Application of fuel cells to power generation systems

• US 5,401,589 A
• Filed: 07/23/1993
• Issued: 03/28/1995
• Est. Priority Date: 11/23/1990
• Status: Expired due to Fees

• Current Assignee: Wellman Defence Limited (TP Group Plc)
• Original Assignee: Vickers Shipbuilding & Engineering Limited (BAE Systems Plc), CJBD Limited
• Inventors: Palmer, Ian, Dams, Robert A. J., Seymour, Clive M.
• Primary Examiner(s): Willis, Jr., Prince
• Assistant Examiner(s): NUZZOLILLO, MARIA
• Application Number:
  US08/064,120
• Time in Patent Office: 613 Days
• Field of Search: 429/13, 429/17, 429/19, 429/24, 44/20
• US Class Current: 429/408
• CPC Class Codes: B63G 8/08 Propulsion schnorkels B63G8/36; nuclear propulsion B63H21/18; submerged exhausting apparatus F01N13/12
• CPC Class Codes: H01M 16/006 of fuel cells with rechargeable batteries
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 8/04 Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
• CPC Class Codes: H01M 8/0612 from carbon-containing material
• CPC Class Codes: H01M 8/0631 Reactor construction specially adapted for combination reactor/fuel cell hydrogen C01B3/00; reactors for physicochemical processes B01J19/00
• CPC Class Codes: H01M 8/0662 Treatment of gaseous reactants or gaseous residues, e.g. cleaning
• CPC Class Codes: H01M 8/247 Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y10S 429/901 Fuel cell including means for utilization of heat for unrelated application, e.g. heating a building

Abstract

The invention is drawn to an electrical power generation system and a method of electrical power generation. The system includes a supply of hydrogen-containing fuel and a reformer for obtaining hydrogen therefrom, a supply of oxygen and a material for producing an exothermic reaction. The system also includes a fuel cell and means for disposing of waste products arising from the fuel cell and other parts of the system, a control means and heat exchange means for regulating flow streams and balancing the heating and cooling requirements. The reformer comprises a reforming chamber, inlet and outlet for the fuel. Also the reformer includes a second chamber which surrounds the reforming chamber and a preheating chamber. Fins extend through a wall separating the reforming and surrounding chamber.

Claims

1. An electrical power generation system comprising:

a supply of a hydrogen-containing fuel;

a reformer for reforming said hydrogen-containing fuel to obtain hydrogen;

a supply of oxygen;

a fuel cell for producing electrical power, said fuel cell being fed with reactants including the hydrogen and the oxygen;

a supply of material for producing an exothermic reaction;

means for feeding the hydrogen and means for feeding the oxygen to the fuel cell for producing electrical power;

means for disposing of waste products arising from the fuel cell and other parts of the electrical power generation system;

a control means for regulating components of the electrical power generation system and for regulating flow streams of the system; and

heat exchange means for substantially balancing the heating and cooling requirements within said system;

wherein the reformer comprises;

(i) a reforming chamber having an outer first wall, inlet means for feeding said hydrogen-containing fuel to the reforming chamber, and outlet means for removing hydrogen from the reforming chamber,

(ii) a second chamber concentrically surrounding said reforming chamber and bounded on its inner side by said first wall and on its outer side by a second wall, said second chamber including inlet means for feeding said material for producing an exothermic reaction to the second chamber and outlet means for removing reaction products from the second chamber, and

(iii) a preheating chamber concentrically surrounding the second chamber for preheating the hydrogen-containing fuel, said concentric preheating chamber being bounded on its inner side by said second wall and on its outer side by a third wall, and having an inlet means for feeding the hydrogen-containing fuel to the preheating chamber and an outlet means for removing preheated hydrogen-containing fuel from the preheating chamber and feeding the fuel to the reforming chamber;

said first wall including a plurality of first fins passing through said first wall and extending into the second chamber and into the reforming chamber, respectively, said first fins being operative to conduct heat from the second chamber to the reforming chamber, said second wall including a plurality of second fins passing through said second wall so as to extend into the preheating chamber and into the second chamber respectively, said second fins being operative to conduct heat from the second chamber to the preheating chamber;

and wherein the flow of material through the second chamber is co-current with respect to the flow of hydrogen-containing fuel through the reforming chamber and is counter-current with respect to the flow of hydrogen-containing fuel to be reformed passing through the preheating chamber.

2. An electrical power generation system according to claim 1 further comprising an apparatus for processing an oxygen containing substance to produce said supply of oxygen.

3. An electrical power generation system according to claim 1 wherein the material for producing an exothermic reaction comprises a combustible material.

4. An electrical power generation system according to claim 1 wherein the material for producing an exothermic reaction comprises hydrogen peroxide and the exothermic reaction comprises a decomposition reaction.

5. An electrical power generation system according to claim 1 wherein the portions of the first fins disposed in the combustion chamber are tapered.

6. An electrical power generation system according to claim 1 wherein the second fins are tapered.

7. An electrical power generation system according to claim 1 further comprising a reforming catalyst on the portions of the first fins disposed in or on the surface of the first wall in the reforming chamber.

8. An electrical power generation system according to claim 1 further comprising a catalyst for said exothermic reaction on the surfaces of the portions of the first and second fins disposed in or on the surfaces of the first and second walls in the second chamber.

9. An electrical power generation system according to claim 1 further comprising means for mixing said hydrogen containing fuel with water before feeding said fuel into the reforming chamber.

10. An electrical power generation system according to claim 9 further comprising means for pressurizing said fuel/water mixture.

11. An electrical power generation system according to claim 10 wherein said means for pressurizing the fuel/water mixture produces a pressure sufficient to impel the reactants or products thereof through said system without further impelling means.

12. An electrical power generation system according to claim 10 further comprising means for heating the pressurized fuel/water mixture to a temperature exceeding the temperature required in the reforming chamber and means for flash evaporating the fuel/water mixture.

13. An electrical power generation system according to claim 12 wherein the heating means includes the preheating chamber.

14. An electrical power generation system according to claim 1 further comprising a reforming catalyst in a pellet form positioned in the reforming chamber.

15. An electrical power generation system according to claim 1 further comprising means for purifying a hydrogen reactant produced by reforming the hydrogen-containing fuel.

16. An electrical power generation system according to claim 15 wherein the purification means includes means for removing hydrocarbons and metallic ions, means for catalytically oxidizing carbon monoxide to carbon dioxide, and membrane means for removing water vapor, carbon dioxide and higher hydrocarbons.

17. An electrical power generation system according to claim 3 further comprising means for including excess hydrogen reactant from the fuel cell in the combustible material.

18. An electrical power generation system according to claim 1 wherein the heat exchange means includes means for preheating the hydrogen-containing fuel for the reformer using heat from the reformer.

19. An electrical power generation system according to claim 1 wherein the heat exchange means includes means for preheating the hydrogen-containing fuel for the reformer using heat from the fuel cell.

20. An electrical power generation system according to claim 1 wherein said means for feeding the hydrogen and means for feeding the oxygen include reservoirs for the reactants.

21. An electrical power generation system according to claim 1 wherein the fuel cell is disposed inside a pressurized container.

22. An electrical power generation system according to claim 21 wherein a size of the pressurized container is in excess of that of a fuel cell and said pressurizable container serves as a reservoir for one of the reactants.

23. An electrical power generation system according to claim 22 wherein the fuel cell is disposed inside a plastic sleeve.

24. An electrical power generation system according to claim 23 wherein hydrogen and/or oxygen sensors are disposed inside the plastic sleeve.

25. An electrical power generation system according to claim 1 further comprising means for providing a high pressure in the reforming chamber.

26. An electrical power generation system according to claim 1 further comprising a turbine driven by waste gas from the system for producing electrical or mechanical power.

27. An electrical power generation system according to claim 1 further comprising a working fluid, means to evaporate the working fluid by heat exchange with waste gases from the system and a turbine driven by the evaporated working fluid.

28. An electrical power generation system according to claim 1 further comprising means for dissolving waste gases from the system in aqueous solution.

29. An electrical power generation system according to claim 1 further comprising means for extracting heat from waste gases from the system and for transporting said heat for use outside the electrical power generation system.

30. An electrical power generation system according to claim 1 further comprising a rechargeable battery disposed in parallel with the fuel cell and wherein the control means comprises a selection means to selectively cause the battery to augment the fuel cell when demand for power increases and to cause the fuel cell to charge the battery when demand decreases or is constant.

31. An electrical power generation system according to claim 1 including a rechargeable battery and wherein the control means includes a selection means for causing the battery to be connected in parallel with the fuel cell such that the battery and the control means are operative to:

(a) supply power to initiate the operation of the fuel cell,

(b) accept power from the fuel cell to recharge the battery and to maintain the battery at a given level of charge, and

(c) supply power from the battery in conjunction with the fuel cell to thereby produce a combined power output to comply with a given power requirement.

32. A method of electrical power generation comprising the steps of:

providing a hydrogen-containing fuel and a supply of oxygen;

providing a fuel cell for producing electrical power when fed with hydrogen and oxygen;

providing a reformer comprising a reforming chamber, a second chamber surrounding the reforming chamber and divided therefrom by a first common wall, and a preheating chamber surrounding said second chamber and divided therefrom by a second common wall;

providing first fins extending through said first common wall into said reforming chamber and said second chamber;

providing second fins extending through said second common wall into said preheating chamber and said second chamber;

supplying a material for producing an exothermic reaction to said second chamber and reacting said material in said second chamber to generate heat;

supplying said hydrogen-containing fuel to said preheating chamber and preheating said fuel by transferring heat to the preheating chamber through said second common wall and said second fins;

supplying said preheated hydrogen containing fuel to said reforming chamber, transferring heat from said second chamber to said reforming chamber, through said first common wall and said first fins, and reforming said hydrogen containing fuel in said reforming chamber to produce hydrogen, whereby said flow of exothermically reacting material through the second chamber is co-current with respect to the flow of fuel through the reforming chamber, such that the amount of heat transferred to the reforming chamber is greater towards entry regions of said chambers than towards exit regions thereof, and said flow of exothermically reacting materials is counter-current with respect to the flow of fuel to be reformed passing through the preheating chamber;

feeding said hydrogen and oxygen to said fuel cell to produce electrical power;

disposing of waste products from the fuel cell and other parts of the power generation system;

providing control means for monitoring the operating parameters of the power generation system as a whole and of individual components of the system and for regulating the same in accordance with the power demands on the system and regulating the flow of fuel, reactants and products between components of the system to substantially balance the heating requirements of one or more parts of the system with the cooling requirements of one or more other parts of the system.

33. A method of electrical power generation according to claim 32 further comprising the step of applying a catalyst for the exothermic reaction to the surface of the portions of the first fins, and to the surface of the first common wall, in the second chamber.

34. A method of electrical power generation according to claim 32 wherein the exothermic reaction is a combustion reaction.

35. A method of electrical power generation according to claim 32 wherein the exothermic reaction comprises the decomposition of hydrogen peroxide.

36. A method of electrical power generation according to claim 32 further comprising the steps of providing a rechargeable battery and connecting said battery in parallel with the fuel cell, said control means including a selection means operable to:

(a) supply power from the fuel cell to the battery to recharge the battery when demand for power decreases or is constant and

(b) draw power from the battery to augment the fuel cell output when demand for power increases.

37. A method of electrical power generation according to claim 36 wherein, when supplying power from the fuel cell to recharge the battery, the control means conditions the output of the fuel cell such that the voltage supplied from the fuel cell to the battery is slightly greater than the voltage of the battery.

38. A method of electrical power generation according to claim 37 wherein the control means regulates the output of the fuel cell by accurate control of the rate of input of one or both of the hydrogen and oxygen to the fuel cell.