106/14.21, 148/273, 148/275
• US Class Current: 148/273
• CPC Class Codes: C23C 22/56 Treatment of aluminium or alloys based thereon
• CPC Class Codes: C23C 22/66 Treatment of aluminium or alloys based thereon
• CPC Class Codes: C23C 22/83 Chemical after-treatment
• CPC Class Codes: C23C 2222/20 Use of solutions containing silanes

Abstract

A non-toxic corrosion resistant conversion coating for aluminum is formed by a process which includes subjecting the aluminum to an acidic aqueous solution containing potassium permanganate and cerous chloride, alone or in combination with strontium chloride. The corrosion resistance is improved by a subsequent treatment in an alkaline solution containing molybdate, nitrite and metasilicate ions. The corrosion resistant is further improved by treating the coated surface with an acholic solution containing glycidoxy(epoxy)polyfunctionalmethoxysilane, alone or in combination with phenyltrimethoxysilane. The coating thus produced is a mixture of oxides and hydroxides of cerium strontium and aluminum. These oxides and hydroxides may also be intermixed with molybdate silicate and nitrite ions. In the most corrosion resistant form the mixture further includes a silane overcoat.

Claims

1. A process for producing a corrosion resistant chemical conversion coating on aluminum and aluminum alloys comprising subjecting a cleaned, degreased and deoxidized aluminum to an alkaline solution containing sodium molybdate, sodium nitrite and sodium metasilicate.

2. The process of claim 1 followed by a thorough rinsing of said aluminum, then subjecting said aluminum to an acidic aqueous solution containing cerous chloride and potassium permanganate, then following a thorough rinsing of said aluminum subjecting said aluminum to an a aqueous solution containing sodium molybdate, sodium nitrate and sodium metasilicate.

3. The process of claim 1 followed by a thorough rinsing of said aluminum, then subjecting said aluminum to an acidic aqueous solution containing cerous chloride and potassium permanganate, then following a thorough rinsing of said aluminum subjecting said aluminum to a solution containing alcohol, phenyltrimethoxysilane and glycidoxy(epoxy)polyfunctionalmethoxysilane.

4. The process of claim 1 followed by a thorough rinsing of said aluminum, then subjecting said aluminum to an acidic aqueous solution containing cerous chloride and potassium permanganate, then following a thorough rinsing of said aluminum subjecting said aluminum to a solution containing alcohol and glycidoxy(epoxy)polyfunctionalmethoxysilane.

5. The process of claim 1 followed by a thorough rinsing of said aluminum, then subjecting said aluminum to an acidic aqueous solution containing cerous chloride, strontium chloride and potassium permanganate, then following a thorough rinsing of said aluminum subjecting said aluminum to a solution containing sodium molybdate, sodium nitrite and sodium metasilicate, then following a thorough rinsing of said aluminum subjecting such aluminum to a solution containing alcohol, phenyltrimethoxysilane and glycidoxy(epoxy)polyfunctionalmethoxysilane.

6. The process of claim 1 followed by a thorough rinsing of said aluminum, then subjecting said aluminum to an acidic aqueous solution containing cerous chloride, strontium chloride and potassium permanganate, then following a thorough rinsing of said aluminum subjecting said aluminum to a solution containing sodium molybdate, sodium nitrite and sodium metasilicate, then following a thorough rinsing of said aluminum subjecting said aluminum to a solution containing alcohol and glycidoxy(epoxy)polyfunctionalmethoxysilane.