Sprayable thermoplastic compositions

• US 5,401,792 A
• Filed: 11/10/1993
• Issued: 03/28/1995
• Est. Priority Date: 11/10/1993
• Status: Expired due to Fees

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Babu, Gaddam N., Hansen, Dennis D.
• Primary Examiner(s): Hoke, Veronica P.
• Application Number:
  US08/150,594
• Time in Patent Office: 503 Days
• Field of Search: 524/271, 524/272, 525/270, 525/94, 428/200, 428/349
• US Class Current: 524/270
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C09J 123/08 Copolymers of ethene C09J123/16 takes precedence
• CPC Class Codes: Y10T 428/24843 with heat sealable or heat releasable adhesive layer
• CPC Class Codes: Y10T 428/2826 Synthetic resin or polymer

Abstract

Sprayable hot-melt adhesive compositions are disclosed comprising (A) styrenic block copolymer, (B) tackifying resin, and (C) ethylene copolymer. Methods of preparing and using said compositions are also disclosed.

Claims

1. A sprayable hot-melt adhesive composition comprising (A) styrenic block copolymer whose interpolymerized units comprise from 12 to 45 weight percent of units derived from styrenic monomers;

(B) tackifying resin; and

(C) ethylene copolymer having a melt index sufficiently high to impart good sprayability and desirably long open time to said composition.

2. The composition of claim 1 wherein said block copolymer is a block copolymer whose interpolymerized units comprise from 25 to 35 weight percent of units derived from styrenic monomers.

3. The composition of claim 2 wherein said block copolymer is a linear block copolymer having an average molecular weight of from 80,000 to 145,000.

4. The composition of claim 2 wherein said block copolymer is a radial block copolymer having an average molecular weight of at least 140,000.

5. The composition of claim 1 wherein said ethylene copolymer is selected from the group consisting of ethylene-vinyl acetate copolymers, ethylene-methyl acrylate copolymers, and ethylene-n-butyl acrylate copolymers.

6. The composition of claim 1 wherein said ethylene copolymer is selected from the group consisting of ethylene-vinyl acetate copolymers having a melt index of at least 150, ethylene-methyl acrylate copolymers having a melt index of at least 70, and ethylene-n-butyl acrylate copolymers having a melt index of at least 150.

7. The composition of claim 1 wherein said block copolymer comprises blocks whose interpolymerized units are derived from isoprene, butadiene, or combinations thereof.

8. The composition of claim 1 wherein said tackifying resin is present in said adhesive composition as 20 to 300 parts by weight per 100 parts by weight of said block copolymer and said ethylene copolymer.

9. The composition of claim 1 wherein said ethylene copolymer is present in an amount sufficient to improve the sprayability of the composition compared to compositions without said ethylene copolymer.

10. The compositions of claim 9 wherein said ethylene copolymer is present as 25 to 400 parts by weight per 100 parts by weight of said block copolymer.

11. The composition of claim 1 wherein said composition is sprayable at temperatures below 149°

C. (300°

F.).

12. The composition of claim 1 further comprising a polymer having an inherent viscosity of 0.2 to 1.4 whose interpolymerized units consist essentially of units derives from alpha-olefins containing from 4 to 18 carbon atoms.

13. The composition of claim 12 wherein said alpha olefins are selected from the group consisting of 1-octene and 1-hexene.

14. An article comprising a first and second substrate, wherein said substrates are bonded together with a sprayable hot-melt adhesive composition comprising a styrenic block copolymer whose interpolymerized units comprise from 12 to 45 weight percent of units derived from styrenic monomers, a tackifying resin, and an ethylene copolymer having a melt index sufficiently high to impart good sprayability and desirably long open times to said composition.

15. The article of claim 14 wherein at least one of said substrates comprises polyethylene or polypropylene.

16. The article of claim 14 wherein said hot-melt composition further comprises a polymer having an inherent viscosity of 0.2 to 1.4 whose interpolymerized units consist essentially of units derived from alpha-olefins containing from 4 to 18 carbon atoms.

17. A method for preparing an article comprising the steps of

(A) preparing a sprayable hot-melt adhesive composition comprising a styrenic block copolymer whose interpolymerized units comprise from 12 to 45 weight percent of units derived from styrenic monomers, a tackifying resin, and an ethylene copolymer having a melt index sufficiently high to impart good sprayability and desirably long open times to said composition,

(B) spraying said adhesive composition onto a first substrate to form an adhesive layer, and

(C) applying a second substrate to said adhesive layer such that a bond is formed between said first and second layers.

18. The method of claim 17 wherein at least one of said substrates comprises polyethylene or polypropylene.

19. The method of claim 17 wherein said hot-melt adhesive composition further comprises a polymer having an inherent viscosity of 0.2 to 1.4 whose interpolymerized units consist essentially of units derived from alpha-olefins containing from 4 to 18 carbon atoms.