Process and installation for the production of gaseous oxygen under pressure

• US 5,400,600 A
• Filed: 06/07/1993
• Issued: 03/28/1995
• Est. Priority Date: 06/23/1992
• Status: Expired due to Term

• Current Assignee: L'Air Liquide Societe Anonyme Pour L'Etude et L'Exploitation Des Procedes Georges Claude (L'Air Liquide SA)
• Original Assignee: L'Air Liquide Societe Anonyme Pour L'Etude et L'Exploitation Des Procedes Georges Claude (L'Air Liquide SA)
• Inventors: Grenier, Maurice
• Primary Examiner(s): KILNER, CHRISTOPHER B
• Application Number:
  US08/072,991
• Time in Patent Office: 659 Days
• Field of Search: 62/39, 62/25, 62/38, 62/44, 62/22, 62/43
• US Class Current: 62/646
• CPC Class Codes: F25J 2215/54 Oxygen production with multiple pressure O2
• CPC Class Codes: F25J 2245/40 the recycled stream being air
• CPC Class Codes: F25J 2290/10 Mathematical formulae, modeling, plot or curves; Design methods
• CPC Class Codes: F25J 3/04084 of nitrogen
• CPC Class Codes: F25J 3/0409 of oxygen
• CPC Class Codes: F25J 3/04175 at a pressure of substantially more than the highest pressure column
• CPC Class Codes: F25J 3/042 having an intermediate feed connection
• CPC Class Codes: F25J 3/04236 Integration of different exchangers in a single core, so-called integrated cores F25J3/04624 takes precedence
• CPC Class Codes: F25J 3/0429 of feed air, e.g. used as waste or product air or expanded into an auxiliary column
• CPC Class Codes: F25J 3/04296 Claude expansion, i.e. expanded into the main or high pressure column
• CPC Class Codes: F25J 3/04303 Lachmann expansion, i.e. expanded into oxygen producing or low pressure column
• CPC Class Codes: F25J 3/04393 using multiple or multistage gas work expansion
• CPC Class Codes: F25J 3/04412 in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
• CPC Class Codes: F25J 3/04678 cooled by oxygen enriched liquid from high pressure column bottoms
• CPC Class Codes: Y10S 62/913 Liquified gas

Abstract

Entering air, all of which is compressed to a first high pressure P1, is partly further compressed to a pressure P2. At intermediate temperatures, a portion of each air current is expanded in a turbine (7, 8). One of the turbines can have an output at a pressure P3 comprised between P1 and the medium pressure. The major proportion of the separated oxygen is withdrawn as a liquid from the low pressure column (13), pumped to the production pressure and vaporized in the heat exchange line (2) by condensation or pseudo-condensation of air at one of the pressures P1, P2 and P3, depending on whether the condensation occurs at subcritical or supercritical pressure.

Claims

1. In a process for the production of gaseous oxygen under pressure by distillation of air in an installation comprising a heat exchange line (2) and a double distillation column (1) which column comprises a first column (12) operating under a medium pressure and a second column (13) operating under a low pressure, pumping (in 9, 10) liquid oxygen withdrawn from the base of the low pressure column to compress the liquid oxygen, and vaporizing the compressed oxygen by heat exchange with compressed air at a high air pressure;

the improvement comprising;

compressing all the air to be treated to a first high pressure P1 substantially greater than said medium pressure;

cooling a first portion of this compressed air to a first intermediate temperature T1, expanding a first fraction of this cooled air in a first turbine (7;

     8); and

cooling, liquefying, expanding and introducing into medium pressure column (12) the rest of this cooled air;

further compressing the rest of the air at the first high pressure P1 to a second high pressure P2 greater than P1 and cooling this further compressed air to a second intermediate temperature T2;

expanding a first flow of this air at temperature T2 in a second turbine (8;

     7); and

liquifying, expanding and introducing into the medium pressure column (12) the rest of this air that was cooled to temperature T2;

withdrawing the major portion of at least the separated oxygen in liquid phase from the low pressure column (13);

compressing the liquid oxygen by pumping to at least one first vaporization pressure at which it vaporizes by heat exchange with air at at least one of said high pressures P1 and P2 thereby to condensate air at said at least one high pressure.

2. Process according to claim 1, wherein the intermediate temperatures T1 and T2 are one between about 0°

C. and -60°

C. and the other between about -80°

C. and -130°

C.

3. Process according to claim 1, wherein the air flow supplying the first turbine (7;

8) is of the order of 20 to 30% of the air flow treated.

4. Process according to claim 1, and withdrawing additional liquid oxygen from the low pressure column (13) and compressing the same by pumping to at least one second vaporization pressure and vaporizing the same at the last-mentioned pressure in heat exchange with air.

5. Process according to claim 1, and withdrawing liquid nitrogen from the double column (1), compressing the same by pumping (10, 11) to at least one nitrogen vaporization pressure, and vaporizing the same at the last-mentioned pressure by heat exchange with air.

6. Process according to claim 1, and at least a portion of the air from the first or the second turbine (7, 8) to the low pressure in a third turbine (30), and introducing the air from the third turbine into the low pressure column (13) or in 5 the residual gas evacuated from an upper portion of the low pressure column (13).

7. Process according to claim 6, wherein all said air from the first or the second turbine (7, 8) is expanded in the third turbine (30), this air being at substantially the medium pressure, as well as a complementary air flow withdrawn from the base of the medium pressure column (12).

8. Process according to claim 1, wherein the further compression of the air is effected by means of at least two blowers (4, 5, 32) in series each coupled to one of the turbines (7, 8, 30).

9. In an installation for the production of gaseous oxygen under pressure by the distillation of air in a double air distillation column (1) comprising a column (13) operating under a low pressure and a column (12) operating under a medium pressure, a pump (9, 10) for compressing liquid oxygen withdrawn from the base of the low pressure column (13), compression means (3, 4, 5, 32) to bring the air to be distilled to a high air pressure substantially greater than the medium pressure, and a heat exchange line (2) to place in heat exchange relation the air at the high pressure and the compressed liquid oxygen;

the improvement wherein the compression means comprise a compressor (3) to bring all the air to be distilled to a first high pressure P1 substantially greater than the medium pressure, and means (4, 5,

     32) for further compressing a fraction of the air under this first high pressure to a second high pressure P2, these further compression means comprising at least two blowers in series each coupled to an expansion turbine (7, 8,

     30), one said blower (4;

     5) being coupled to a said turbine (7;

     8) for expanding air under the first high pressure P1 and another said blower (5;

     4) being coupled to a second said turbine (8;

     7) for expanding a portion of the further compressed air, the heat exchange line (2) comprising cooling passages for air from the said turbine (7) having the higher inlet temperature, and means for passing air from said turbine (7) having the higher inlet temperature through said cooling passages in countercurrent heat exchange relation with said compressed oxygen.

10. Installation according to claim 9, wherein the inlet temperature T1 for one (7) of the two turbines is comprised between about 0°

C. and -60°

C., while the inlet temperature T2 of the other turbine (8) is comprised between about -80°

C. and -130°

C.

11. Installation according to claim 9, which further comprises a second pump (10) for liquid oxygen or liquid nitrogen, the heat exchange line (2) comprising passages for vaporization-reheating of liquid thus pumped.

12. Installation according to claim 9, which further comprises a third turbine (3(:

)) for expanding to the low pressure at least a portion of the air from the said turbine (7) having the higher inlet temperature, and means to introduce the air from the third turbine into the low pressure column (13) or into a residual gas conduit from the low pressure column (13).

13. Installation according to claim 12, which further comprises means (33) to complete the supply of the third turbine (30) with air withdrawn from the base of the medium pressure column (12), said air from said turbine (7) having the higher inlet temperature being substantially at the medium pressure.

14. In an installation for the production of gaseous oxygen under pressure by distillation of air in a double air distillation column (1) comprising a column (13) operating under a low pressure and a column (12) operating under a medium pressure, a pump (9, 10) for compressing liquid oxygen withdrawn from the base of the low pressure column (13), compression means (3, 4, 5, 32) to supply air to be distilled at a high air pressure substantially greater than the medium pressure, and a heat exchange line (2) to place in heat exchange relation the air at the high pressure and the compressed liquid oxygen;

the improvement wherein the compression means comprise a compressor (3) to bring all the air to be distilled to a first high pressure P1 substantially greater than the medium pressure, and means (4, 5,

     32) for further compressing a fraction of the air under this first high pressure to a second high pressure P2, these further compression means comprising at least two blowers in series each coupled to an .expansion turbine (7, 8,

     32), one said blower (4;

     5) being coupled to one turbine (7;

     8) for expanding air under the first high pressure P1 and another said blower (5;

     4) being coupled to a second turbine (8;

     7) for expansion of a portion of the further compressed air, the inlet temperature T1 of one (7) of the two turbines being between about 0°

C. and -60°

C., while the inlet temperature T2 of the other turbine (8) is between about -80°

C. and -130°

C., the outlet pressure of said one turbine (7) being a pressure of said column (1) and means for passing air directly to said column (1) from said one turbine (7).

15. Installation according to claim 14, wherein the heat exchange line (2) comprises cooling passages for air from the turbine (7) having the higher inlet temperature, and means for passing air from said turbine (7) having the higher inlet temperature through said cooling passages in countercurrent heat exchange relation with said compressed oxygen.