Process and installation for producing nitrogen and oxygen

• US 5,404,725 A
• Filed: 10/12/1993
• Issued: 04/11/1995
• Est. Priority Date: 10/27/1992
• Status: Expired due to Fees

• Current Assignee: L'Air Liquide Societe Anonyme Pour L'Etude et L'Exploitation Des Procedes Georges Claude (L'Air Liquide SA)
• Original Assignee: L'Air Liquide Societe Anonyme Pour L'Etude et L'Exploitation Des Procedes Georges Claude (L'Air Liquide SA)
• Inventors: Arriulou, Pascal
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US08/134,545
• Time in Patent Office: 546 Days
• Field of Search: 62/25, 62/38, 62/40
• US Class Current: 62/646
• CPC Class Codes: F25J 2200/50 using multiple (re-)boiler-condensers at different heights of the column
• CPC Class Codes: F25J 2200/72 Refluxing the column with at least a part of the totally condensed overhead gas
• CPC Class Codes: F25J 2200/76 Refluxing the column with condensed overhead gas being cycled in a quasi-closed loop refrigeration cycle
• CPC Class Codes: F25J 2200/90 Details relating to column internals, e.g. structured packing, gas or liquid distribution
• CPC Class Codes: F25J 2250/20 Boiler-condenser with multiple exchanger cores in parallel or with multiple re-boiling or condensing streams
• CPC Class Codes: F25J 3/04296 Claude expansion, i.e. expanded into the main or high pressure column
• CPC Class Codes: F25J 3/04351 of nitrogen
• CPC Class Codes: F25J 3/044 using a single pressure main column system only F25J3/0446, F25J3/04624, F25J3/04636 take precedence
• CPC Class Codes: F25J 3/04884 Arrangement of reboiler-condensers
• CPC Class Codes: Y10S 62/939 Partial feed stream expansion, air

Abstract

A column (4) for producing nitrogen comprises, below the air introduction point, a section (17, 18) enriched in oxygen and a sump reboiler (9) supplied by recycled high pressure nitrogen. The expanded liquid (at 19) for supplying the overhead condenser (8) is withdrawn at an intermediate level between the level of air introduction and the reboiler, and the liquid in the sump of the column, after vaporization, constitutes a minority product of the installation consisting essentially of oxygen.

Claims

1. Process for producing a majority of nitrogen and a minority of oxygen by distilling a gaseous mixture, comprising:

cooling the gaseous mixture and thereafter introducing it at an intermediate level of a distillation column (4) operating at a medium pressure and equipped with a head condenser (8) and a sump reboiler (9);

vaporizing in the head condenser liquid richer in oxygen than is said gaseous mixture, withdrawn from said column below the introduction point of the gaseous mixture, after expansion (at

     19) to a low pressure less than the medium pressure;

withdrawing gaseous nitrogen from the head condenser and reheating it, with a portion thereof being compressed to a high pressure greater than the medium pressure, cooled and introduced into the reboiler (9) to be condensed therein; and

expanding (at

     15) at least a portion of the liquid nitrogen thus obtained to the medium pressure and introducing it into the head of the column;

wherein;

said liquid is withdrawn at an intermediate level between the level of gaseous mixture introduction into said column and the reboiler; and

liquid in the sump of the column is vaporized and recovered as a minority product consisting essentially of oxygen.

2. Process according to claim 1, wherein the sump liquid intended to constitute said minority product is vaporized by the reboiler (9) and withdrawn in gaseous form immediately above this latter.

3. Process according to claim 1, wherein the sump liquid intended to constitute said minority product is expanded (at 24) and thereafter vaporized in an auxiliary condenser (25) provided in the upper part of the column (4).

4. Process according to claim 3, wherein the auxiliary condenser (25) is arranged below the head condenser (8).

5. Process according to claim 3, wherein the auxiliary condenser (25) is arranged in parallel with the head condenser (8), said sump liquid being expanded (at 24) to a pressure lower than the said low pressure.

6. Process according to claim 1, wherein the gaseous mixture is air. recovering the resulting gas, consisting essentially of oxygen, as a minority product of the installation.

7. Process according to claim 1, wherein liquid in the sump of the column is richer in oxygen than is said withdrawn liquid.

8. Process according to claim 1, and providing in said column solid surfaces (17, 18) for liquid-vapor mass transfer between said introduction point of gaseous mixture and said sump, some (17) of said solid surfaces being below said point of introduction of gaseous mixture but above said intermediate level of withdrawal of said liquid and others (18) of said surfaces being above said sump but below said intermediate level of liquid withdrawal.

14. Installation according to claim 7, wherein the point of withdrawal of said liquid is such that the liquid in the sump of the column has a higher oxygen content than said withdrawn liquid.

9. Installation for producing a majority of nitrogen and a minority of oxygen by distillation of a gaseous mixture, comprising:

a distillation column (4) operating under a medium pressure and equipped with a head condenser (8) and a sump reboiler (9);

means (1, 2, 3,

     5) for compressing, purifying and cooling the gaseous mixture and introducing it at an intermediate level into the column;

means (16) for withdrawing a liquid richer in oxygen than is said gaseous mixture, at a level of said column lower than the level of introduction of the gaseous mixture, means (19) for expanding this liquid at a low pressure and means for introducing it into the head condenser (8) so as to vaporize it;

means (11) for withdrawing nitrogen from the head of the column, and means (6, 3, 7,

     14) for reheating, compressing to a high pressure, cooling and introducing into the reboiler (9) a portion of this nitrogen; and

means (15) for expanding to the medium pressure at least a portion of the liquid nitrogen issuing from the reboiler and for introducing it into the head of the column;

wherein

the withdrawal level of the said liquid is intermediate between the level of introduction of the gaseous mixture into said column and the reboiler (9); and

said installation further comprises means (9, 20, 21, 23 to

     26) for vaporizing the liquid in the sump of the column and for recovering the resulting gas, consisting essentially of oxygen, as a minority product of the installation.

10. Installation according to claim 9, wherein the column (4) comprises a conduit (20) for withdrawing said minority product immediately above the reboiler (9).

11. Installation according to claim 9, wherein the column (4) comprises an auxiliary condenser (25) supplied with said sump liquid via a conduit (23) equipped with an expansion valve (24).

12. Installation according to claim 11, wherein the auxiliary condenser (25)is mounted at a lower level than the head condenser (8).

13. Installation according to claim 11, wherein the auxiliary condenser (25)is mounted in parallel with the head condenser (8).

15. Installations according to claim 9, there being solid surfaces (17, 18) for liquid-vapor mass transfer within said column between said introduction point of gaseous mixture and said sump, some (17) of said solid surfaces being below said point of introduction of gaseous mixture but above said intermediate level of withdrawal of said liquid and others (18) of said surfaces being above said sump but below said intermediate level of liquid withdrawal.