EMI shielding composites

• US 5,399,295 A
• Filed: 07/29/1993
• Issued: 03/21/1995
• Est. Priority Date: 06/11/1984
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Gamble, Jeffrey, Yats, Larry D.
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): Marcantoni, Paul
• Application Number:
  US08/099,297
• Time in Patent Office: 600 Days
• Field of Search: 252/511, 252/512, 252/518, 523/137, 428/195, 428/196, 428/197, 428/242, 428/244, 428/297, 428/323, 428/408
• US Class Current: 252/511
• CPC Class Codes: C08K 7/04 inorganic
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: H05K 9/0088 comprising a plurality of shielding layers; combining different shielding material structure
• CPC Class Codes: Y10T 428/24994 Fiber embedded in or on the surface of a polymeric matrix
• CPC Class Codes: Y10T 428/249948 Fiber is precoated
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

A composite sheet is disclosed comprising a continuous matrix of a synthetic resinous material having randomly dispersed therein conductive fibers and a particulate, conductive or semi-conductive filler. In addition to providing excellent EMI shielding properties, the composite sheets are formable and are of sufficient strength to act as structural components.

Claims

1. A composite sheet comprising

(a) a continuous matrix of a polymeric resin, having randomly dispersed therein;

(b) from about 0.05 to about 30 weight percent of the composite of a fine particulate conductive or semi-conductive filler material, and

(c) from about 0.25 to about 45 weight percent of the composite of conductive fibers having an aspect ratio from 25 to 2000, a diameter of from 2.5 μ

m to 50 μ

m, and a length from 1.6 mm to 25 mm, said fibers being randomly oriented in two dimensions substantially in the plane defined by the sheet.

2. The composite sheet of claim 1 wherein said conductive fibers have an average length of from 4.0 to 13.0 mm and a diameter of from 6.5 to 25.0 micrometer.

3. The composite sheet of claim 1 wherein the aspect ratio of said conductive fibers is from 200 to 1,800.

4. The composite sheet of claim 1 wherein said composite sheet comprises from 2 to 35 percent conductive fibers and from 0.1 to 5 percent filler material, based on the weight of the composite.

5. The composite sheet of claim 4 wherein said filler material has a resistivity of from 10^-2 to 10⁹ ohms-cm.

6. The composite sheet of claim 5 wherein said filler material is a furnace carbon black having a resistivity of less than 10 ohm/cm.

7. The composite sheet of claim 1 wherein said conductive fibers are selected from selected from the group consisting of stainless steel, nickel, carbon, graphite, metallized glass, metallized graphite or metallized plastic.

8. The composite sheet of claim 1 wherein said conductive fibers are nickel-coated graphite or aluminum-coated glass and said filler material is carbon black.

9. The composite sheet of claim 1, wherein said composite sheet includes from 25 to 50 percent by weight of non-conductive reinforcing fibers.

10. The composite sheet of claim 9, wherein said reinforcing fibers are glass fibers.

11. The composite sheet of claim 1 wherein said sheet has an EMI shielding effectiveness of greater than 20 to 80 decibels under conditions as specified by ASTM Designation ES 7-83.

12. The composite sheet of claim 1 wherein said sheet is capable of dissipating an electrostatic charge of +5 kv or -5 kv to 0 percent of total charge within 2 seconds.

13. The composite sheet of claim 12 wherein said sheet is capable of dissipating an electrostatic charge of +5 kv or -5 kv to 0 percent of total charge within 0.5 seconds.