Chromium-free catalyst for the hydrogenation of organic compounds

• US 5,403,962 A
• Filed: 05/31/1994
• Issued: 04/04/1995
• Est. Priority Date: 12/13/1991
• Status: Expired due to Fees

• Current Assignee: Sud-Chemie AG (Clariant AG)
• Original Assignee: Sud-Chemie AG (Clariant AG)
• Inventors: Schneider, Michael, Maletz, Gerd, Kochloefl, Karl
• Primary Examiner(s): EVANS, JOSEPH
• Application Number:
  US08/251,625
• Time in Patent Office: 308 Days
• Field of Search: 568/885, 568/881, 568/862, 568/864
• US Class Current: 568/885
• CPC Class Codes: B01J 23/8892 Manganese
• CPC Class Codes: C07C 29/149 with hydrogen or hydrogen-containing gases
• CPC Class Codes: C07C 31/125 containing five to twenty-two carbon atoms

Abstract

The invention describes a chromium-free catalyst for hydrogenation of organic compounds, especially organic compounds containing the carbonyl function, such as aldehydes, ketones, or carboxylic acids or their esters, to the corresponding alcohols wherein the catalysts is characterized by the following features:

its oxide form corresponds to the composition

Cu.sub.a Al.sub.b Zr.sub.c Mn.sub.d O.sub.x

wherein the following relations apply:

for the first embodiment:

a>O; b>O; c≧O; d>O; a>b/2; b>a/4; a>c; a>d;

and for the second embodiment:

a>O; b=a/40 to a/4; c≧O; d>O; a>c; a=0.5 d to 0.95 d

and x is the number of oxygen ions needed per formula unit for electrical neutrality.

Claims

1. A process for hydrogenation of organic compounds containing the carbonyl function or unsaturated organic compounds using a chromium-free catalyst which in the oxide form is comprised of a chemical composition corresponding to the formula:

space="preserve" listing-type="equation">Cu.sub.a Al.sub.b Zr.sub.c Mn.sub.d O.sub.x

wherein the following relationships apply;

a>

0;

b>

0;

c>

0;

d>

0;

a>

b/2;

b>

a/4;

a>

c;

a>

d; and

x is the number of oxygen ions needed per formula unit for electrical neutrality;

wherein after thermal treatment, said catalyst in the oxide form has a BET surface area between about 10 and about 150 m² /g, and wherein the acid resistance of said catalyst as measured by the solubility of the copper, aluminum, zirconium, and manganese in said catalyst in acid is not more than 400 mg as determined by stirring 10 g of said catalyst in 100 ml of 10 weight percent aqueous acetic acid at 20°

C. for 2 minutes.

2. The process of claim 1 wherein the organic compounds are aldehydes, ketones, or carboxylic acids or their esters.

3. The process of claim 2 which is a liquid phase hydrogenation of carboxylic acids having 5 to 24 carbon atoms and their esters to the corresponding fatty alcohols.

4. A process for hydrogenation of organic compounds containing the carbonyl function or unsaturated organic compounds which in the oxide form is comprised of a chemical composition corresponding to the formula:

space="preserve" listing-type="equation">Cu.sub.a Al.sub.b Zr.sub.c Mn.sub.d O.sub.x

wherein the following relations apply;

a>

0;

b=a/40 to a/4;

c>

0;

d>

70;

a>

c;

a=0.5 d to 0.95 d and x is the number of oxygen ions needed per formula unit for electrical neutrality;

wherein after thermal treatment of an intermediate convertible to the oxide in the temperature range from 450°

C. to 900°

C., said catalyst in the oxide form has a BET surface area between about 10 and about 150 m² /g, and wherein the acid resistance of said catalyst as measured by the solubility of the copper, aluminum, zirconium, and manganese in said catalyst in acid is not more than 400 mg as determined by stirring 10 g of said catalyst in 100 ml of 10 weight percent aqueous acetic acid at 20°

C. for 2 minutes.

5. The process of claim 4 wherein the organic compounds are aldehydes, ketones, or carboxylic acids or their esters.

6. The process of claim 5 which is a liquid phase hydrogenation of carboxylic acids having 5 to 24 carbon atoms and their esters to the corresponding fatty alcohols.